Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Linear symbolic operator

A set of linear symbolic operators drawn from differential calculus and from finite... [Pg.146]

As basic elements we consider monomer 1, monomer 2,. , monomer n, that can be polymerized to form various polymers and copolymers. As the basic operations we designate the following symbols P (polymerization), G (grafting), and C (crosslinking). Polymerization will be assumed to be linear unless operation C is specified. Most important the present group is noncommutative, and the time sequence of events must be preserved. Thus the order of the operations must be maintained. [Pg.232]

For simple flow fields the polyadic resistance formulation normally provides more insight into the physical phenomena which arise than does the equivalent symbolic operator method. In the case of a general linear shear field the undisturbed flow at infinity may be written in the form (B23)... [Pg.318]

In the nonrelativistic quantum mechanics to which we are confining ourselves, electron spin must be introduced as an additional hypothesis. We have learned that each physical property has its corresponding linear Hermitian operator in quantum mechanics. For such properties as orbital angular momentum, we can construct the quantum-mechanical operator from the classical expression by replacing p Py,Pz by the appropriate operators. Hie inherent spin angular momentum of a microscopic particle has no analog in classical mechanics, so we cannot use this method to construct operators for spin. For our purposes, we shall simply use symbols for the spin operators, without giving an explicit form for them. [Pg.282]

Postulate 2 For every physically observable variable in classical mechanics, there exists a corresponding linear, Hermitian operator in quantum mechanics. Examples are shown in Table 3.2, where the symbol indicates a quantum mechanical operator and h = h/2n. A Hermitian operator is one which satisfies Equation (3.28). [Pg.65]

In these equations n(r) is the neutron density, c (r) the density of precursors, d the fractional production of precursors per neutron produced in the core. The symbols G and P are linear integral operators, the operator G denoting absorption and transport processes while P denotes production by fission. We will assume that all the reactivity feedback takes place through the operator G, although this assumption is not essential. This assumption may be expressed in the form ... [Pg.300]

In Table I, 3D stands for three dimensional. The symbol symbol in connection with the bending potentials means that the bending potentials are considered in the lowest order approximation as already realized by Renner [7], the splitting of the adiabatic potentials has a p dependence at small distortions of linearity. With exact fomi of the spin-orbit part of the Hamiltonian we mean the microscopic (i.e., nonphenomenological) many-elecbon counterpart of, for example, The Breit-Pauli two-electron operator [22] (see also [23]). [Pg.489]

Operational sequence diagrams are flcw-charting techniques that represent any sequence of control movements and information collection activities that are executed in order to perform a task. Various activities in the diagram are represented with a symbolic notation, supported where necessary by a text description. For the majority of simple applications, OSDs assume a linear flow drawn from top to bottom with a limited degree of branching and looping. The symbols used are usually tailored to fit the type of task being studied and its level of analysis. [Pg.172]

Once plotted, a new menu bar appears with plot options. The plot can be displayed as points, connected, or as a bar chart. The data can be presented on linear or log axes, with or without grid. Text can be placed on the display in a variety of sizes and types. Lines or arrows can be drawn or areas filled. The user can edit all axis labels and titles if desired. Re-scaling is accomplished by means of the shrink and zoom options or by entering exact scale limits. Multiple curves can be annotated with keyed symbols. Plot coordinates are displayed in real time as the operator moves the mouse over the plot. [Pg.16]

By definition, a numerical matrix is a rectangular array of numbers (termed elements ) enclosed by square brackets [ ]. Matrices can be used to organize information such as size versus cost in a grocery department, or they may be used to simplify the problems associated with systems or groups of linear equations. Later in this chapter we will introduce the operations involved for linear equations (see Table 2-1 for common symbols used). [Pg.9]

Linear molecules belong to either 6 or the character tables are given in Section 9.12. The operation Ca(z) is a rotation by an angle a about the CM axis. In addition to the Mulliken notation, the spectroscopic symbols 2,n,A,... are also given. As we saw in Section 1.19, apart from spin degeneracy, 2 electronic levels are nondegenerate (A), whereas... [Pg.463]

The mn product functions (9.127) are thus transformed into linear combinations of one another by the symmetry operators of the group they therefore form a basis for some mn-dimensional representation Ty of the group. The representation T, is called the direct product (or Kronecker product) of the representations and TG this is symbolized by... [Pg.475]

The decomposition eq. (2-6) of the spin-free space FSP induces a decomposition on the Pauli-allowed portion of the Hilbert space of the Hamiltonian H of eq. (2-1). The Hamiltonian H which includes spin interactions may operate on any ket of the space Fsp V", where V is the electronic spin space. Here the symbol indicates a tensor product, so that Fsp Va consists of all spatial-spin kets which are composed of linear combinations of a simple product of a spatial ket of FSP and a spin ket of Va. The Pauli-allowed portion of the total A-electron Hilbert space of is... [Pg.5]

