Mercury film electrode , stripping analysis

Anodic stripping voltammetry at a mercury film electrode can be used to determine whether an individual has recently fired a gun by looking for traces of antimony in residue collected from the individual s hands, fn a typical analysis a sample is collected with a cotton-tipped swab that had been wetted with 5% v/v HNO3. When returned to the lab, the swab is placed in a vial containing 5.00 mb of 4 M HCl that is 0.02 M in hydrazine sulfate. After allowing the swab to soak overnight,... 

Scarponi et al. [781] studied the influence of an unwashed membrane filter (Millpore type HA, 47 mm diameter) on the cadmium, lead, and copper concentrations of filtered seawater. Direct simultaneous determination of the metals was achieved at natural pH by linear-sweep anodic stripping voltammetry at a mercury film electrode. These workers recommended that at least 1 litre of seawater be passed through uncleaned filters before aliquots for analysis are taken the same filter can be reused several times, and only the first 50-100 ml of filtrate need be discarded. Samples could be stored in polyethylene containers at 4 °C for three months without contamination, but losses of lead and copper occurred after five months of storage. 

EDTA was determined in waste water by Fayyad et al, who used potentiometric stripping analysis after adding Bi(III) and K C O to the test solution. Uncomplexed Bi(III) was electrodeposited on a mercury film electrode (at -0.4 V vs. SCE) for 50 seconds. The working range was 4.5-95 ppb of EDTA [20]. 

Taking advantage of the ability to detect multiple group II and group III metals at mercury film electrodes using stripping analysis, a multianalyte DNA sensor was developed using different semiconductor nanocrystals (ZnS, CdS, and PbS) for the... 

The mercury film electrode (MFE), used for stripping analysis or flow amperometry, consists of a very thin (10-100-pm) layer of mercury covering a conducting and inert support. Because of the adherent oxide films on metal surfaces, and the interaction of metals with mercury, glassy carbon is most often used as a substrate for the MFE. The mercury film formed on a glassy carbon support is actually composed of many droplets. Because they do not... 

Mercury film electrode An electrode that has been coated with a thin layer of mercury used in place of a hanging mercury drop electrode in anodic stripping analysis. 

The mercury electrode used in stripping analysis is either a conventional HMDE or a mercury film electrode (MFE). In current practice, the MFE is typically deposited onto a rotating glassy carbon or wax-impregnated graphite disk. One usually adds mercuric ion... 

Hoyer B and Kryger L (1985) A theoretical and experimental study of the waveform in potentiometric stripping analysis with a rotating mercury film electrode - the reversible case. Talanta 32 839-844. 

Economou A, Fieldtai PR (1997) Applications, pofimtialities and limitations of adsorptive stripping analysis on mercury film electrodes. Trends Anal Chem 16 286-292... 

Anodic shipping voltammetry (ASV) is the most widely used form of stripping analysis, hi this case, the metals are preconcenhated by elechodeposition into a small-volume mercury electrode (a tiiin mercury film or a hanging mercury drop). The preconcenhation is done by catiiodic deposition at a controlled tune and potential. The deposition potential is usually 0.3-0.5 V more negative than E° for the least easily reduced metal ion to be determined. The metal ions reach die mercury electrode by diffusion and convection, where diey are reduced and concentrated as amalgams ... 

Stripping voltammetry or stripping analysis has a special place in electrochemistry because of its extensive application in trace metal analysis. Stripping voltammetry (SV) is a two-step process as shown schematically in Fig. 18b. 12. In the first step, the metal ion is reduced to metal on a mercury electrode (thin mercury film on glassy carbon or a HMDE) as amalgam. 

Potentiometric stripping analysis (PSA) is another attractive version of stripping analysis [7]. The preconcentration step in PSA is the same as for ASV that is, the metal is electrolytically deposited (via reduction) onto the mercury electrode (usually a film). The stripping, however, is done by chemical oxidation, for example, with oxygen or mercuric ions present in the solution ... 

Thin layer concepts may also be involved in metal deposition into thin films of mercury during stripping analysis, in (electro)chemical processes in adsorbates, films or precipitates on modified electrodes, or in scanning electrochemical microscopy. 

A special branch of cyclic polarography is the stripping analysis [10-13] which makes possible the determination of very small amounts of substances (subnanograms), j.e., an analysis of 10 " M solutions. The precision is lower than in cla ical polarography (here it is about 2%) and depends on the substance td be determined and on its concentration. The basis of the stripping analysis is an electrolytical accumulation from the solution of the substance to be determined on the stationary mercury electrode. This is effected either as amalgam or as film formation on the mercury electrode. In some special cases, a solid, e.g., carbon electrode. 

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