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Iron bond formation

Although a variety of oxidizing agents are available for this transformation it occurs so readily that thiols are slowly converted to disulfides by the oxygen m the air Dithiols give cyclic disulfides by intramolecular sulfur-sulfur bond formation An example of a cyclic disulfide is the coenzyme a lipoic acid The last step m the laboratory synthesis of a lipoic acid IS an iron(III) catalyzed oxidation of the dithiol shown... [Pg.650]

Ceramic bond formation and grain growth by diffusion are the two prominent reactions for bonding at the high temperature (1100 to 1370°C, or 2000 to 2500°F, for iron ore) employed. The minimum temperature required for sintering may be measured by modern dilatometry techniques, as well as by differential scanning calorimetry. See Compo et al. [Powder Tech., 51(1), 87 (1987) Paiticle Characterization, 1, 171 (1984)] for reviews. [Pg.1902]

Martin, Padron, and coworkers have reported on the scope and limitations of the use of iron(lll) halides as effective catalysts in the coupling of alkenes or acetylenes with aldehydes to achieve a wide variety of useful synthetic transformations. All these reactions are shown in Scheme 10, which serves as a guide through the aliphatic C-C bond formation section [27]. [Pg.8]

Scheme 15 Iron(III)-mediated synthesis of alkenyl halides via direct C-C bond formation of benzylic alcohols and aryl alkynes... Scheme 15 Iron(III)-mediated synthesis of alkenyl halides via direct C-C bond formation of benzylic alcohols and aryl alkynes...
Scheme 36 Iron-catalyzed C sp )-C sp ) bond formation through C sp )- functionalization... Scheme 36 Iron-catalyzed C sp )-C sp ) bond formation through C sp )- functionalization...
Abstract Organic syntheses catalyzed by iron complexes have attracted considerable attention because iron is an abundant, inexpensive, and environmentally benign metal. It has been documented that various iron hydride complexes play important roles in catalytic cycles such as hydrogenation, hydrosilylation, hydro-boration, hydrogen generation, and element-element bond formation. This chapter summarizes the recent developments, mainly from 2000 to 2009, of iron catalysts involving hydride ligand(s) and the role of Fe-H species in catalytic cycles. [Pg.27]

C-C and C-E (E = heteroatom) bond formations are valuable reactions in organic synthesis, thus these reactions have been achieved to date by considerable efforts of a large number of chemists using a precious-metal catalysts (e.g., Ru, Rh, and Pd). Recently, the apphcation range of iron catalysts as an alternative for rare and expensive transition-metal catalysts has been rapidly expanded (for recent selected examples, see [12-20, 90-103]). In these reactions, a Fe-H species might act as a reactive key intermediate but also represent a deactivated species, which is prepared by p-H elimination. [Pg.52]

As an alternative method for the C-C bond formation, oligomerization and polymerization reactions of olefins catalyzed by a bis(imino)pyridine iron complex are also well known (Scheme 40) [121-124]. [Pg.58]

It is worth noting that the N—N bond formation via N202 intermediate has already been postulated on the basis of spectroscopic results to take place on metallic surfaces [79,80] and in biological systems containing copper [81,82,83] and iron [84] as well. [Pg.59]

An example of an iron-catalyzed C-C bond formation reaction was reported in 2001 [89]. Treatment of propargyl sulfides 87 with trimethylsilyldiazomethane in the presence of 5 mol% FeCl2(dppb) gave substituted homoallenylsilanes 88 in good to moderate yields (Scheme 3.43). The silanes 88d and 88e, which bear two centers of chirality, were obtained as 1 1 mixtures of diastereomers. Slight diastereoselectivity (2 1) was seen for the formation 88f, which is an axially chiral allene with a sterogenic center. [Pg.111]

The iron-mediated construction of the carbazole framework proceeds via consecutive C-C and C-N bond formation as key steps [70,71]. The C-C bond formation is achieved by electrophilic substitution of the arylamine with a tricarbonyliron-coordinated cyclohexadienyl cation. The parent iron complex salt for electrophilic substitutions, tricarbonyl[/j -cyclohexadienylium] iron tetrafluoroborate 6a, is readily available by azadiene-catalyzed complexation and subsequent hydride abstraction (Scheme 9). [Pg.122]

An oxidative cyclization leads to the C-N bond formation and furnishes the carbazole nucleus. The three modes of the iron-mediated carbazole synthesis differ in the procedures which are used for the oxidative cyclization [77,78]. [Pg.122]

The carbazole construction using iron-mediated arylamine cydization for the C-N bond formation was applied to the synthesis of 4-deoxycarbazomycin B [84]. The synthesis of this model compound demonstrates also the course of the two key steps which are involved in the iron-mediated carbazole synthesis (Scheme 10). [Pg.123]

Despite many applications of the iron-mediated carbazole synthesis, the access to 2-oxygenated tricyclic carbazole alkaloids using this method is limited due to the moderate yields for the oxidative cyclization [88,90]. In this respect, the molybdenum-mediated oxidative coupling of an arylamine and cyclohexene 2a represents a complementary method. The construction of the carbazole framework is achieved by consecutive molybdenum-mediated C-C and C-N bond formation. The cationic molybdenum complex, required for the electrophilic aromatic substitution, is easily prepared (Scheme 23). [Pg.132]


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See also in sourсe #XX -- [ Pg.481 ]




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Iron formation

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