Laminar microscopic flow equations

It turns out that Eq. (5-56) can also be applied to turbulent flow over a flat plate and in a modified way to turbulent flow in a tube. It does not apply to laminar tube flow. In general, a more rigorous treatment of the governing equations is necessary when embarking on new applications of the heat-trans-fer-fluid-friction analogy, and the results do not always take the simple form of Eq. (5-56). The interested reader may consult the references at the end of the chapter for more information on this important subject. At this point, the simple analogy developed above has served to amplify ouf understanding of the physical processes in convection and to reinforce the notion that heat-transfer and viscous-transport processes are related at both the microscopic and macroscopic levels. 

This expression applies to the transport of any conserved quantity Q, e.g., mass, energy, momentum, or charge. The rate of transport of Q per unit area normal to the direction of transport is called the flux of Q. This transport equation can be applied on a microscopic or molecular scale to a stationary medium or a fluid in laminar flow, in which the mechanism for the transport of Q is the intermolecular forces of attraction between molecules or groups of molecules. It also applies to fluids in turbulent flow, on a turbulent convective scale, in which the mechanism for transport is the result of the motion of turbulent eddies in the fluid that move in three directions and carry Q with them. 

Show how the Hagen-Poiseuille equation for the steady laminar flow of a Newtonian fluid in a uniform cylindrical tube can be derived starting from the general microscopic equations of motion (e.g., the continuity and momentum equations). 

Axial dispersion in packed beds, and Taylor dispersion of a tracer in a capillary tube, are described by the same form of the mass transfer equation. The Taylor dispersion problem, which was formulated in the early 1950s, corresponds to unsteady-state one-dimensional convection and two-dimensional diffusion of a tracer in a straight tube with circular cross section in the laminar flow regime. The microscopic form of the generalized mass transfer equation without chemical reaction is... 

At the microscopic, molecular level, very complex theoretical equations are required to describe the chromatographic process. These include expressions for laminar or turbulent fluid flow random walk, diffusional broadening of analyte bands in both the mobile and stationary phases and the kinetics of near-equilibrium mass transfer between the phases. Such discussions are beyond the scope of this text. 

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