Mercaptobenzene

Malonic acid diamide, m4 Malonylurea, bl Margaryl alcohol, hi a Mellitic acid, b20 MEM chloride, m74 Menadione, m321 1,8-Mentanediamine, d51 / -Mentha-1,8-diene, L17, L18 / -Mentha-6,8-dien-2-one, c20 Mercaptobenzene, tl 56... 

MERCAPTOBENZENE (108-98-5) Forms explosive mixture with air (flash point 71°F/22°C also listed at 132°F/56°C cc technical grades can be contaminated with carbon disulfide which may tend to lower the flash point). Reacts with water, steam, or acids, producing toxic and flammable vapors. Oxidizes on exposure to air, forming diphenyl disulfide. Incompatible with strong acids, caustics, alkali metals. Oxidizes on contact with air. Corrosive to carbon steel. 

Thimerfonate Sodium. EthyH4-mercaptobenzene-sulfonato-S )mercury sodium salt sodium p-ethylmercuri-thiophenylsulfonate ethyl[(p-sulfopheny])thio]mercury sodium salt Sulfo-Merthiolate. CgHgHgNaOjS, mol wt 440.89. 

Beilstein Handbook Reference) AI3-16418 Benzene, mercapto- Benzenethiol BRN 0506623 EINECS 203-635-3 FEMA No, 3616 HSDB 5387 Mercaptobenzene NSC 6953 Phenol, thio- Phenyl mercaptan Phenylthiol RCRA waste number P014 Thiofenol Thiophenol UN2337 USAF XR-19, Intermediate in synthesis of pesticides and pharmaceuticals. Oil mp = -14.8° bp = 169,1° d = 1.0775 wm = 240 nm (e = 7244, EtOH) insoluble in H2O, slightly soluble in CCI4, soluble in EtOH, EtzO, OeHe. ICI Americas Inc, Janssen Chimica Lancaster Synthesis Co. Sigma-Aldrich Fine Chem. 

Dibasic tridentate Schiff bases derived from salicylaidehydes and 2-aminobenzoic add or l amino-2-mercaptobenzene react with aqueous zirconium nitrate to give monomeric complexes of the type [Zr(0H)2(L)(H20)]. IR spectra of these compounds support an ONO-or ONS-tridentate attachment of the (L) ligands. 

Synonyms/Trade Names Mercaptobenzene, Phenyl mercaptan, Thiophenol... 

Mercaptobenzene. See Thiophenol 2-Mercaptobenzimidazole CAS 583-39-1 EINECS/ELINCS 209-502-6 Synonyms 2-Benzimidazolethiol Benzimidazole-2-thiol 2-Benzimidazolinthion MBI o-Phenylenethiourea Empirical C7H6N2S... 

Carbon dioxide radical anions, C02 , are commonly used in aqueous chemistry as a reducing agent for metalloporphyrins or as intermediate in the formation of superoxide anion. COf has been reported to undergo efficient electron transfer reactions with methyl violo-gen, quinones, alkyl halides, fumarates, nitro and nitrosobenzenes and chlorinated benzaldehydes. With nitrobenzenes and chlorinated benzaldehydes, electron attachment occurs on the nitro and aldehyde groups, respectively. CO2 radicals have also been reported to add to some unsaturated compounds such as acrylamide and pyridin-3-ol. Efficient hydrogen abstraction from mercaptobenzenes have also been reported. 

J. Shi, Zhe Wang and Hu Un Li, Selfassembly of gold nanoparticles onto the surface of multiwall carbon nanotubes functionalized with mercaptobenzene moieties. Journal of Nanoparticle Research, 8(5), 743-747 (2006). 

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