Metal polynuclear transition

The magnetic properties of polynuclear transition metal complexes. P. W. Ball, Coord. Chem. Rev., 1969, 4, 361-383 (150). 

On the general theory of magnetic susceptibilities of polynuclear transition metal compounds. J. S. Griffith, Struct. Bonding (Berlin), 1972,10, 87-126 (43). 

Structural and magnetic studies of polynuclear transition metal p-polyketonates. M. D. Glick and R. L. Lintvedt, Prog. Inorg. Chem., 1976, 21, 233-260 (51). 

Structural chemistry of polynuclear transition metal cvanides. A. Ludi and H. U. Giidel, Struct. Bonding (Berlin), 1973,14, 1-21 (71). 

A possible mechanism for the reactions of electrophiles with polynuclear transition metal carbonyls and related complexes. A. R. Manning, Coord. Chem. Rev., 1983, 51, 41-67 (41). 

Polynuclear transition metal cyanides such as the well-known Prussian blue and its analogues with osmium and ruthenium have been intensely studied Prussian blue films on electrodes are formed as microcrystalline materials by the electrochemical reduction of FeFe(CN)g in aqueous solutionThey show two reversible redox reactions, and due to the intense color of the single oxidation states, they appear to be candidates for electrochromic displays Ion exchange properties in the reduced state are limited to certain ions having similar ionic radii. Thus, the reversible... 

Ludi A, Gudel HU (1973) Structural Chemistry of Polynuclear Transition Metal Cyanides. 14 1-21... 

Ruiz E (2004) Theoretical Study of the Exchange Coupling in Large Polynuclear Transition Metal Complexes Using DFT Methods 113 71-102... 

Griffith, J. S. On the General Theory of Magnetic Susceptibilities of Polynuclear Transition-metal Compounds. Vol. 10, pp. 87—126. 

Balzani V, Juris A, Venturi M (1996) Luminescent and redox-active polynuclear transition metal complexes. Chem Rev 96 759-833... 

PB analogs (other polynuclear transition metal hexacyanometallates94-96) that have been reported as thin films are surveyed in this section. 

K. Itaya, I. Uchida, and V.D. Neff, Electrochemistry of polynuclear transition metal cyanides Prussian blue and its analogues. Aco. Chem. Res. 19, 162—168 (1986). 

P.J. Kulesza and Z. Galus, Polynuclear transition metal hexacyanoferrate films. In-situ electrochemical determination of their composition. J. Electroanal. Chem. 267, 117-127 (1989). 

Amino acid is one of the most important biological ligands. Researches on the coordination of metal-amino acid complexes will help us better understand the complicated behavior of the active site in a metal enzyme. Up to now many Ln-amino acid complexes [50] and 1 1 or 1 2 transition metal-amino acid complexes [51] with the structural motifs of mononuclear entity or chain have been synthesized. Recently, a series of polynuclear lanthanide clusters with amino acid as a ligand were reported (most of them display a Ln404-cubane structural motif) [52]. It is also well known that amino acids are useful ligands for the construction of polynuclear copper clusters [53-56], Several studies on polynuclear transition metal clusters with amino acids as ligands, such as [C03] [57,58], [Co2Pt2] [59], [Zn6] [60], and [Fe ] [61] were also reported. 

Molecular Rearrangements in Polynuclear Transition Metal Complexes, 16, 319... 

In the last few years a great number of polynuclear transition metal complexes have been synthesized. Such compounds usually have well-defined composition and, in several cases, present a modular structure since they can contain repetitive metal-based components and/or spacers made of repetitive units. Research in the field of polynuclear transition metal complexes can give an important contribution to the development of modular chemistry and to the bottom-up design of nanostructures. ... 

When interaction between the metal-based components is weak, polynuclear transition metal complexes belong to the field of supramolecular chemistry. At the roots of supramolecular chemistry is the concept that supramolecular species have the potential to achieve much more elaborated tasks than simple molecular components while a molecular component can be involved in simple acts, supramolecular species can performIn other words, supramolecular species have the potentiality to behave as molecular devices. Particularly interesting molecular devices are those which use light to achieve their functions. Molecular devices which perform light-induced functions are called photochemical molecular devices (PMD). Luminescent and redox-active polynuclear complexes as those described in this chapter can play a role as PMDs operating by photoinduced energy and electron transfer processes. ... 

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