Hydrogen peroxide dissociative

Both acids are detected in the atmosphere. Hydrogen peroxide dissociates into OH radicals by absorption of light below 3200 A [see Section V11—61... 

Various types of possible interactions between reactions are discussed. Some of them are united by the general idea of chemical reaction interference. The ideas on conjugated reactions are broadened and the determinant formula is deduced the coherence condition for chemical interference is formulated and associated phase shifts are determined. It is shown how interaction between reactions may be qualitatively and quantitatively assessed and kinetic analysis of complex reactions with under-researched mechanisms may be performed with simultaneous consideration of the stationary concentration method. Using particular examples, interference of hydrogen peroxide dissociation and oxidation of substrates is considered. 

INTERFERENCE OF HYDROGEN PEROXIDE DISSOCIATION AND SUBSTRATE OXIDATION REACTIONS... 

Interference of Hydrogen Peroxide Dissociation and Substrate Oxidation Reactions... 

The kinetics and mechanisms of the majority of these reactions were also studied. It is shown that successful application of hydrogen peroxide is promoted by a combination of high induction properties and effectiveness and specificity of action in it, accompanied by the harmlessness of hydrogen peroxide dissociation products. 

Analyzing the dependencies deduced, it may be concluded that the yield of oxygen formed at hydrogen peroxide dissociation decreases with the increase in methanol yield. 

Kinetics and the Mechanism of Synchronous (Interfering) Reactions of Hydrogen Peroxide Dissociation and Oxidation of Substrates in the Gas Phase... 

Actually, from an energy-gaining position, it is desirable to carry out such reactions conjugated with another reaction, which can be hydrogen peroxide dissociation. 

The scope of the experimental data allowed the determination of several kinetic regularities, among which the synchronized curves (Figure 5.2) are of special interest which demonstrate the induction effect of the primary reaction (hydrogen peroxide dissociation) on the secondary (inducible) reaction of CH4 hydroxylation. 

HYDROGEN PEROXIDE DISSOCIATION INTHE LIQUID PHASE... 

Figure 6.1 The mechanism of hydrogen peroxide dissociation in the Fenton system. The sketch is based on the data by Kazarnovsky [7], Haber-Weiss [9], Bard [6] and Uri [25].

In the framework of the theory of elementary open catalytic system self-development suggested by Rudenko [59] evolutionary changes in homogeneous catalytic systems based on hydrogen peroxide dissociation are indicated [60], Hence, it is suggested that formation of amino acids, for example, is associated with the transformation of components in the... 

In alkaline solution, hydrogen peroxide dissociates (Figure 2.4). 

The perhydroxyl ion, HO2, is formed by hydrogen peroxide dissociation in base ... 

This explanation, however, is no longer tenable. There is no absolute certainty about the nature of the bleaching action but it is believed that the perhydroxyl ion is the active species. These ions are formed when hydrogen peroxide dissociates in the following manner ... 

Oxygen dissociation 2. Peroxyl dissociation 3. Hydrogen peroxide dissociation... 

It has been observed that the addition of hydrogen peroxide to a reaction mixture containing [Co(NH3)5Cl] ion and hydroxide ion reduces the rate of the base hydrolysis. Hydrogen peroxide dissociates as... 

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