Mass turbulent flow

Most ion-molecule techniques study reactivity at pressures below 1000 Pa however, several techniques now exist for studying reactions above this pressure range. These include time-resolved, atmospheric-pressure, mass spectrometry optical spectroscopy in a pulsed discharge ion-mobility spectrometry [108] and the turbulent flow reactor [109]. 

Film Theory. Many theories have been put forth to explain and correlate experimentally measured mass transfer coefficients. The classical model has been the film theory (13,26) that proposes to approximate the real situation at the interface by hypothetical "effective" gas and Hquid films. The fluid is assumed to be essentially stagnant within these effective films making a sharp change to totally turbulent flow where the film is in contact with the bulk of the fluid. As a result, mass is transferred through the effective films only by steady-state molecular diffusion and it is possible to compute the concentration profile through the films by integrating Fick s law ... 

The physics and modeling of turbulent flows are affected by combustion through the production of density variations, buoyancy effects, dilation due to heat release, molecular transport, and instabiUty (1,2,3,5,8). Consequently, the conservation equations need to be modified to take these effects into account. This modification is achieved by the use of statistical quantities in the conservation equations. For example, because of the variations and fluctuations in the density that occur in turbulent combustion flows, density weighted mean values, or Favre mean values, are used for velocity components, mass fractions, enthalpy, and temperature. The turbulent diffusion flame can also be treated in terms of a probabiUty distribution function (pdf), the shape of which is assumed to be known a priori (1). 

Eddy diffusion as a transport mechanism dominates turbulent flow at a planar electrode ia a duct. Close to the electrode, however, transport is by diffusion across a laminar sublayer. Because this sublayer is much thinner than the layer under laminar flow, higher mass-transfer rates under turbulent conditions result. Assuming an essentially constant reactant concentration, the limiting current under turbulent flow is expected to be iadependent of distance ia the direction of electrolyte flow. 

As may be expected, turbulent flow (9,11) is more efficient for droplet formation in low viscosity Hquids. With the average amount of energy dissipated per unit time and volume equal to Z and mass density equal to p, the larger eddies are characterized by a velocity gradient equal to... 

Diffusion is the molecular transport of mass without flow. The diffu-sivity (D) or diffusion coefficient is the proportionality constant between the diffusion and the concentration gradient causing diffusion. It is usually defined by Fick s first law for one-dimensional, binary component diffusion for molecular transport without turbulence shown by Eq. (2-149)... 

Here, h is the enthalpy per unit mass, h = u + p/. The shaft work per unit of mass flowing through the control volume is 6W5 = W, /m. Similarly, is the heat input rate per unit of mass. The fac tor Ot is the ratio of the cross-sectional area average of the cube of the velocity to the cube of the average velocity. For a uniform velocity profile, Ot = 1. In turbulent flow, Ot is usually assumed to equal unity in turbulent pipe flow, it is typically about 1.07. For laminar flow in a circiilar pipe with a parabohc velocity profile, Ot = 2. 

Because this mass-transfer step is so vital, conventional dead-end operation of ultrafilters is veiy rare. There are many ways to depolarize a membrane. Cross-flow is by far the most common. Turbulent flow is more common than laminar flow. 

Computational fluid dynamics (CFD) is the numerical analysis of systems involving transport processes and solution by computer simulation. An early application of CFD (FLUENT) to predict flow within cooling crystallizers was made by Brown and Boysan (1987). Elementary equations that describe the conservation of mass, momentum and energy for fluid flow or heat transfer are solved for a number of sub regions of the flow field (Versteeg and Malalase-kera, 1995). Various commercial concerns provide ready-to-use CFD codes to perform this task and usually offer a choice of solution methods, model equations (for example turbulence models of turbulent flow) and visualization tools, as reviewed by Zauner (1999) below. 

The major mechanism of a vapor cloud explosion, the feedback in the interaction of combustion, flow, and turbulence, can be readily found in this mathematical model. The combustion rate, which is primarily determined by the turbulence properties, is a source term in the conservation equation for the fuel-mass fraction. The attendant energy release results in a distribution of internal energy which is described by the equation for conservation of energy. This internal energy distribution is translated into a pressure field which drives the flow field through momentum equations. The flow field acts as source term in the turbulence model, which results in a turbulent-flow structure. Finally, the turbulence properties, together with the composition, determine the rate of combustion. This completes the circle, the feedback in the process of turbulent, premixed combustion in gas explosions. The set of equations has been solved with various numerical methods e.g., SIMPLE (Patankar 1980) SOLA-ICE (Cloutman et al. 1976). 

