Metallic placement

An imponant component of the complex metallizations for both semiconductor devices and magnetic media is the diffusion barrier, which is included to prevent interdiffiision between layers or diffusion from overlyii layers into the substrate. A good example is placement of a TiN barrier under an Al metallization. Figure 7a illustrates the results of an SNMSd high-resolution depth profile measurement of a TiN diffusion barrier inserted between the Al metallization and the Si substrate. The profile clearly exhibits an uneven distribution of Si in the Al metallization and has provided a clear, accurate measurement of the composition of the underlying TiN layer. Both measurements are difficult to accomplish by other means and dem-... 

With all these advantages one might well wonder why the left-step table has not attracted more attention and indeed why it has not been widely adopted. The answer to this question lies in the placement of one crucial element, helium. In the left-step table, helium is placed among the alkaline earth metals as mentioned above. To most chemists this is completely abhorrent since helium is regarded as the noble gas par excellence. Meanwhile, to a physicist or somebody who emphasizes electronic properties, helium falls rather naturally into the alkaline earths since it has two outer-shell electrons. 

The element hydrogen has been placed by different authors in the alkali metals, in group 14 on top of carbon, among the halogens and sometimes simply allowed to float in an apparently unconnected manner above the main body of the periodic table. Citations for the first placement are unnecessary because this is a frequent choice. For the second, third, and fourth placements, see [36-40]. 

At least 2 weeks for bare metal stent placement. 

Stenting Placement of a stent (a short metal or plastic tube) to allow blood flow through an artery. 

Precise placement of metal complexing sites within the infrastructure of a cascade molecule is of importance from a variety of perspectives. In the construction of the above noted Micellane family (cf. Sect. 3.1), we reported the construction of dendrimers with four alkyne moieties at sites equidistant from each other in the interior (17, Fig. 8) [60]. These were treated with decaborane (B10H14) to afford 1,2-dicarba-closo-dodecaboranes (o-carboranes) [71]. Rendering boron clusters soluble in water is of interest because of their use in cancer treatment by Boron Neutron Cancer Therapy. First and second generation water-soluble dendrimers containing four and twelve precisely located boron cluster sites, respectively, were synthesized (e.g., 18). These water soluble dendrimers and their precursors were characterized by 13C-, and nB-NMR spectroscopy (Fig. 8). 

Anthocyanins are colored flavonoids that attract animals when a flower is ready for pollination or a fruit is ready to eat. They are glycosides (i.e., the molecule contains a sugar) that range in color from red, pink, and purple to blue depending on the number and placement of substitutes on the B ring (see Fig. 3.7), the presence of acid residues, and the pH of the cell vacuole where they are stored. Without the sugar these molecules are called anthocyanidins. The color of some pigments results from a complex of different anthocyanin and flavone molecules with metal ions. 

According to ACC/AHA 2007 guidelines, clopidogrel is indicated for up to 12 months in NSTE ACS patients, with a minimum treatment duration of 1 month after placement of a bare-metal stent and 12 months after placement of a sirolimus- or paclitaxel-coated stent. 

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