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Method state preparation

Inorganic Compounds. Inorganic selenium compounds are similar to those of sulfur and tellurium. The most important inorganic compounds are the selenides, haUdes, oxides, and oxyacids. Selenium oxidation states are —2, 0, +1, +2, +4, and +6. Detailed descriptions of the compounds, techniques, and methods of preparation, and references to original work are available (1—3,5,6—10, 51—54). Some important physical properties of inorganic selenium compounds are Hsted in Table 3. [Pg.331]

Properties of lakes that enhance their usefiilness iaclude their opacity, their abiUty to be iacorporated iato products ia the dry state, their relative iasolubihty, and their superior stabiUty toward heat and light. Such properties have made possible the more effective and more efficient preparation of candy and tablet coatings, and often eliminate the need to remove moisture from dry products before coloring them. Lakes have also made possible the coloring of certain products that, because of their nature, method of preparation, or method of storage, caimot be colored with ordinary color additives. [Pg.444]

The most reliable method of preparing benzofuroxans is by decomposition of o-nitrophenyl azides. Decomposition can be achieved by irradiation, or more usually by pyrolysis temperatures between 100° and 1.50° are commonly used. Refluxing in glacial acetic acid is the recommended procedure for 4- or 5-sub-stituted 2-nitrophenyl azides, but with 3- or 6-substituted compounds higher boiling solvents are usually necessary. Quantitative studies on the reaction rate have been made, and a cyclic transition state invoked, an argument which has been used to account for the greater difficulty of decomposition of the 6-substituted 2-nitrophenyl azides. Substituent effects on the reaction rate have also been correlated with Hammett a constants, ... [Pg.14]

In comparing his three main S5mtheses of pyrylium salts (see Sections II,B,2,f C,2,g and D, l,b) besides his less general syntheses (see Sections II,B,2,e C,2,a and D,2,a), Dilthey stated that the type in Section D, l,b is the most convenient. This is the standard method for preparing 2,4,6-triarylpyTylium salts with identical 2- and 6-substituents, in particular 2,4,0-triphenylpyrylmm. 398,389 vepage yields are SQ% in the presence of BF3-Et.20 they can be raised to 40%. The reaction can be applied to substituted... [Pg.304]

Besides acetophenone, this reaction was also applied to p-chloro- andp-methoxyacetophenone, and even to an aliphatic ketone, acetone (although the yield was stated to be only half as large as that obtained from mesityl oxide, i.e., less than 30%, Dorofeenko and co-workers reported a 45% yield of 2,4,6-trimethylpyrylium perchlorate from acetone, acetic anhydride, and perchloric acid), and is the standard method for preparing pyrylium salts with identical substituents in positions 2 and 4. The acylating agent may be an anhydride in the presence of anhydrous or hydrated ferric chloride, or of boron fluoride, or the acid chloride with ferric chloride.Schneider and co-workers ... [Pg.309]

An interesting method for preparing 2,6-dioxo-l,3-oxazine derivatives was described by Wasserman and Koch who stated that the five-membered ring of an a-keto-lactam could be transformed into the 1,3-oxazine (22) by ozone followed by reduction with zinc. [Pg.322]

It should be noted that the properties of a CTC depend to a considerable degree on the conditions of their preparation. Temperature increase, in particular, favors the accumulation of complete charge transfer states in a CTC. In the case of a CTC obtained in solution, the increase of dielectric constant of the solvent has the same effect. The method of preparation of a CTC also affects the kinetic curves of the accumulation and depletion of complete transfer states arising at protoirradiation. [Pg.33]

The data presented here has provided a chronological picture of the evolution and current state of the possible positive or negative association of some methylxanthine-containing products and various types of cancer. Perhaps the best conclusion at this time is an extension to tea and other methylxanthine-containing products of the statement by Stavric" who in 1990 wrote that certain controversial issues about the effect of coffee on human health remains unresolved. Future work should focus on types and methods of preparation of teas, roasting and preparation methods for coffees, and consider the whole beverage rather than caffeine or other methylxanthine per se. Meanwhile it appears that both tea and coffee and... [Pg.342]

Chemists are invited to submit for publication in Organic Syntheses procedures for the preparation of compounds which are of general interest or which illustrate useful synthetic methods. The procedures submitted should represent, as nearly as possible, optimum conditions for the preparations, and should have been checked carefully by the submitter. Full details of all steps in the procedure should be included, and the range of yields should be reported rather than the maximum yield obtainable. The melting point of each solid product should be given, and the boiling-point range and refractive index (at 25°) of each liquid product. The method of preparation or source of the reactants and the criteria for the purity of the products should be stated. [Pg.1]

The above theory is usually called the generalized linear response theory because the linear optical absorption initiates from the nonstationary states prepared by the pumping process [85-87]. This method is valid when pumping pulse and probing pulse do not overlap. When they overlap, third-order or X 3 (co) should be used. In other words, Eq. (6.4) should be solved perturbatively to the third-order approximation. From Eqs. (6.19)-(6.22) we can see that in the time-resolved spectra described by x"( ), the dynamics information of the system is contained in p(Af), which can be obtained by solving the reduced Liouville equations. Application of Eq. (6.19) to stimulated emission monitoring vibrational relaxation is given in Appendix III. [Pg.64]

A related method of preparation involves the oxidative addition of a tin(II) salt to propargylic iodides, which yield mixtures of allenyl- and propargyltin halides on treatment with SnCl2 in DMF-DMI (l,3-dimethylimidazol-2-one) (Eq. 9.75) [68], These intermediates react in situ with aldehydes to afford mixtures of propargylic and allenic carbinols via a cyclic SE2 process (Eqs. 9.76 and 9.77). As explained in the Introduction, the ratio of these two products reflects the relative transition-state energies of the addition reactions. [Pg.544]

Project-research proved to be an effective method of organizing research on chemical warfare during World War 1. It solved a problem encountered early in the United States preparation for chemical warfare, that of efficiently coordinating the work of volunteer chemists who were isolated in separate laboratories. Later in the war it was continued more because it enabled the examination of the chemical, pharmacological, and technical aspects of one problem to proceed simultaneously in several research units. In this way results were expected to be obtained in the shortest possible time. [Pg.192]


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See also in sourсe #XX -- [ Pg.95 ]




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Prepared states

State method

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