Introduction to macromolecules

L. Mandelkern, An Introduction to Macromolecules, Springer-Verlag, New York (1972). 

Taramae, N., Hiroguchi, M. Tanaka, S. (1982) Bull. Chem. Soc. Japan, 55, 2097-2100. Tonelli, A. E. Srinivasarao, M. (2001) Polymers from the Inside Out An Introduction to Macromolecules, New York Wiley-Interscience. 

Mandelkern, L. L. "An Introduction to Macromolecules" Springer-Verlag New York, 1972. 

ToneUi, Alan E. (2001). Polymers from the Inside Out An Introduction to Macromolecules. New York Wiley-Interscience. 

He is author of Crystallization of Polymers, first edition, published by McGraw-Hill in 1964. He is also author of Introduction to Macromolecules, first edition 1972, second edition 1983, published by Springer-Verlag. 

Depending on the chemical structure of the starting monomers, their mutual quantitative relationship and the method of conducting the reaction one can obtain copolymers of different composition and different properties. Physicochemical properties of copol5miers depend on their composition, but in most cases the relationship is not additive. Often the introduction to macromolecule during the copolymerization of a relatively small amount of another monomer provides the polymer with completely new properties. As an example one can cite a copolymer of isobutylene with a small amount (0.6-3. 0%) of isoprene. In this way the formed polymer gets properties of rubber and can be vulcanized with sulfur, while the pol5dsobutylene does not have such a capacity. 

Mandelkern, L., An Introduction to Macromolecules , 2nd edn., Springer-Verlag, New York, 1983. For the beginning student, an introduction to the structure and properties of macromolecular substances. 

TonelU, A.E., Polymers From the Inside Out—An Introduction to Macromolecules, John Wiley Sons, Inc., 2001. 

Morawitz, H., Macromolecules in Solution, Interscience, New York, 1965. Richards, E. G., An Introduction to the Physical Properties of Large Molecules in Solution, Cambridge University Press, Cambridge, 1980. 

BOVEY, F. A. and winslow, f. h. (Eds.), Macromolecules—An introduction to polymer science. Academic Press, New York (1979)... 

As already stressed in the Introduction to this article, the use of organic plastics as biomaterials is expected to evolve in a natural way towards the utilization of increasingly higher quantities of inorganic polymers, because of the limitations inherently present in the first class of materials which seem to be absent or reduced in the second type of macromolecules. 

K. S. Schmitz, An Introduction to Dynamic Light Scattering by Macromolecules. Academic... 

As we mentioned in the introduction to this chapter, carbon has the ability to bond to itself in long and complex chains. These large molecules, called macromolecules, may have... 

A short introduction in the application of MT techniques has been given in Section 3.3. Mechanisms of MT are described by interactions between two separated pools of protons, one of them consisting of free protons with long transverse relaxation time (pool A, 7 2 > 10 ms) and the other of protons bound to macromolecules with an inherent short transverse relaxation time (pool B, T2< 10 ps). By selective saturation of the magnetization of the protons in pool B it is possible to reduce signal intensity of pool A and therefore to draw conclusions about the amount of protons present in pool B. 

Bovey FA, Winslow FH (eds) (1979) Macromolecules an introduction to polymer science. Academic, New York... 

Polymeric compounds (macromolecules) do not fall easily into either of these categories, and for them a subsystem of macromolecular nomenclature has been developed. A brief introduction to macromolecular nomenclature is presented in Chapter 6. Non-stoichiometric compounds also are clearly difficult to name within the constraints of a description which generally implies localised electron-pair bonds or specific atom-atom interactions. For these, further systems of nomenclature are in the process of development. Finally, oxoacids and inorganic rings and chains have their own nomenclature variants. 

Trinitrotoluene (TNT)-based aromatic diamines are used for the preparation of substituted polyimides. Interest in substituted polyimides is very understandable due to the known poor tractability of unsubstimted aromatic polyimides [1—4], As is known, the introduction of methoxy substituents to macromolecules of polyimides enhances their solubility in organic solvents [5]. One of the simplest TNT derivatives, 3,5-diaminoanisole, is used for the preparation of methoxy-substituted polyimides [6]. 

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