Interference of Hydrogen Peroxide Dissociation and Substrate Oxidation Reactions

5 INTERFERENCE OF HYDROGEN PEROXIDE DISSOCIATION AND SUBSTRATE OXIDATION REACTIONS 

The examples given below, for instance, methane oxidation to methanol and propylene oxidation to propylene oxide, demonstrate experimental approaches to the study of interfering reaction dynamics and, with the help of the determinant equation, the potential abilities of reaction media are assessed and the type of chemical interference determined. 

In the chemical system studied biosimulator catalyzes two interrelated (catalase and monooxygenase) reactions, which are synchronized and proceed according to the following mechanisms  

Both reactions (1) and (2) in the scheme proceed via general PPFe3+OH/AlMgSi intermediating compound, which certainly is the transferring agent for the inductive action of the primary reaction to the secondary reaction. The determinant calculated by equation (2.17), which allows quantitative identification of an interaction between reactions, equals  

However, presenting the interference picture via a diagram has several principal disadvantages 1. diagrams do not show how coherence is implemented 2. phase shifts may not be shown 3. maxima and minima in accumulation of products of both reactions and 4. the absence of asymptotic curves. 

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Interference of Hydrogen Peroxide Dissociation and Substrate Oxidation Reactions... 

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