Akers and Williams (1969), calculating non-linear terms, noticed that the stresses are real quantities, which are determined through real quantities. That is why we ought to remember that formulae always contain the real parts of complex quantities, so that one has to bear in mind that Vik means vik + k ik), where the operation of complex conjugation is denoted by the bar above the symbol. [Pg.177]

Introduction. - Linear functionals and adjoint operators of different types are used as tools in many parts of modem physics [1]. They are given a strict and deep going treatment in a rich literature in mathematics [2], which unfortunately is usually not accessible to the physicists, and in addition the methods and terminology are unfamiliar to the latter. The purpose of this paper is to give a brief survey of this field which is intended for theoretical physicists and quantum chemists. The tools for the treatment of the linear algebra involved are based on the bold-face symbol technique, which turns out to be particularly simple and elegant for this purpose. The results are valid for finite linear spaces, but the convergence proofs needed for the extension to infinite spaces are usually fairly easily proven, but are outside the scope of the present paper. [Pg.372]

If, further, T is a linear operator defined on the L2 space , one says that an element F = F(X) belongs to the domain D(T) of the operator T, if both T and its image TT belong to L2 the set T P is then referred to as the range of the operator T. It should be observed that a bounded operator T as a rule has the entire Hilbert space as its domain—or may be extended to achieve this property—whereas an unbounded operator T has a more restricted domain. In the latter case, we will let the symbol C(T) denote the complement to the domain D(T) with respect to the Hilbert space. A function F = (X) is hence an element of C(T), if it belongs to L2, whereas this is not true for its image 7 F. [Pg.100]

Let us consider a system in equilibrium, described in the absence of external perturbations by a time-independent Hamiltonian Ho. We will be concerned with equilibrium average values which we will denote as (...), where the symbol (...) stands for Trp0... with p0 = e H"/ Vre the canonical density operator. Since we intend to discuss linear response functions and symmetrized equilibrium correlation functions genetically denoted as Xba(, 0 and CBA t,t ), we shall assume that the observables of interest A and B do not commute with Ho (were it the case, the response function %BA(t, t ) would indeed be zero). This hypothesis implies in particular that A and B are centered A) =0,... [Pg.269]

In the following table, all of the operator symbols denote the dimensionless ratio (angular momentum). (Although this is a universal practice for the quantum numbers, some authors use the operator symbols to denote angular momentum, in which case the operators would have SI units J s.) The column heading Z-axis denotes the space-fixed component, and the heading z-axis denotes the molecule-fixed component along the symmetry axis (linear or symmetric top molecules), or the axis of quantization. [Pg.26]

For polydenlate ligands, a right superscript numeral is added to the symbol k in order to indicate the number of identically bound ligating atoms in the flexiilenlure - ligand. Any doubling prefixes, such as bis-, are presumed to operate on the k locant index as well. Examples [I and 2] use tndentate chelation by the linear tetraammine ligand. /V, -bis(2-aminoethyl)-l,2-ethanediamine to illustrate these rules. [Pg.1047]

The mathematical formalism jofitjuantum mechanics is expressed in terms of linear operators, which rep resent the observables of a system, acting on a state vector which is a linear superposition of elements of an infinitedimensional linear vector space called Hilbert space. We require a knowledge of just the basic properties and consequences of the underlying linear algebra, using mostly those postulates and results that have direct physical consequences. Each state of a quantum dynamical system is exhaustively characterized by a state vector denoted by the symbol T >. This vector and its complex conjugate vector Hilbert space. The product clT ), where c is a number which may be complex, describes the same state. [Pg.353]


See other pages where Linear symbolic operator is mentioned: [Pg.146]    [Pg.146]    [Pg.248]    [Pg.310]    [Pg.1134]    [Pg.178]    [Pg.71]    [Pg.251]    [Pg.28]    [Pg.99]    [Pg.231]    [Pg.282]    [Pg.84]    [Pg.104]    [Pg.139]    [Pg.215]    [Pg.5]    [Pg.1047]    [Pg.87]    [Pg.289]    [Pg.35]    [Pg.191]    [Pg.256]    [Pg.436]    [Pg.50]    [Pg.218]    [Pg.18]    [Pg.342]   
See also in sourсe #XX -- [ Pg.146 ]




SEARCH



Linear operations

Linear operator

Operation. Symbols

Symbolic Operators

© 2024 chempedia.info