Indiums formation

Admittedly this scheme is daunting in its complexity and the kinetic implications are as yet unclear. Early studies on p-GaP, p-GaAs and other Group III-V (13-15) semiconductors reported onset of cathodic photocurrents (attributable to HER) only at potentials far removed (ca. 0.6 V) from V[b (see, e.g., Ref [264]). This was attributed to steps 33b and 33h in the above scheme. More recent work [91] has shown that the HER at illuminated p-InP-electrolyte contacts is accompanied by a photocorrosion reaction, leading to indium formation on the semiconductor surface. Representative PEIS data from this study are shown in complex plane format in Figure 28. Note that unlike in the cases above (e.g.. Figure 27), multiple relaxa-... 

Pocza J F, Barna A and Barna P B 1969 Formation processes of vacuum deposited indium films and thermodynamical properties of submicroscopic particles observed by in situ electron microscopy J. Vac. Sc/. Techno . 6 472... 

The conventional electrochemical reduction of carbon dioxide tends to give formic acid as the major product, which can be obtained with a 90% current efficiency using, for example, indium, tin, or mercury cathodes. Being able to convert CO2 initially to formates or formaldehyde is in itself significant. In our direct oxidation liquid feed fuel cell, varied oxygenates such as formaldehyde, formic acid and methyl formate, dimethoxymethane, trimethoxymethane, trioxane, and dimethyl carbonate are all useful fuels. At the same time, they can also be readily reduced further to methyl alcohol by varied chemical or enzymatic processes. 

Sulfides. The main sulfide of indium is I1I2S2 [12030-24-9], which can be prepared by heating the metal with sulfur or by precipitation from weak acid solutions of indium salts by H2S. Precipitated I1I2S2 varies in color from yellow to red-brown, and in crystal size depending on formation conditions. It dissolves in acids and sodium sulfide solution. Other reported sulfides of indium ate InS [12030-14-7], a red-brown soHd In2S [12196-52-0], and In S [12142-00-5]. 

Rapp (1961) has confirmed this equation in a study of the oxidation in air of Ag-In alloys at 550°C. The reaction proceeds with tire internal formation of In203 particles over a range of indium concenuations, but at a critical mole fraction of indium in the alloy, external oxidation occurs with the growdr of a layer of In203 covering the alloy. The n airsitioir from internal to external oxidation was found by Rapp to occur at the mole fraction of indium cone-sponding to... 

Indium (III) oxide [1312-43-2] M 277.6, d 7.18, m sublimes at 850°. Wash with H2O and dry below 850°. Volatilises at 850° and dissolves in hot mineral acids to form salts. Store away from light because it darkens due to formation of In. 

Scheme 37 shows a reaction sequence leading to a mono(amidinato) indium bia(arylimido) complex. Subsequent treatment of the latter with Ti(NMe2)4 resulted in formation of the heterobimetallic In/Ti complex [But(NPr )2]In /t-NCgH3Pri-2,6 2Ti(NMe2)2 (cf. Sections 111.B.2 and V.A.l)." ... 

In contrast, reactions of trimethylindium with free amidines led to formation of dinuclear amidinate-bridged indium complexes. These reactions are illustrated in Scheme 38. ... 

The telluride halides crystallize in monoclinic lattices, but only In-TeBr and InTel are isotypic 162). InTeCl forms a layer type of structure, as do InSCl and its analogs, but, owing to the size of the Te atom and the enhanced covalency of the In-Te bond, only a coordination number of 4 for indium is realized. The structure is built up of strongly distorted, InTesraCli/j tetrahedra that share the corners and edges occupied by Te atoms. The Cl atoms are coordinated to one tetrahedron each, and do not take part in the layer formation 324, 325). 

Formation 8.3.3.1 Reaction with octaethylporphyri-nato-indium and thalliumchloride 6.5.Z2... 

In searching to formulate a mechanism of CuInSc2 phase formation by one-step electrodeposition from acid (pH 1-3) aqueous solutions containing millimolar concentrations of selenous acid and indium and copper sulfates, Kois et al. [178] considered a number of consecutive reactions involving the formation of Se, CuSe, and Cu2Se phases as a pre-requisite for the formation of CIS (Table 3.2). Thermodynamic and kinetic analyses on this basis were used to calculate a potential-pH diagram (Fig. 3.10) for the aqueous Cu+In-i-Se system and construct a distribution diagram of the final products in terms of deposition potential and composition ratio of Se(lV)/Cu(ll) in solution. 

Rabchynski SM, Ivanou DK, Streltsov EA (2004) Photoelectrochemical formation of indium and cadmium selenide nanoparticles through Se electrode precursor. Electrochem Commun 6 1051-1056... 

Palladium catalyzes allylation of carbonyl compounds with various ally lie compounds using In-InCl3 in aqueous media (Eq. 8.66).158 Various allylic compounds can be effectively applied via the formation of TT-allylpalladium(II) intermediates and their transmetalation with indium in the presence of indium trichloride in aqueous media. 

Limited formation of mixed crystals occurs when the two components have different structures, as for example in the case of indium and cadmium. Mixed crystals containing much indium and little cadmium have the structure of indium, while those containing little indium and much cadmium have the cadmium structure. At intermediate compositions a gap is observed, i.e. there are no homogeneous mixed crystals, but instead a mixture of crystals rich in indium and crystals rich in cadmium is formed. This situation can even... 

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