Iron deposits

If deposits are minimized, the areas where caustic can be concentrated is reduced. To minimize the iron deposition in 6.895-12.07 x 10 Pa boilers, specific polymers have been designed to disperse the iron and keep it in the bulk water. As with phosphate precipitation and chelant control programs, the use of these polymers with coordinated phosphate—pH treatment improves deposit control. 

High Water Velocities. The abiUty of high water velocities to minimize fouling depends on the nature of the foulant. Clay and silt deposits are more effectively removed by high water velocities than aluminum and iron deposits, which are more tacky and form interlocking networks with other precipitates. Operation at high water velocities is not always a viable solution to clay and silt deposition because of design limitations, economic considerations, and the potential for erosion corrosion. 

In some reports Gallionella have been associated with manganese and iron deposits that also contain chloride. It has been postulated that deep undercut pits on stainless steels (especially at welds) containing such deposits are indirectly caused by these bacteria, since the iron-manganese deposition can be accelerated by Gallionella. In spite of numerous literature citings, however, evidence for stainless steel... 

Four pilot plant experiments were conducted at 300 psig and up to 475°C maximum temperature in a 3.07-in. i.d. adiabatic hot gas recycle methanation reactor. Two catalysts were used parallel plates coated with Raney nickel and precipitated nickel pellets. Pressure drop across the parallel plates was about 1/15 that across the bed of pellets. Fresh feed gas containing 75% H2 and 24% CO was fed at up to 3000/hr space velocity. CO concentrations in the product gas ranged from less than 0.1% to 4%. Best performance was achieved with the Raney-nickel-coated plates which yielded 32 mscf CHh/lb Raney nickel during 2307 hrs of operation. Carbon and iron deposition and nickel carbide formation were suspected causes of catalyst deactivation. 

Anonymous Several speakers found iron deposited on the nickel catalyst. Where is the iron believed to come from, and what steps will be taken to prevent the deposition ... 

Dr. Moeller In our plant, we investigated our catalyst after 4000 and 5000 hrs of operation and we found no trace of iron on our catalysts. But we know that if you take no precautions against iron carbonyl formation, then you will destroy some part of your activity by iron deposition on your catalyst. And we found that the iron carbonyl is formed mainly at the mild steel tube walls or at the tube in the temperature range of 150°-200°C. So, if you enter this range and you have to heat up your gas, which has a high CO content and steam in it, you have to... 

A further problem is FW line iron deposits, which may be produced where soluble iron is present. The iron precipitates as a result of heat and the presence of trace amounts of oxygen. The reactions under these circumstances include the following ... 

Low iron levels in the feed are essential to avoid damage to the electrode from iron deposition. This is achieved only by correct condensate line corrosion treatment. Polymer dispersants should be fed direct to the feed line and boiler to ensure particulate iron is effectively removed with the BD. 

Morris, C.J., Blake, D.R., Wainwright, A.C. and Steven, M.M. (1986). Relationship between iron deposits and tissue damage in the synovium an ultrastructural study. Ann. Rheum. Dis. 45, 21-26. 

Zeimer, R, Belkin, M., Leitersdorff, E. and Rachmilewitz, E.A. (1978). A non-invasive method for the evaluation of tissue iron deposition in beta-thalassemia major. J. Lab. Clin. Med. 91, 24-31. 

A certain carbonate species with magnetite and iron deposits microorganisms could have been involved in its formation. 

However, ferritins isolated from the bacterium Pseudomonos aeruginosa (Mann et ah, 1986) and from the chiton Acanthopleura hirtosa (St. Pierre et ah, 1990) have iron cores of limited crystallinity, despite having P Fe ratios of around 1 40, perhaps suggesting that core crystallinity is influenced by the rate of iron deposition as well as by the composition of the medium. The way in which phosphate may influence core development is discussed below. 

Although many animal models for iron overload exist, some mimicking certain aspects of HH, the 32-microglobulin knockout mouse is of special interest as it revealed for the first time crucial aspects of the pathogenesis of human HH in an animal model, and also because it underlines the important links between iron metabolism and the immune system. Hepatic iron overload in 32-microglobulin ( 32m)-deficient mice appeared to be similar to that found in HH, with pathological iron depositions occurring predominantly in liver parenchymal cells (de Sousa et ah,... 

Filamentous spirally curled organisms, (Grypania) Major land masses shallow seas, Iron deposits, BIFs 0.1%... 

It is known that erythrocytes from patients with sickle cell anemia contain various types of abnormal iron deposits [398], which could be the origin of the overproduction of oxygen radicals in these cells. Indeed, Hebbel et al. [399] has showed that sickle erythrocytes spontaneously generate approximately twice as much superoxide as normal erythrocytes. Later on, it has been shown that these cells are also able to generate hydroxyl radicals catalyzed by three types of iron, preexisting free iron, free iron released during oxidative stress, and iron that cannot be chelated with desferrioxamine [400]. 

Fig. 1. Map showing location of the study sites relative to Hogarth and Caland pit lakes. Black outline represents original lake level (prior to draining for mining). Inset shows location of the Steep Rock iron deposit within Ontario.

Leo, G.W. Genq, M.A. 1986. Geology and iron deposits of the amli area, Balikesir Province, MTA, Turkiye. 

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