Coordination chemistry transition metals

Link, T. A. Hatzfeld, O. M. Saynovits, M. In Bioinorganic Chemistry— Transition Metals in Biology and their Coordination Chemistry Trautwein, A. X., Ed. Wiley-VCH Weinheim, 1997, 312-325. 

Trautheim AX (1997) Bioinorganic chemistry transition metals in biology and their coordination chemistry. Wiley-VCH, Weinheim... 

Trautwein, A. X. Bioinorganic Chemistry—Transition Metals in Biology and their Coordination Chemistry 1997, Wiley-VCH Weinheim. 

This book should be of interest to academic and industrial researchers involved in the fields of organometallic, coordination and bioinorganic chemistry, transition metal catalysis, and organic synthesis. 

The stabilization of these heteroaldehydes and -ketones by coordination to transition metals is the subject of this review. Many problems connected with the high reactivity of these heterocarbonyl compounds can be circumvented by using their transition metal complexes. The chemistry of organo-sulfur and organoselenium transition metal complexes in more general terms30,31 and some aspects of thio- and selenoaldehydes and -ketones as... 

The study of species in which ethylene is coordinated to transition metal centres holds great interest in areas of catalytic and polymerization chemistry (7). The bonding of the ethylene ligand to the metal centre in such species has been compared to that of the dihydrogen complexes described above (14,15,22). Photolysis of chromium hexacarbonyl, Cr(CO)6, in conventional solvents in the presence of dissolved ethylene gas is known to lead initially to a highly labile species in which one CO ligand is replaced by ethylene. Further photolysis leads to a more stable compound which contains two ethylene ligands trans to each other across the metal centre (25), equation 3. The conventional synthesis is experimentally difficult the two photochemical... 

How does the gas-phase chemistry of a bare and, therefore, highly coordinatively unsaturated transition metal ion compare to its solution counterpart As a representative example, Beauchamp and coworkers proposed Scheme I for the dehydrogenation of butane by Ni [2]. 

Keywords. Electrospray ionization, Ion-molecule chemistry, Transition-metal coordination compounds, Organometallic catalysis... 

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