Laminar limit

As velocity continues to rise, the thicknesses of the laminar sublayer and buffer layers decrease, almost in inverse proportion to the velocity. The shear stress becomes almost proportional to the momentum flux (pk ) and is only a modest function of fluid viscosity. Heat and mass transfer (qv) to the wall, which formerly were limited by diffusion throughout the pipe, now are limited mostly by the thin layers at the wall. Both the heat- and mass-transfer rates are increased by the onset of turbulence and continue to rise almost in proportion to the velocity. 

Exact Solutions to the Navier-Stokes Equations. As was tme for the inviscid flow equations, exact solutions to the Navier-Stokes equations are limited to fairly simple configurations that aHow for considerable simplification both in the equation and in the boundary conditions. For the important situation of steady, fully developed, laminar, Newtonian flow in a circular tube, for example, the Navier-Stokes equations reduce to... 

Eddy diffusion as a transport mechanism dominates turbulent flow at a planar electrode ia a duct. Close to the electrode, however, transport is by diffusion across a laminar sublayer. Because this sublayer is much thinner than the layer under laminar flow, higher mass-transfer rates under turbulent conditions result. Assuming an essentially constant reactant concentration, the limiting current under turbulent flow is expected to be iadependent of distance ia the direction of electrolyte flow. 

TABLE 5-4 Values of Limiting Nusselt Number in Laminar Flow in Closed Ducts... 

Limiting Nusselt numbers for laminar flow in annuli have been calculated by Dwyer [Nucl. Set. Eng., 17, 336 (1963)]. In addition, theoretical analyses of laminar-flow heat transfer in concentric and eccentric annuh have been published by Reynolds, Lundberg, and McCuen [Jnt. J. Heat Ma.s.s Tran.sfer, 6, 483, 495 (1963)]. Lee fnt. J. Heat Ma.s.s Tran.sfer, 11,509 (1968)] presented an analysis of turbulent heat transfer in entrance regions of concentric annuh. Fully developed local Nusselt numbers were generally attained within a region of 30 equivalent diameters for 0.1 < Np < 30, lO < < 2 X 10, 1.01 <... 

Stokes diameter is defined as the diameter of a sphere having the same density and the same velocity as the particle in a fluid of the same density and viscosity settling under laminar flow conditions. Correction for deviation from Stokes law may be necessary at the large end of the size range. Sedimentation methods are limited to sizes above a [Lm due to the onset of thermal diffusion (Brownian motion) at smaller sizes. 

Equations (22-86) and (22-89) are the turbulent- and laminar-flow flux equations for the pressure-independent portion of the ultrafiltra-tion operating curve. They assume complete retention of solute. Appropriate values of diffusivity and kinematic viscosity are rarely known, so an a priori solution of the equations isn t usually possible. Interpolation, extrapolation, even precuction of an operating cui ve may be done from limited data. For turbulent flow over an unfouled membrane of a solution containing no particulates, the exponent on Q is usually 0.8. Fouhng reduces the exponent and particulates can increase the exponent to a value as high as 2. These equations also apply to some cases of reverse osmosis and microfiltration. In the former, the constancy of may not be assumed, and in the latter, D is usually enhanced very significantly by the action of materials not in true solution. 

The fitting of limiting boundaries such as walls pros ides solutions similar to those of laminar airflow (LAP) units tir cabinets. An increase in the supply and exhaust supply rates provides a solution similar to ventilated booths (.see Section 10,. ). 

Before the size of the flammable portion of a vapor cloud can be calculated, the flammability limits of the fuel must be known. Flanunability limits of flammable gases and vapors in air have been published elsewhere, for example, Nabert and Schon (1963), Coward and Jones (1952), Zabetakis (1965), and Kuchta (1985). A summary of results is presented in Table 3.1, which also presents autoignition temperatures and laminar burning velocities referred to during the discussion of the basic concepts of ignition and deflagration. 

Gas or Vapor Flammability Limits (vol. %) Flash Point rc) Autoignition Temperature rc) Laminar Burning Velocity (mis)... 

Such effects principally cannot be observed in multi band detectors such as a UV diode array detector or a Fourier transform infrared (FTIR) detector because all wavelengths are measured under the same geometry. For all other types of detectors, in principle, it is not possible to totally remove these effects of the laminar flow. Experiments and theoretical calculations show (8) that these disturbances can only be diminished by lowering the concentration gradient per volume unit in the effluent, which means that larger column diameters are essential for multiple detection or that narrow-bore columns are unsuitable for detector combinations. Disregarding these limitations can lead to serious misinterpretations of GPC results of multiple detector measurements. Such effects are a justification for thick columns of 8-10 mm diameter. 

Estimation of the pressure-drop The system is designed to work within a given pressure limit thus, one needs a relation giving the pressure-drop in the column (per unit length). Darcy s law gives the relation of AP/L versus the mobile phase velocity u. However, the Kozeny-Carman equation is best adapted for laminar flows as described ... 

The original Reynolds analogy involves a number of simplifying assumptions which are justifiable only in a limited range of conditions. Thus it was assumed that fluid was transferred from outside the boundary layer to the surface without mixing with the intervening fluid, that it was brought to rest at the surface, and that thermal equilibrium was established. Various modifications have been made to this simple theory to take account of the existence of the laminar sub-layer and the buffer layer close to the surface. 

Experiments have been carried out on the mass transfer of acetone between air and a laminar water jet. Assuming that desorption produces random surface renewal with a constant fractional rate of surface renewal, v, but an upper limit on surface age equal to the life of the jet, r, show that the surface age frequency distribution function, 4>(t), for this case is given by ... 

Pressure drop measurements. For the majority of experiments the instrumentation was relatively similar. Due to limitations associated with the small size of the channels, pressures were not measured directly inside the micro-channels. To obtain the channel entrance and exit pressures, measurements were taken in a plenum or supply line prior to entering the channel. It is insufficient to assume that the friction factor for laminar compressible flow can be determined by means of analytical predictions for incompressible flow. 

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