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Hydrogenations fatty ester

The mechanism for sulfonation of hydrogenated fatty esters is accepted as a two-stage process. A rapid sequence of reactions leads to the formation of intermediates having approximately 2 1 stoichiometry of sulfur trioxide to ester. In the subsequent slower and higher temperature aging step, the SO is released for further reactions and the starting material conversion proceeds to completion (133). [Pg.80]

The catalytic hydrogenation of esters is of great commercial importance. It is one of the industrial methods used to produce long-chain fatty alcohols (eg, dodecyl and decyl alcohols) from fatty acid methyl esters (33). The method is also suitable for the conversion of dimethyl 1,4-cyclohexanedicarboxylate [94-60-0] into 1,4-cydohexanedimethanol [105-08-8] an important intermediate in the manufacturing of polyesters. [Pg.389]

Fatty Acid Esters and Fatty Alcohols Fatty acid esters are obtained by transesterification of triglycerides (vegetable oils) or by esterification of fatty acid with alcohol or polyols. Fatty alcohols are obtained by hydrogenation of esters on metal catalysts. Fatty acid esters and fatty alcohols are useful platform molecules to prepare surfactants, emulsifier, lubricants and polymers. [Pg.62]

Slurry reactors (bubble towers) are fluidized with continuous flow of gas. The particles are smaller (less than 0.1 mm) than in the liquid fluidized systems (0.2-1 mm). In some operations the liquid and solid phases are stationary, but in others they circulate through the vessel. Such equipment has been used in Frscher-Tropsch plants and for hydrogenation of fatty esters to alcohols, furfural to furfuryl alcohol, and of glucose to sorbitol. Hydrogenation of benzene to cyclohexane is done at 50 bar and 220-225°C with Raney nickel of 0.01-0.1 mm dia. The relations between gas velocities, solids... [Pg.605]

FATTY ESTER. A fatly acid with the active hydrogen replaced by the alkyl group of a monohydric alcohol. The esterification of a fatty acid. RCOOH. by and alcohol. R OH. yields the fatly ester RCOOR. The most common alcohol used is methanol, yielding the methyl ester RCOOCHj. The methyl esters of fatly acids have higher vapor pressures than the corresponding acids and are distilled more easily. [Pg.604]

As already noted by Verkuijlen and Boelhouwer in 1974 [29], the SM of highly unsaturated fatty esters produces, among other compounds, considerable amounts of 1,4-cyclohexadiene (1,4-CHD). This fact has been exploited by Mathers et al. for the production of 1,3-cyclohexadiene (1,3-CHD) via metathesis and isomerization reactions of plant oils [141]. For instance, 1,4-CHD was obtained by treatment of soybean oil with C4 and was subsequently isomerized with RuHCl(CO)(PPh3)3. Then, the produced 1,3-CHD was polymerized with nickel(II)acetylacetonate/ methaluminoxane. Interestingly, the polymerizations could be carried out in bulk and using hydrogenated D-limonene as renewable solvent. The polymers thus obtained presented / m around 300°C. [Pg.32]

The hydrogenation of fatty acids or fatty esters is of industrial importance for the production of fatty alcohols. Usually, the hydrogenation is performed in slurry-phase or fixed-bed reactors over copper-chromium oxide catalyst at elevated temperature and pressure.37 Rieke et al. investigated the hydrogenation of methyl dodecanoate over copper-chromium oxide at 280°C and 13.8 MPa H2, in order to study the side reactions that occur during hydrogenation.37 On the basis of the potential reaction routes described by Rieke et al., the pathways leading to C12 alcohol and various byproducts are summarized in Scheme 10.2, with exclusion of the formation and reactions of acetals. It has been found that both catalytic activity and selectivity correlated well with the crystallinity of the copper-chromium ox-... [Pg.393]

Mono-unsaturated Fatty Esters by Partial Hydrogenation of Natural Oils... [Pg.90]

Rendered fats may be further processed by refining, bleaching, and deodorizing, and these may be used as raw materials in hydrogenation, hydrolysis to fatty acids, and frawi-esterification to fatty esters. Many factors affect the suitability of rendered fats for such use these include... [Pg.3060]

Homogeneous Hydrogenation of Unsaturated Fatty Esters by Fe(CO), and Diene-Fe(CO)3... [Pg.177]


See other pages where Hydrogenations fatty ester is mentioned: [Pg.446]    [Pg.447]    [Pg.448]    [Pg.100]    [Pg.70]    [Pg.389]    [Pg.20]    [Pg.470]    [Pg.124]    [Pg.502]    [Pg.149]    [Pg.150]    [Pg.153]    [Pg.377]    [Pg.377]    [Pg.381]    [Pg.100]    [Pg.209]    [Pg.389]    [Pg.335]    [Pg.124]    [Pg.84]    [Pg.389]    [Pg.298]    [Pg.310]    [Pg.446]    [Pg.447]    [Pg.448]    [Pg.592]    [Pg.1263]    [Pg.1929]    [Pg.2445]    [Pg.177]    [Pg.178]   
See also in sourсe #XX -- [ Pg.418 ]




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Fatty hydrogenation

Hydrogenation ester

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