Laser experimental arrangement

Figure 5.13 shows a typical experimental arrangement for obtaining the Raman spectmm of a gaseous sample. Radiation from the laser source is focused by the lens Lj into a cell containing the sample gas. The mirror Mj reflects this radiation back into the cell to increase... 

In many respects the time-resolved pump-probe technique is similar to the CW counterpart. The use of pulsed laser light permits direct probing of both the magnitude of the PA and its dynamics. The experimental arrangement is practically the same as for the CW version, i.e., both pump and probe beams are focused and overlapped onto same spot on a sample. In addition, the pump and probe pulses are synchronized so that the lime interval t between them is constant and confined to a certain time range (in our case up to 3 ns). 

The experimental arrangement for Raman spectroscopy is similar to that used for fluorescence experiments (see Figure 1.8), although excitation is always performed by laser sources and the detection system is more sophisticated in regard to both the spectral resolution (lager monochromators) and the detection limits (using photon counting techniques see Section 3.5). 

Fig. 1. Experimental arrangement commonly used in absorption spectroscopy with laser lines, tuned by a longitudinal magnetic field...

Fig. 6. Experimental arrangement for lifetime measurements by the phase-shift method, using laser excitation. The laser beam is amplitude-modulated by a Pockel cell with analysing Nicol prism and a small part of the beam is reflected by a beam splitter B into a water cell, causing Rayleigh scattering. This Rayleigh-scattered light and the fluorescence light from the absorption cell are both focused onto the multiplier cathode PMl, where the difference in their modulation phases is detected. (From Baumgartner, G., Demtroder, W., Stock, M., ref. 122)).

A description of a fast laser photolysis experimental arrangement has been given by Porter and Topp who used a 1.5 Joule, 20nsec ruby giant pulse, frequency doubled in ADP, to measure singlet lifetimes in phenantrene, pyrene and other organic molecules. 

Fig. 9. Experimental arrangement for laser photolysis, using the frequency-doubled output from a giant-pulse ruby laser as pump pulse and the wavelength continuum from a laser-induced high-temperature gas plasma as analysing pulse. (From Novak, J.R., Windsor, M.W., ref. 15 ))...

FIGURE 6.9a An experimental arrangement for observing the real-time flow of microscopic particle through the focal volume of the incident laser beam. 

Fig. 7. Experimental arrangement of a giant-pulse laser (Q-switching by dye solution). AM, active material (e.g. ruby crystal rod), F, flashlamp, Mj, 2, resonator mirrors, DC, dye cell...

Fig. 12. Experimental arrangement for the measurement of pulse widths of ultrashort pulses by the two-photon fluorescence method. B, beam splitter. Mi, 2, mirrors, DC, dye cell containing fluorescing dye solution that absorbs at half the laser wavelength, C, camera...

Figure 2.19 Experimental arrangement of laser ion source (H. ]. Dietze, ]. S. Becker and Z. Fresenius, Anal. Chem. 32 i, 490 (1985). Reproduced by permission of Springer Science and Business Media.)...

The experimental arrangement of LA-ICP-MS using a powerful laser ablation system coupled to a double-focusing sector field ICP-MS (Element, Thermo Fisher Scientific, Bremen) is shown in Figure 5.22. A cooled laser ablation chamber using two Peltier elements in serial connection... 

Figure 6.23 Experimental arrangement of solution based calibration using a micronebulizer (DS-5, CETAC) inserted in a cooled laser ablation chamber for imaging of thin sections of brain tissue. (/. S. Becker et ai, Anal. Chem. 77, 3208 (2005). Reproduced by permission of American Chemical Society.)...

Fig. 14.13 Experimental arrangement for velocity selecting and focusing the atomic beam. The rotating slotted disc and the pulsed laser beam select atoms in a velocity group, and the hexapole magnet focuses them where they cross the laser beam (from ref. 18).

Flash photolysis and laser flash photolysis are probably the most versatile of the methods in the above list they have been particularly useful in identifying very short-lived intermediates such as radicals, radical cations and anions, triplet states, carbenium ions and carbanions. They provide a wealth of structural, kinetic and thermodynamic information, and a simplified generic experimental arrangement of a system suitable for studying very fast and ultrafast processes is shown in Fig. 3.8. Examples of applications include the keton-isation of acetophenone enol in aqueous buffer solutions [35], kinetic and thermodynamic characterisation of the aminium radical cation and aminyl radical derived from N-phenyl-glycine [36] and phenylureas [37], and the first direct observation of a radical cation derived from an enol ether [38],... 

The results reported by the different groups have all been obtained with experimental arrangements that differ greatly in the types of laser used, the wavelengths, time regime- and irradiances on the sample, in the sample geometry and sample preparation, the mass spectrometers and the detection systems. The most pertinent information on the different systems that have been successfully applied to organic mass spectrometry is compiled in ref. (). 

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