Light fundamental components

A modern laser Raman spectrometer consists of four fundamental components a laser source, an optical system for focusing the laser beam on to the sample and for directing the Raman scattered light to the monochromator entrance slit, a double or triple monochromator to disperse the scattered light, and a photoelectric detection system to measure the intensity of the light passing through the monochromator exit slit (Fig. 7). 

Even while Raman spectrometers today incorporate modem technology, the fundamental components remain unchanged. Commercially, one still has an excitation source, sample illuminating optics, a scattered light collection system, a dispersive element and a detection system. Each is now briefly discussed. 

The polarimeter is an instrument with which the essential oil chemist cannot possibly dispense. The hypothesis, first seriously enunciated by Le Bel and van t Hoff, that substances which contained an asymmetric carbon atom i.e. a carbon atom directly united to four different atoms or radicles) were capable of rotating the plane of polarisation of a beam of polarised light, has now become a fundamental theory of organic chemistry-. The majority of essential oils contain one or more components containing such a carbon atom, and so possess the power of effecting this rotation. In general, the extent to which a given oil can produce this effect is fairly constant, so that it can be used, within limits, as a criterion of the purity or otherwise of the oil. 

Raman excitation. and I2s are the high-frequency and low-frequency components of the pump light pulse. A probe pulse of frequency 12 interacts with the coherence to present the optical response of the fundamental frequency 12 + C0fsl2. (c) Fourth-order coherent Raman scattering, the optical response of the second harmonic frequency 212 + co 2I2 is modulated by the vibrational coherence. 

The fundamental scattering mechanism responsible for ROA was discovered by Atkins and Barron (1969), who showed that interference between the waves scattered via the polarizability and optical activity tensors of the molecule yields a dependence of the scattered intensity on the degree of circular polarization of the incident light and to a circular component in the scattered light. Barron and Buckingham (1971) subsequently developed a more definitive version of the theory and introduced a definition of the dimensionless circular intensity difference (CID),... 

Ackeskog et al. (1993) made the first heat transfer measurements in a scale model of a pressurized bubbling bed combustor. These results shed light on the influence of particle size, density and pressure levels on the fundamental mechanism of heat transfer, e.g., the increased importance of the gas convective component with increased pressure. 

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