Long fiber materials

Long fiber material with synthetic rubber binder suitable for service conditions, or spiral wound stainless steel and equal gasket material... 

In summary, it can be seen that plastics and RPs design analysis follows the same three steps (a) to (c) as that for metals, but there are some differences of emphasis and difficulty. In particular, step (a) is usually more substantial for the newer materials, partly because a full stress/strain/deformation analysis is required and partly because of the need to take account of viscoelasticity, inhomogeneity, and/or anisotropy. For long fiber materials, the component design analysis may need to contain the associated material design analysis. 

The presence of hemoglohin-S (Hb-S) ia red blood cells leads to the formation of Hquid crystalline aggregates iaside the ceU under conditions of low oxygen tension (43,44). The morbid aggregates ultimately arrange themselves iato a gel-like material composed of long fibers that extend the entire length of the ceU and distort its usual shape. 

The majority of particles in the atmosphere are spherical in shape because they are formed by condensation or cooling processes or they contain core nuclei coated with liquid. Liquid surface tension draws the material in the particle into a spherical shape. Other important particle shapes exist in the atmosphere e.g., asbestos is present as long fibers and fly ash can be irregular in shape. 

Proteins are usually separated into two distinct functional classes passive structural materials, which are built up from long fibers, and active components of cellular machinery in which the protein chains are arranged in small compact domains, as we have discussed in earlier chapters. In spite of their differences in structure and function, both these classes of proteins contain a helices and/or p sheets separated by regions of irregular structure. In most cases the fibrous proteins contain specific repetitive amino acid sequences that are necessary for their specific three-dimensional structure. 

Quite specific effects in the flow of dispersions of long fibers are connected with particles orientation in the flow. Indeed, the state of fibers during the flow changes greatly as compared the initial state, so that the material in a steady-state flow is an anisotropic medium. Therefore the viscosity of such a suspension may become independent of a fiber s length [30], The most strong effects caused by a deformation of anisotropic particles should be expected in transient flows, in particular if the particles themselves are flexible and deformed in the flow. 

The functions and property characteristics of a product will be largely determined by the performance requirements and material selected for fabrication. The basic requirement of the process is its capability of handling a suitable material. For example, if a major function requirement is for resistance to creep under high loads, it is probable that a long-fiber RP will be necessary. Thus it would immediately eliminate such processes as blow molding and conventional injection molding. 

Uniaxial deformations give prolate (needle-shaped) ellipsoids, and biaxial deformations give oblate (disc-shaped) ellipsoids [220,221], Prolate particles can be thought of as a conceptual bridge between the roughly spherical particles used to reinforce elastomers and the long fibers frequently used for this purpose in thermoplastics and thermosets. Similarly, oblate particles can be considered as analogues of the much-studied clay platelets used to reinforce a variety of materials [70-73], but with dimensions that are controllable. In the case of non-spherical particles, their orientations are also of considerable importance. One interest here is the anisotropic reinforcements such particles provide, and there have been simulations to better understand the mechanical properties of such composites [86,222],... 

The systems discussed up to now all showed chiral susceptibilities that were of the same order of magnitude or smaller than the achiral susceptibility components. The system that we discuss in this section has chiral susceptibilities that dominate the nonlinear optical response.53 The material is a chiral helicenebisquinone derivative shown in Figure 9.22. In bulk samples, the nonracemic, but not the racemic, form of the material spontaneously organizes into long fibers clearly visible under an optical microscope. These fibers comprise columnar stacks of helicene molecules.54,55 Similar columnar stacks self-assemble in appropriate solvents, such as n-dodecane, when the concentration exceeds 1 mM. This association can be observed by a large increase in the circular dichroism (CD) of the solutions. 

The care of microfiber products is similar to that of the normal fiber materials made from the same polymer. One caution is heat sensitivity. Because the fibers are so fine, heat penetrates easily causing them to scorch or glaze more quickly than normal fibers if too much heat is applied or heat is applied over too long a period. Typically, microfibers are wrinkle-resistant, but if ironing is done, it should be accomplished using lower temperatures and only as directed. 

While many fillers are spherical, some are fiberlike. When the length of these fibrous materials approaches 100 times their thickness, many combinations offer great increases in the strength-related properties of the materials that contain them. If these fibers are contained within a continuous phase, they are generally described as traditional composites. Because of their importance, much of this chapter will deal with such traditional long-fiber composites. 

FIGURE 8.8 General forms for discontinuous phase materials, from left, are continuous or long fibers, short fibers, whiskers, and particulates. 

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