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Magnesium phosphide

The stability of phosphinous amides depends, to a large extent, on the substituents at phosphorus and nitrogen. Normally, tetrasubstituted and N,P,P-trisubstituted phosphinous amides are stable and well-known compounds. The parent compound H2PNH2 is a volatile compound that is formed on hydrolysis of a solid state solution mixture of magnesium phosphide and magnesium... [Pg.79]

Phosphine is generated when phosphide salts (i.e., Aluminum phosphide Calcium phosphide Magnesium phosphide Magnesium aluminum phosphide Potassium phosphide Sodium phosphide Stannic phosphide Strontium phosphide Zinc phosphide) come into contact with water. [Pg.317]

Aluminum Magnesium Phosphide Aluminum Phosphide Amarelinho (Citrus)... [Pg.630]

Magnesium phosphate compounds, uses for, 75 416-416 Magnesium phosphide, 19 58 Magnesium preparation, for Grignard reactions, 72 824... [Pg.543]

The reaction of phosphine (produced in situ from magnesium phosphide and hydrogen chloride in dioxan solution) with 1,5-diketones gives106 the phosphorina-none derivatives (104). Carbonyl compounds and heterocumulenes (e.g. CO2, CS2) insert into the germanium-phosphorus bond of germaphospholans to form derivatives of the germaphosphepin system [e.g. (105)].106>107... [Pg.18]

Calcium phosphide and magnesium phosphide, crystallise in a lattice which can be deduced from the fluorite structure. One way to describe the... [Pg.19]

The presence of phosphorus may also be ascertained by heating the compound with magnesium powder, and moistening the cold product with water, whereby phosphine (recognised by its smell) is liberated from the magnesium phosphide. . ... [Pg.445]

MRH Phosphine 2.13/11, phosphorus trioxide 0.46/43, magnesium phosphide 4.02/39 Borondiiodophosphide, phosphine, phosphorus trioxide and trimercury tetraphos-phide all ignite in contact with chlorine at ambient temperature. Trimagnesium diphosphide and trimanganese diphosphide ignite in warm chlorine [1], while ethyl-phosphine explodes with chlorine [2]. Unheated boron phosphide incandesces in chlorine. [Pg.1458]

White phosphoms has been used in the manufacture of rat and cockroach poisons, pesticides, matchheads, firecrackers, and ammunitions in the military. However, other chemicals such as sulfur have replaced phosphorus in matchheads. Phosphoms is also used as a fumigant in the storage of grain in the form of aluminum phosphide pellets. Due to ease of application, pellets of aluminum or magnesium phosphide are commonly used (Garry et al. 1989). [Pg.22]

Includes aluminium phosphide, zinc phosphide, magnesium phosphide. [Pg.794]

Magnesium phosphide was first obtained from the metal and organic substances containing phosphorus,5 but is best prepared by heating the metal in phosphorus vapour or with red phosphorus in an atmosphere of hydrogen.6,7... [Pg.61]

Magnesium phosphide,10 aluminium phosphide 11 and phosphides of several other metals also yield phosphine when treated with acids. [Pg.70]

See other pages where Magnesium phosphide is mentioned: [Pg.587]    [Pg.318]    [Pg.377]    [Pg.230]    [Pg.229]    [Pg.4]    [Pg.210]    [Pg.154]    [Pg.230]    [Pg.161]    [Pg.1409]    [Pg.1412]    [Pg.1589]    [Pg.1766]    [Pg.672]    [Pg.245]    [Pg.98]    [Pg.150]    [Pg.360]    [Pg.587]    [Pg.65]    [Pg.106]    [Pg.123]    [Pg.805]    [Pg.842]    [Pg.1455]    [Pg.1655]    [Pg.1847]    [Pg.2107]    [Pg.2438]    [Pg.1409]    [Pg.1412]    [Pg.1589]    [Pg.1766]    [Pg.179]    [Pg.145]    [Pg.201]   
See also in sourсe #XX -- [ Pg.19 ]



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