Metal Complex Synthesis

Dinitrogen-transition metal complexes synthesis, properties and significance. D. Sellmann, Angew. Chem., Int. Ed. Engl., 1974,13, 639-649 (86). 

Tris(bipyridyl) complexes structure, 1, 63 Tris(diketonate) complexes structure, 1,65 Trisdithiolencs metal complexes synthesis, 2, 597... 

Imidazolium salts that can be prepared by the first procedure, the alkylation of imidazole, are easy to obtain and often used for metal complex synthesis. Potassium imidazolide is reacted with the first equivalent of alkyl halide in toluene to give the 1-alkylimidazole. Subsequent alkylation in 3-position is achieved by addition of another equivalent of alkyl halide [Eq. (2)]. " A variant of this approach employs commercially available A-trimethylsilyl imidazole with 2 equiv of an alkyl chloride, under elimination of volatile MesSiCl. The drawback of these simple routes is the fact that only primary alkyl halides can be reacted in satisfactory yields because secondary and tertiary alkyl halides give substantial amounts of elimination by-products. 

Diaza-l3-butadiene Metal Complexes Synthesis, Occurrence and Properties 208... 

Diaza-l,3-butadiene Metal Complexes Synthesis, Occurrence and Properties 13.5.3.4.1 Monodentate bonded 1,4-diaza-l,3-butadiene ligands (a-N two electron)... 

Formamide, diphenyl-metal complexes, 491 Formamide, -methyl-metal complexes synthesis, 492... 

Phosphinimato complexes transition metals, 122,125 bonding, 124 IR spectroscopy, 124 reactions, 125 structure, 124 synthesis, 123 Phosphini mines imido metal complexes synthesis from, 167 Phosphoglucomutase zinc complexes, 965 Phospholes... 

Sulfide oxidases, 773 Sulfinylamines imido metal complexes synthesis from, 167 Sulfites... 

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