Modular chemistry

Michl J (ed) (1997) Modular Chemistry. Kluwer, Dordrecht Hori Y, Noda K, Kobayashi S, Taniguchi H (1969) Tetrahedron Lett 3563 Hopf H, Kreuzer M, Jones PC (1991) Chem Ber 124 1471 Tykwinski RR, Diederich F (1997) Liebigs Ann/Recueil 649... 

Diederich F (1997) Tetraethynylethenes Versatile Carbon-rich Building Blocks for Two-dimensional Acetylenic Scaffolding. In Michl J (ed) Modular Chemistry. Kluver,... 

In the last few years a great number of polynuclear transition metal complexes have been synthesized. Such compounds usually have well-defined composition and, in several cases, present a modular structure since they can contain repetitive metal-based components and/or spacers made of repetitive units. Research in the field of polynuclear transition metal complexes can give an important contribution to the development of modular chemistry and to the bottom-up design of nanostructures. ... 

Figure 19-11 Flow injection analysis system with enlarged view of chemistry section. Different modular chemistry units are installed for different analyses. [Courtesy Skalar, Inc.. Norcross. GA]... 

Manickam, G. and Schluter, A. D. (2000) New parts for a construction set of bifunctional oligo(het)arylene building blocks for modular chemistry, Synthesis, 3, 442-446. 

Eddaoudi M., Moler D. B., Li Hailian, Chen Banglin, Reineke T. M., O Keeffe M. and Yaghi O. M., Modular Chemistry Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks, Acc. Chem. Res. 34 (2001) pp. 319-330. 

A. D. Schliiter, V. Hensel, P. Liess, K. Liitzow, Modular Chemistry, Kluwer, Dordrecht, The Netherlands, 1997. 

Ellman utilized the Suzuki coupling twice between a support-bound vinyl bromide and an alkyl 9-BBN derivative in a solid-phase synthesis of E- and F-series prostaglandins. The Suzuki reaction was performed in situ, with the hydroboration of a terminal olefin being followed by the palladium-mediated step. This sequence is attractive in library synthesis because of the wide range of suitable commercially available alkenes. The inspiration behind this chemistry was the solution-phase work of Johnson and Braun, where the couplings of 35 with 2-iodo-4-(silyloxy)cyclopent-2-enone 36 went well at room temperature with PdCljCdppO-AsPhj as catalyst (Scheme 41). The modular chemistry demonstrated in this paper was clearly amenable to adaptation to a solid-phase strategy. 

Rajca, A. (1997). Assembling triarylmethyls into mesoscopic-size polyradicals How to maintain strong interactions between multiple sites in a single molecule In Modular Chemistry, Michl, J. (ed.), pp. 193-200, Kluwer Academic Publishers, Dordrecht, The Netherlands... 

Eddaoudi et al. 2001 Modular chemistry SBUs in porous carboxylate design [42]... 

R.E. Smalley and D.T. Colbert, in Proceedings from NATO Advanced Research Workshop Modular Chemistry , J. Michl (ed.), Kluwer Academic Publishers 1997. 

Diederich, F. (1997) in Modular Chemistry (ed. J. Michl), Kluwer Academic Publishers, Dordrecht, p. 17. 

D.A. TomaUa. Nanoscopic modules for the construction of higher ordered complexity, in Modular Chemistry, Proceedings of the NATO Advanced Research Workshop on Modular Chemistry. J. Michl, Ed. Kluwer PubUshers The Netherlands, pp. 183-191,1997. 

Tomalia DA (1997) Nanoscopic modules for the construction of higher ordered cranplexity. In Michl J (ed) Modular cherrristry proceedings of the NATO advanced research wrakshop on modular chemistry. KIuwct, The Netherlands, pp 183—191... 

DA Tomaha. Dendrimers Nanoscopie Modules for the Construction of Higher Ordered Complexity. In J Miehl ed. Modular Chemistry, Proceedings of the NATO... 

Advanced Research Workshop on Modular Chemistry, The Netherlands Kluwer Academic 1997, 183-191. 

In their search to modular chemistry, Michl eta/, described the synthesis of (if-Ch)Co derivatives 294 in which the cyclobutadiene (Gb) moiety was substituted by 4-pyridine or 4-R-phenyl groups permitting the access to square-grid polymers (Figure 57)." ... 

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