Indium II chloride

InCl Indium (I) chloride, 7 19, 20 InCh Indium (II) chloride, 7 19,... 

CulnS2, CulnSe2. CuInS2 (CIS),films have been grown from mixed copper(II) chloride, indium(III) chloride cation precursor, and sodium sulfide anion precursor solutions.121122 XPS and XRD analyses revealed that, when the copper/indium concentration ratio in the solution was 1.25, a stoichiometric CIS film could be grown. The electrical parameters obtained with different copper/indium concentration ratios have been investigated.121... 

Dibromogermane, 0267 Germanium tetrachloride, 4162 Gold(III) chloride, 0111 Indium bromide, 0289 Iridium hexafluoride, 4362 Iron(II) bromide, 0266 Iron(III) bromide, 0286 Iron(II) chloride, 4061 Iron(III) chloride, 4133 Iron(II) iodide, 4395... 

Indium mediates a highly enantioselective Barbier-type allylation of both aromatic and aliphatic aldehydes, using a chiral ethanolamine auxiliary, readily recoverable by acid extraction.193 Barbier coupling of aldehydes can be carried out in water using tin(II) chloride, with cobalt(II) acetylacetonate as catalyst.194... 

The rather complicated In-P framework of 51 was obtained by the reaction of indium(III) chloride with PhP(SiMe3)2 in the presence of triethylphosphane [Eq. (8)].108 Apparently, a complex redox process occurred, in the course of which P atoms were oxidized by the formation of three P-P bonds, while six In atoms were reduced from +3 to +2 accompanied by the formation of three In-In bonds. The indium(II) atoms... 

The disadvantages associated with the use of chloroaluminate(iii) ionic liquids have led various authors to investigate alternative Lewis acidic ionic liquid media such as those based on zinc(ii) chloride [25], tin(ii) chloride [26] and indium(iii) chloride [27]. These ionic liquids are considerably more water stable although much less reactive than the chloroaluminate(iii) systems. 

Triethylsilane and trityl salts.or Trimethylsilyl Triftuoro-methanesulfonate are effective for the reduction of various ketones and acetals, as are combinations of Chlorotrimethylsi-lane and indium(III) chloride and Tin(II) Bromide and Acetyl Bromide. Isophthaldehyde undergoes reductive polycondensation to a polyether when treated with triethylsilane and Triphenyl-methyl Perchlorate. ... 

Instead of using a stoichiometric amount of indium, the allylation of aldehydes and ketones can be carried out by using catalytic amounts of indium(III) chloride in combination with aluminum or zinc metals in a THF/water (5 2) mixture at room temperature. The reaction is much slower relative to the same reaction mediated by a stoichiometric amount of indium. When the reaction was carried out in anhydrous THE, the yield dropped considerably, while side reactions (such as reducing to alcohol) increased. The combinations of Al/InCh or Zn/InCh gave comparable results. The indium-mediated allylation carried out with allylstannanes in combination with indium chloride in aqueous medium was reported by Marshall and Hinkle. Allyl indium was proposed as the reaction intermediate. Various allylic compounds undergo palladium-catalyzed allylation of carbonyls via the transmetala-tion of r -allylpalladium(II) intermediates with indium in the presence of indium trichloride in aqueous media. °... 

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