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Influencer relationships

The reactor was charged with 37 elastomer which was Insoluble In the chromatographic mobile phase. Thus, the relationship between calculated and measured solids contents should have, and did, differ by at least 37 at low conversions. Expected formation of Insoluble graft polymer would also have Influenced relationship between calculated and measured total solids. [Pg.83]

Finally, the expression of the inflnence operator corresponds to the alternate way of writing the influence relationship between activity and chemical potential ... [Pg.215]

Statistics is not always applicable. The influence relationship in physical chemistry is classically introduced (Atkins 1998) as a definition of the activity in arguing that it obeys Boltzmann statistics. This is generally a perfectly acceptable model as, in a gas or a liquid, thermal agitation indnces flnctuations in the system that can be treated in terms of probability of events. However, there are cases in which molecules are immobilized in a lattice or on a surface and which still obey the capacitive relationship shown in Equation D3.9. This clearly means that the powerful tool and concept of probability cannot be used in all cases. [Pg.215]

The question that is tackled now is the relationship between the pole constitutive properties and the corresponding dipole property. To derive this dipole constitutive relationship, the influence relationships introduced in Section 7.1 at the level of the poles need to be combined with the poles-dipole connections between variables. We take the case of the capacitive relationships for detailing the model the other cases of inductive relationships being similar will be merely given without justification. [Pg.235]

The conductive influence relationships have been introduced in Section 7.1 in Equations 7.5 and 7.6 they are recalled hereafter for the case of a conduction ensured by exchange by flows. [Pg.237]

Integration of this differential equation provides the final result that was sought and that expresses the mutual influence relationship for a physical chemical dipole. [Pg.246]

For compounds with log Kq between 1 and 5 correlations between Kqw and K( are generally linear. When deviations from linear behaviour occur, metabolic transformation has to be considered as the principal reason for this effect, since all other factors influencing relationships apply only to... [Pg.120]

In practice, defining and controlling life-cycle costs is difficult. The future behavior of materials is often uncertain, as are the future uses of most systems, the environmental conditions to which they may be exposed, and the financial and economic conditions that influence relationships between present and future costs. An effective life-cycle cost analysis depends on having a reasonable range of possible alternatives that are likely to dehver equally satisfactory service over a given service life. Substantial obstacles to implementing life-cycle cost control in practice include ... [Pg.389]

The upside to creating influencer relationships for the purpose of social content syndication is that you both get the benefits of each other s network and reach. [Pg.234]

Fig. 2 shows the response of a C2 film system on a step wedge (wall thickness range 2. .. 18 mm) exposed with a X-ray tube at 160 kV. For the exposure withy-rays (Irl92 or Co60) corresponding linear relationships are obtained. From this linear relationship it is followed, that the influence of the scattered radiation and the energy dependence of the absorption coefficient can be considered by an effective absorption coefficientPcff in equation (1). [Pg.562]

Most of the Langmuir films we have discussed are made up of charged amphiphiles such as the fatty acids in Chapter IV and the lipids in Sections XV-4 and 5. Depending on the pH and ionic strength of the subphase, electrostatic effects can become quite important. Here we develop the theoretical foundation for charged films with the Donnan relationship. Then we mention the influence of subphase pH on film behavior. [Pg.553]

The practical and computational complications encountered in obtaining solutions for the described differential or integral viscoelastic equations sometimes justifies using a heuristic approach based on an equation proposed by Criminale, Ericksen and Filbey (1958) to model polymer flows. Similar to the generalized Newtonian approach, under steady-state viscometric flow conditions components of the extra stress in the (CEF) model are given a.s explicit relationships in terms of the components of the rate of deformation tensor. However, in the (CEF) model stress components are corrected to take into account the influence of normal stresses in non-Newtonian flow behaviour. For example, in a two-dimensional planar coordinate system the components of extra stress in the (CEF) model are written as... [Pg.14]

Solvents exert their influence on organic reactions through a complicated mixture of all possible types of noncovalent interactions. Chemists have tried to unravel this entanglement and, ideally, want to assess the relative importance of all interactions separately. In a typical approach, a property of a reaction (e.g. its rate or selectivity) is measured in a laige number of different solvents. All these solvents have unique characteristics, quantified by their physical properties (i.e. refractive index, dielectric constant) or empirical parameters (e.g. ET(30)-value, AN). Linear correlations between a reaction property and one or more of these solvent properties (Linear Free Energy Relationships - LFER) reveal which noncovalent interactions are of major importance. The major drawback of this approach lies in the fact that the solvent parameters are often not independent. Alternatively, theoretical models and computer simulations can provide valuable information. Both methods have been applied successfully in studies of the solvent effects on Diels-Alder reactions. [Pg.8]

Influence of Applied Potential on the Faradaic Current As an example, let s consider the faradaic current when a solution of Fe(CN)6 is reduced to Fe(CN)6 at the working electrode. The relationship between the concentrations of Fe(CN)6 , Fe(CN)6 A and the potential of the working electrode is given by the Nernst equation thus... [Pg.510]

The thermal conductivity of most materials decreases with temperature. When the foam stmcture and gas composition are not influenced by temperature, the k of the cellular material decreases with decreasing temperature. When the composition of the gas phase may change (ie, condensation of a vapor), then the relationship of k to temperature is much more complex (143,191,198). [Pg.414]

P and Pg, exist in foUicular fluid. Control of inhibin secretion involves a feedback relationship in which circulating FSH stimulates inhibin secretion, which in turn reduces the secretion of FSH (8). Both the homo- and the heterodimers of the P-subunits of inhibin promote the secretion of FSH and thus have been termed activins. Activin is secreted by the ovary and the testes into the circulation. In addition, both inhibin and activin have intragonadal autocrine and paracrine effects that influence gonadal steroidogenesis (9). [Pg.172]

Condensation occurs most readily at a pH value equal to the piC of the participating silanol group. This representation becomes less vaUd at pH values above 10, where the rate constant of the depolymerization reaction k 2 ) becomes significant and at very low pH values where acids exert a catalytic influence on polymerization. The piC of monosilicic acid is 9.91 0.04 (51). The piC value of Si—OH decreases to 6.5 in higher order sihcate polymers (52), which is consistent with piC values of 6.8 0.2 reported for the surface silanol groups of sihca gel (53). Thus, the acidity of silanol functionahties increases as the degree of polymerization of the anion increases. However, the exact relationship between the connectivity of the silanol sihcon and SiOH acidity is not known. [Pg.6]

Dose—response relationships are useful for many purposes in particular, the following if a positive dose—response relationship exists, then this is good evidence that exposure to the material under test is causally related to the response the quantitative information obtained gives an indication of the spread of sensitivity of the population at risk, and hence influences ha2ard evaluation the data may allow assessments of no effects and minimum effects doses, and hence may be valuable in assessing ha2ard and by appropriate considerations of the dose—response data, it is possible to make quantitative comparisons and contrasts between materials or between species. [Pg.232]

Pharmacokinetic studies should allow an assessment of the relationship between the environmental-exposure conditions and the absorbed dose, and how these influence the doses of test material and metaboHtes received by various body tissues and fluids, and the potential for storage. Numerous texts are available on the design and conduct of metaboHsm and pharmacokinetic studies (117—119). [Pg.237]


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See also in sourсe #XX -- [ Pg.202 ]




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