Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Ionic organic synthesis

From Section 2.1 it has become very clear that the synthesis of an ionic liquid is in general quite simple organic chemistry, while the preparation of an ionic liquid of a certain quality requires some know-how and experience. Since neither distillation nor crystallization can be used to purify ionic liquids after their synthesis (due to their nonvolatility and low melting points), maximum care has to be taken before and during the ionic liquid synthesis to obtain the desired quality. [Pg.21]

In this context it is important to note that the detection of this land of alkali cation impurity in ionic liquids is not easy with traditional methods for reaction monitoring in ionic liquid synthesis (such as conventional NMR spectroscopy). More specialized procedures are required to quantify the amount of alkali ions in the ionic liquid or the quantitative ratio of organic cation to anion. Quantitative ion chromatography is probably the most powerful tool for this kind of quality analysis. [Pg.27]

Chloroaluminate(III) ionic liquid systems are perhaps the best established and have been most extensively studied in the development of low-melting organic ionic liquids with particular emphasis on electrochemical and electrodeposition applications, transition metal coordination chemistry, and in applications as liquid Lewis acid catalysts in organic synthesis. Variable and tunable acidity, from basic through neutral to acidic, allows for some very subtle changes in transition metal coordination chemistry. The melting points of [EMIM]C1/A1C13 mixtures can be as low as -90 °C, and the upper liquid limit almost 300 °C [4, 6]. [Pg.43]

Although a great deal of excitement has surrounded the use of ionic liquids as solvents for organic synthesis, the rational synthesis of inorganic and organometallic compounds in ionic liquids has remained largely unexplored. [Pg.289]

Ionic liquids hold as much promise for inorganic and organometallic synthesis as they do for organic synthesis. Their lade of vapor pressure has already been exploited [13], as have their interesting solubility properties. The field can only be expected to accelerate from its slow beginnings. [Pg.293]

Kitazume T. Organic Synthesis in Ionic Liquids Kagaku Kogyo 2000 51 437-444... [Pg.303]

Dell C. P. Cycloaddition in Synthesis Contemporary Organic Synthesis 1997 4 87 Keywords natural products, metal catalyzed, asymmetric reactions, Ionic reactions, transannular reactions, tethered reactions, tandem reactions, benzo-qulnones, quinodimethanes, hefero-Dlels-Alder reactions... [Pg.313]

Verkade JG (2003) P(RNCH2CH2)3N Very Strong Non-ionic Bases Useful in Organic Synthesis. [Pg.239]

Miao, W. Chan, T.H. (2003) Exploration of Ionic Liquids as Soluble Supports for Organic Synthesis. Demonstration with a Suzuki Coupling Reaction. Organic Letters, 5, 5003-5005. [Pg.185]

Catalysis at interfaces between two immiscible liquid media is a rather wide topic extensively studied in various fields such as organic synthesis, bioenergetics, and environmental chemistry. One of the most common catalytic processes discussed in the literature involves the transfer of a reactant from one phase to another assisted by ionic species referred to as phase-transfer catalyst (PTC). It is generally assumed that the reaction process proceeds via formation of an ion-pair complex between the reactant and the catalyst, allowing the former to transfer to the adjacent phase in order to carry out a reaction homogeneously [179]. However, detailed comparisons between interfacial processes taking place at externally biased and open-circuit junctions have produced new insights into the role of PTC [86,180]. [Pg.231]

Varvoglis A (2003) Preparation of Hypervalent Iodine Compounds. 224 69-98 Verkade JG (2003) P(RNCH2CH2)3N Very Strong Non-ionic Bases Useful in Organic Synthesis. 223 1-44... [Pg.234]

Organic Synthesis Using Microwaves and Supported Reagents 6.2.7.6 Solvent-free Synthesis of Ionic Liquids... [Pg.212]

Room-temperature Ionic Liquids (RTIL) - Synthesis and Applications in Organic Synthesis under the Action of Microwaves... [Pg.287]

Limited studies of the germanium and tin hydride analogs of the silicon hydrides show that they share this ability to function as hydride sources in ionic hydrogenations however, their relatively greater reactivity toward acids appears to restrict their practical applications in organic synthesis.24,25... [Pg.6]

Ionic and Organometallic-Catalyzed Organosilane Reductions is intended to be a useful, easily read tool for all practitioners of organic synthesis. [Pg.983]


See other pages where Ionic organic synthesis is mentioned: [Pg.147]    [Pg.245]    [Pg.28]    [Pg.153]    [Pg.945]    [Pg.245]    [Pg.182]    [Pg.293]    [Pg.353]    [Pg.375]    [Pg.132]    [Pg.207]    [Pg.267]    [Pg.224]    [Pg.207]    [Pg.77]    [Pg.297]    [Pg.182]    [Pg.18]    [Pg.61]    [Pg.66]    [Pg.72]    [Pg.358]    [Pg.359]    [Pg.51]    [Pg.109]    [Pg.182]    [Pg.151]    [Pg.349]    [Pg.27]    [Pg.198]   
See also in sourсe #XX -- [ Pg.265 ]




SEARCH



Ionic synthesis

Organic ionicity

© 2024 chempedia.info