Interface science

The reports were that water condensed from the vapor phase into 10-100-/im quartz or pyrex capillaries had physical properties distinctly different from those of bulk liquid water. Confirmations came from a variety of laboratories around the world (see the August 1971 issue of Journal of Colloid Interface Science), and it was proposed that a new phase of water had been found many called this water polywater rather than the original Deijaguin term, anomalous water. There were confirming theoretical calculations (see Refs. 121, 122) Eventually, however, it was determined that the micro-amoimts of water that could be isolated from small capillaries was always contaminated by salts and other impurities leached from the walls. The nonexistence of anomalous or poly water as a new, pure phase of water was acknowledged in 1974 by Deijaguin and co-workers [123]. There is a mass of fascinating anecdotal history omitted here for lack of space but told very well by Frank [124]. 

Fig. XI-13. Adsorption isotherms for SNBS (sodium p-3-nonylbenzene sulfonate) (pH 4.1) and DPC (dodecyl pyridinium chloride) (pH 8.0) on mtile at approximately the same surface potential and NaCl concentration of O.OlAf showing the four regimes of surfactant adsorption behavior, from Ref. 175. [Reprinted with permission from Luuk K. Koopal, Ellen M. Lee, and Marcel R. Bohmer, J. Colloid Interface Science, 170, 85-97 (1995). Copyright Academic Press.]...

D. W. Dwight, M. E. Counts, and J. P. Wightman, Colloid and Interface Science, Vol. ni. Adsorption, Catalysis, Solid Surfaces, Wetting, Surface Tension, and Water, Academic, New York, 1976, p. 143. 

Manne S and Gaub FI E 1995 Molecular organization of surfactants at solid-liquid interfaces Science 270 1480-3... 

Institute for Studies of Interface Science, FacuJies Universitaires Noire Dame de la Paix,... 

Adler, P.M., 1981. Heterocoagulation in shear flow. Journal of Colloid and Interface Science, 83, 106-115. 

Synchrotron Radiation Research Advances in Surface and Interface Science, Vol. I (Ed. R.Z. Bachrach), Plenum, New York 1992. 

G.-Q. Lu, and A. Wieckowski, Heterogeneous Electrocatalysis A Core field of Interfacial Science, Current opinion in Colloid and Interface Science 5, 95 (2000). 

Questions similar to these are being researched by chemical engineers who are active in the broad field of colloid and interface science. Future contributions by chemical engineers may be the key to the success of the EPID concept in visual display applications. 

Rubio-Hernandez F.J., Carrique F., Ruiz-Reina E. The primary electroviscous effect in colloidal suspensions. Advances in Colloid and Interface Science 107 (2004) 51-... 

Rubio-Hernandez F. J., Ruiz-Reina E., and Gomez-Merino A. I. Primary Electroviscous Effect with a Dynamic Stern Layer Low Ka Results. Journal of Colloid and Interface Science 226,180-184 (2000). 

Gaunt, J. A. Knight, A. E. Windsor, S. A. and Chechik, V. (2005). Stability and quantum yield effects of small molecules additives on solutions of semiconductor nanoparticles. /. Colloid and Interface Science, 290 (2), 437-443. 

V Turco Liveri. In JE Desnoyers, F Franks, G. Gritzner, LG Hepler, H Ohtaki, eds. Current Topics in CoUoid and Interface Science. Vol 3. Trivandrnm Research Trends, 1999, pp 65-74. 

Chul, M Phillips, R McCarthy, M, Measurement of the Porous Microstructure of Hydrogels by Nuclear Magnetic Resonance, Journal of Colloid and Interface Science 174, 336, 1995. Cohen, Y Ramon, O Kopeknan, IJ Mizrahi, S, Characterization of Inhomogeneous Polyacrylamide Hydrogels, Journal of Polymer Science Part B Polymer Physics 30, 1055, 1992. Cohen Addad, JP, NMR and Statistical Structures of Gels. In The Physical Properties of Polymeric Gels Cohen Addad, JP, ed. Wiley Chichester, UK, 1996 39. 

Hinton, DP Johnson, CS, Diffusion Coefficients, Electrophoretic Mobilities, and Morphologies of Charged Phospholipid Vesicles by Pulsed Field Gradient NMR and Electron Microscopy, Journal of Colloid and Interface Science 173, 364, 1995. 

Israelachvili, J, Intermolecular and Surface Forces, 2nd ed. Academic Press London, 1992. Ivory, CF, Transient Electrophoresis of a Dielectric Sphere, Journal of Colloid and Interface Science 100, 239, 1984. 

Jansons, KM Phillips, CG, On the Application of Geometric Probability Theory to Polymer Networks and Suspensions, I, Journal of Colloid and Interface Science 137, 75, 1990. 

Ohshima, H Kondo, T, Electrophoretic Mobility and Donnan Potential of a Large Colloidal Particle with a Surface Charge Layer, Journal of Colloid and Interface Science 116, 305, 1987. O Neil, GA Torkelson, JM, Modeling Insight into the Diffusion-Limited Cause of the Gel Effect in Free Radical Polymerization, Macromolecules 32,411, 1999. 

Phillips, RJ Deen, WM Brady, JF, Hindered Transport in Fibrous Membranes and Gels Effect of Solute Size and Fiber Configuration, Journal of Colloid and Interface Science 139,363, 1990. 

Rikvold, PA Stell, G, D-Dimensional Interpenetrable-Sphere Models of Random Two-Phase Media Micro structure and an Application to Chromatography, Journal of Colloid and Interface Science 108, 158, 1985. 

Stigter, D, The Charged Colloidal Cylinder with a Gouy Double Layer, Journal of Colloid and Interface Science 53, 296, 1975. 

Weirsema, PH Loeb, AL Overbeek, JTG, Calculation of the Electrophoretic Mobility of a Spherical Colloid Paricle, Journal of Colloid and Interface Science 22, 78, 1966. 

Zhou, Z Chu, B, Light-Scattering Study on the Association Behavior of Triblock Polymers of Ethylene Oxide and Propylene Oxide in Aqueous Solution, Journal of Colloid and Interface Science 126, 171, 1988. 

C. B. Duke and E. W. Plummer (eds), Frontiers in Surface and Interface Science, Elsevier, Amsterdam, 2002. 

N Garti, A Aserin. Double emulsions stabilized by macromolecular surfactants. Advances in colloid and interfaces science 65 37-69, 1996. 

Chiu G, Meehan EJ. 1977. Monodisperse sulfur sols from the air oxidation of hydrogen sulfide solutions. Journal of Colloid and Interface Science 62 1-7. 

We acknowledge with gratitude the financial support of the Office of Naval Research for the radiation sensitive polymer research and the University of Massachusetts Institute for Interface Science and IBM for the surface active polymer research. 

Vincent, B., Luckham, P.F. and Waite, F.A. (1980) The effect of free polymer on the stability of sterically stabilized dispersions. Journal of Colloid and Interface Science, 73 (2), 508-521. 

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