Figure 10-50C. Tube-side (inside tubes) liquid film heat transfer coefficient for Dowtherm . A fluid inside pipes/tubes, turbulent flow only. Note h= average film coefficient, Btu/hr-ft -°F d = inside tube diameter, in. G = mass velocity, Ib/sec/ft v = fluid velocity, ft/sec k = thermal conductivity, Btu/hr (ft )(°F/ft) n, = viscosity, lb/(hr)(ft) Cp = specific heat, Btu/(lb)(°F). (Used by permission Engineering Manual for Dowtherm Heat Transfer Fluids, 1991. The Dow Chemical Co.)...

X(( = correlation for turbulent-turbulent flow, dimensionless W = mass flow rate, lb/sec... 

Liquids in motion have characteristics different from liquids at rest. Frictional resistances within the fluid, viscosity, and inertia contribute to these differences. Inertia, which means the resistance a mass offers to being set in motion, will be discussed later in this section. Other relationships of liquids in motion you must be familiar with. Among these are volume and velocity of flow flow rate, and speed laminar and turbulent flow and more importantly, the force and energy changes which occur in flow. 

Calderbank s correlation for turbulent flow aeration shows mass transfer is proportional to... 

In streamline flow, E is very small and approaches zero, so that xj p determines the shear stress. In turbulent flow, E is negligible at the wall and increases very rapidly with distance from the wall. LAUFER(7), using very small hot-wire anemometers, measured the velocity fluctuations and gave a valuable account of the structure of turbulent flow. In the operations of mass, heat, and momentum transfer, the transfer has to be effected through the laminar layer near the wall, and it is here that the greatest resistance to transfer lies. 

Linton, W.H. and Sherwood, T.K. Chem. Eng. Prog. 46 (1950) 258. Mass transfer from solid shapes to water in streamline and turbulent flow. 

Sherwood, T.K. Trans. Am. Inst. Chem. Eng. 36 (1940) 817. Mass transfer and friction in turbulent flow. 

In addition to momentum, both heat and mass can be transferred either by molecular diffusion alone or by molecular diffusion combined with eddy diffusion. Because the effects of eddy diffusion are generally far greater than those of the molecular diffusion, the main resistance to transfer will lie in the regions where only molecular diffusion is occurring. Thus the main resistance to the flow of heat or mass to a surface lies within the laminar sub-layer. It is shown in Chapter 11 that the thickness of the laminar sub-layer is almost inversely proportional to the Reynolds number for fully developed turbulent flow in a pipe. Thus the heat and mass transfer coefficients are much higher at high Reynolds numbers. 

For flow in a smooth pipe, the friction factor for turbulent flow is given approximately by the Blasius equation and is proportional to the Reynolds number (and hence the velocity) raised to a power of -2. From equations 12.102 and 12.103, therefore, the heat and mass transfer coefficients are both proportional to w 75. 

Obtain the Taylor-Prandtl modification of the Reynolds Analogy between momentum transfer and mass transfer (equimolecular counterdiffusion) for the turbulent flow of a fluid over a surface. Write down the corresponding analogy for heat transfer. State clearly the assumptions which are made. For turbulent flow over a surface, the film heat transfer coefficient for the fluid is found to be 4 kW/m2 K. What would the corresponding value of the mass transfer coefficient be. given the following physical properties ... 

When two or more phases are present, it is rarely possible to design a reactor on a strictly first-principles basis. Rather than starting with the mass, energy, and momentum transport equations, as was done for the laminar flow systems in Chapter 8, we tend to use simplified flow models with empirical correlations for mass transfer coefficients and interfacial areas. The approach is conceptually similar to that used for friction factors and heat transfer coefficients in turbulent flow systems. It usually provides an adequate basis for design and scaleup, although extra care must be taken that the correlations are appropriate. 

Mass and heat transfer to the walls in turbulent flows is a complex mixture of molecular transport and transport by turbulent eddies. The generally assumed analogy between mass and heat transfer by assuming Sh = Nu, is not valid for turbulent flows [26]. Simulations and measurements have shown that there is a laminar film close to the surface where most of the mass transfer resistance for high Sc liquids is located. This fUm is located below y+ = 1 and for low Sc fluids, and for heat transfer the whole boundary layer is important [27]. 

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