Litre weight

Moleeular weight sal 19. Molecular volume anomalous I i I I. 1 litre weight 79 4 eritht. 

BSI 2000. Methods of Analysis of Fats and Fatty Oils. Part 1. Physical Methods, Section 1.1. Determination of litre weight in air. British Standards Institution, London. 

The bulk density of a clinker, determined under standard conditions by rejecting material passing a 5-mm sieve, pouring the remainder into a conical container, and weighing, is called the litre weight. This quantity, which is typically 1.25-1.35 kg 1 gives some indication of the operating conditions. Its optimum value depends on the composition. 

Atomic might =16. Molecular might 82. Molecular volume I I I. 1 litre weight 10 eriths. Atomeitg", Evidence... 

Sfokeuhr weight 60. Molecular vobme onomafout CD 1 litre weight U erithe. 

Molecular weight <= 64. Molecular volume IT). 1 litre weight 82 erithe. Solid at —7VP. Liquid under thcpretcure qf two aimatphoret at 7° C. 

Hoiemler weight =81. Mblewlar whawem. 1 litre weight 40iiorithe. 

Atomic weight 19. Molecular weight 88 (P). Molecular volume rn. 1 litre weight 19 orithe (P). Atomicity Evidence ef atomicity t—... 

Molecular weight >=>78. Molecular volume QD. 1 litre weight 89 eritha. Both at —40°. 

Litre-weight Test. A works test for the routine control of the firing of portland cement clinker it was introduced by W. Anselm (Zement, 25, 633,1936). 

Extinguishant type Capacity litres Weight kg Discharge Fire rating ... 

Sodium Hypochi ite. zM- This may be prepared with sufficient accuracy by dissolving 100 g. of NaOH in 200 ml. of water in a large beaker, cooling the solution, and then adding about 500 g. of crushed ice. Now counterpoise the beaker on a rough set of scales, and pass in chlorine from a cylinder until an increase in weight of 72 g. is obtained. Make up the solution to i litre and stir well. The solution must be kept in a cool dark place, but even then slowly decomposes. 

Equip a 1-litre three-necked flask with a mechanical stirrer, a separatory funnel and a thermometer. Place a solution of 47 g. of sodium cyanide (or 62 g. of potassium cyanide) in 200 ml. of water in the flask, and introduce 58 g. (73-5 ml.) of pure acetone. Add slowly from the separatory fumiel, with constant stirring, 334 g. (275 ml.) of 30 per cent, sulphuric acid by weight. Do not allow the temperature to rise above 15-20° add crushed ice, if necessary, to the mixture by momentarily removing the thermometer. After all the acid has been added continue the stirring for 15 minutes. Extract the reaction mixture with three 50 ml. portions of ether, dry the ethereal extracts with anhydrous sodium or magnesium sulphate, remove most of the ether on a water bath and distil the residue rapidly under diminished pressure. The acetone cyanohydrin passes over at 80-82°/15 mm. The yield is 62 g. 

In a 2-litre round-bottomed flask, equipped with a double surface condenser, place 60 g. of triniethylene dicyanide (Section 111,114) and 900 g. of 50 per cent, sulphuric acid (by weight). Reflux the mixture for 10 hours and allow to cool. Saturate the solution with ammonium sul phate and extract wit-h four 150 ml. portions of ether dry the ethereal extracts with anhydrous sodium or magnesium sulphate. Distil off the ether on a water bath the residual glutaric acid (69 g.) crystallises on cooling and has m.p. 97-97-5°. Upon recrystalhsation from chloroform, or benzene, or benzene mixed with 10 per cent, by weight of ether, the m.p. is 97 -5-98°. 

In a 1 litre round-bottomed flask, equipped with an air condenser, place a mixture of 44 g. of o-chlorobenzoic acid (Section IV,157) (1), 156 g. (153 ml.) of redistilled aniline, 41 g. of anhydrous potassium carbonate and 1 g. of cupric oxide. Reflux the mixture in an oil bath for 2 hours. Allow to cool. Remove the excess of aniline by steam distillation and add 20 g. of decolourising carbon to the brown residual solution. Boil the mixture for 15 minutes, and filter at the pump. Add the filtrate with stirring to a mixture of 30 ml. of concentrated hydrochloric acid and 60 ml. of water, and allow to cool. Filter off the precipitated acid with suction, and dry to constant weight upon filter paper in the air. The yield of iV-phenylanthranilic acid, m.p. 181-182° (capillary tube placed in preheated bath at 170°), is 50 g. This acid is pure enough for most purposes. It may be recrystaUised as follows dissolve 5 g. of the acid in either 25 ml. of alcohol or in 10 ml. of acetic acid, and add 5 ml. of hot water m.p. 182-183°. 

Figure 1 The solubility of the prineipal atmospherie gases in seawater, as a funetion of temperature. Units are millilitres of gas eontained in a litre of seawater of salinity 35 psu, assuming an overlying atmosphere purely of eaeh gas. Note that salinity is defined in terms of a eonduetivity ratio of seawater to a standard KCl solution and so is dimensionless. The term praetieal salinity unit , or psu, is often used to define salinity values, however. It is numerieally praetieally identieal to the old style unit of parts per thousand by weight...

Another area which is of considerable interest is the development of rotationally moulded products. These mouldings include air ducting housing and a 700-litre frozen food container, both of which are greater than 20 kg in weight. 

In treated water for high-pressure boilers or where radiation effects are important, as in some nuclear projects, impurities are measured in very small units (e.g. g/litre or p.p. 10 ), but for most purposes it is convenient to express results in mg/litre. In water analysis, determinations (except occasionally for dissolved gases) are made on a weight/volume basis but some analysts still express results in terms of parts per million (p.p.m.). The difference between mg/litre and p.p.m. is small and for practical purposes the two units are interchtmgeable. For some calculations, the use of milli-equivalents per litre or equivalents per million (e.p.m.) has advantages but has not found much application. Hardness, whatever the constituent salts, is usually expressed as p.p.m. CaCOs (see Table 2.10). 

It follows from this, that a molar solution of sulphuric acid will contain 98.074 grams of sulphuric acid in 1 litre of solution, or 49.037 grams in 500 mL of solution. Similarly, a 0.1 M solution will contain 9.8074 grams of sulphuric acid in 1 litre of solution, and a 0.01 M solution will have 0.980 74 gram in the same volume. So that the concentration of any solution can be expressed in terms of the molar concentration so long as the weight of substance in any specified volume is known. 

Solutions of EDTA of the following concentrations are suitable for most experimental work 0.1M, 0.05M, and 0.01 M. These contain respectively 37.224 g, 18.612g, and 3.7224 g of the dihydrate per litre of solution. As already indicated, the dry analytical grade salt cannot be regarded as a primary standard and the solution must be standardised this can be done by titration of nearly neutralised zinc chloride or zinc sulphate solution prepared from a known weight of zinc pellets, or by titration with a solution made from specially dried lead nitrate. 

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