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Long Time Response

Adsorption is a process of molecular binding on the surface of the gel. Absorption is that of molecular binding into the gel. The model only considers the former case, adsorption. If we take time, absorption process grows. It becomes difficult to ignore the effect of absorption. This is one of the biggest limitations of the model. [Pg.46]


MCT can be best viewed as a synthesis of two formidable theoretical approaches, namely the renormalized kinetic theory [5-9] and the extended hydrodynamic theory [10]. While the former provides the method to treat both the very short and the very long time responses, it often becomes intractable in the intermediate times. This is best seen in the calculation of the velocity time correlation function of a tagged atom or a molecule. The extended hydrodynamic theory provides the simplicity in terms of the wavenumber-dependent hydrodynamic modes. The decay of these modes are expressed in terms of the wavenumber- and frequency-dependent transport coefficients. This hydrodynamic description is often valid from intermediate to long times, although it breaks down both at very short and at very long times, for different reasons. None of these two approaches provides a self-consistent description. The self-consistency enters in the determination of the time correlation functions of the hydrodynamic modes in terms of the... [Pg.70]

The decrease in response is probably due to the poorer material quality (as measured by X-ray diffraction) associated with increasing the aluminium composition. As in the GaN detectors, long time responses (1 ms) are reported for AlGaN devices. [Pg.636]

Long time response (2) long time response and increasing complexity (3) V/F control is not desirable in general (4) column bottom level control by steam flow is desirable. (Comments are due toT. Umeda). b Direct M.B. = direct material balance control Indirect M.B. indirect material balance control V/F = vapor to feed ratio control... [Pg.273]

Trying to control the liquid level at the bottom of the column with the reflux flow or distillate flow rate involves very long time responses because the action of the manipulated variable must travel the whole length of the distillation column before it is felt by the controlled variable. Therefore, control-loop configurations 4, 5,10,12,14,16,17,18, 20, 21, 23, and 24 are ruled out. [Pg.629]

A long time response is also involved when we try to control the level in the overhead accumulator by manipulating the bottoms flow rate for the same reason as above. This rules out configurations 1 and 8. [Pg.629]

A flow chart demonstrating the protocol is shown in Fig. 6. The procedure has been demonstrated for poly(3-methylthiophene) films, by analysis of frequency response as a function of time during film electropolymerization short (long) time responses represent the acoustically thin (thick) film scenario [24]. Film mass (whether or not directly accessible from A/ data) defines the product hypy, so (as shown in Fig. 6 [24]) a plot of hy versus py is a hyperbola. As film mass (polymer coverage) increases, a series of hyperbolae are generated. The acoustically thin film data (A/ and Q) define the unique solution (of the infinity of solutions on the hyperbola) for p as indicated in Fig. 6 [24] this value is projected across all the hyperbolae. [Pg.243]

German KONVOI plants are equipped with a permanent in-core instrumentation. N4 plants have very accurate movable in-core instrumentation with long time response used to calibrate the less accurate ex-core instrumentation used in the core protection system. With the fixed in-core measurements, periodically calibrated by the very quick movable aeroball system, the on-line core surveillance and protection is far more precise and contributes to a significant increase of the safety margins. [Pg.174]

The dynamic behavior of the optical-field-in-duced Freedericksz transition is also analogous to the dc case. The initial response of the induced molecular reorientation to the laser switch-on and the long-time response to the laser switch-off are both exponential with relaxation times Tqjj and Toff, respectively. [Pg.108]

Long-Time Response Time-Averaged Velocity Profiles... [Pg.30]

If the early stages of formation of the banding structure seem to be common to various semidilute solutions, the space and long-time responses strongly differ from one sample to another. [Pg.43]

A master curve for a polymer for a temperature of 100° C is given in the figure below. Assuming the TTSP and the WLF equation is valid, estimate the short and long time response for temperatures of 120° C and 90° C. Sketch the expected master curves for each temperature on the given graph. [Pg.273]

Direct time-dependent detection is limited by the response time of detectors, which depends on the frequency range, and the electronics used for data acquisition. In the most favourable cases, modem detector/oscilloscope combinations achieve a time resolution of up to 100 ps, but 1 ns is more typical. Again, this reaction has been of fiindamental theoretical interest for a long time [59, 60]. [Pg.2126]

This result shows that the highest modes of response have the shortest relaxation times and influence the initial response of the sample. Conversely, the longest relaxation time is ti, which we can identify with the terminal behavior of the sample. For example, in Fig. 3.9 the final collapse of the modulus at long times occurs at Ti. An example will show how we can use this idea. [Pg.190]

Copper has been employed as a bactericide, moUuscicide, and fungicide for a long time and is of importance in the control of schistosomiasis (see also Antiparasitic AGENTS, ANTHELMINTICS FUNGICIDES, AGRICULTURAL). Addition of copper to lake water acts as an efficient deterrent to transmittal of the disease by eliminating snails that act as hosts for the responsible parasite. Copper is commonly utilized at ca 0.1 mg/L as an algicide. In fresh water, acute toxicosis in fish is unusual if the copper concentration is below 0.025 mg/L (70) (see Poisons, economic). [Pg.212]

Many double-charged anions, such as sulfate, hydrophosphate, oxalate etc., are highly widespread in natural sources and at the same time lack any convenient technique for their determination. Therefore, development of ion-selective electrodes (ISEs), responsive to these anions, is of great practical importance. However, for a long time all attempts directed toward creation of such electrodes were unsuccessful (except for carbonate ISEs based on trifluoroacetylbenzene derivatives), and only in recent years this field has shown significant progress. [Pg.302]

Arguably, risk assessment from exposure to carcinogens merits special consideration because of the low levels of exposure capable of producing an adverse response in certain individuals coupled with the often long time-lag (latency period) between exposure and onset of disease. [Pg.90]


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