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Hydrogen sampling for

With the INS technique, force fields can be refined with respect to the fiiU spectral profiles including both frequencies and intensities [14,15]. This technique is most powerfiil for hydrogenous samples for which intensities are dominated by modes involving large proton displacements. Contributions from other atoms are much weaker and can be easily overlooked. [Pg.278]

Atomic absorption spectroscopy is an alternative to the colorimetric method. Arsine is stiU generated but is purged into a heated open-end tube furnace or an argon—hydrogen flame for atomi2ation of the arsenic and measurement. Arsenic can also be measured by direct sample injection into the graphite furnace. The detection limit with the air—acetylene flame is too high to be useful for most water analysis. [Pg.232]

Apply colloidal palladium solution to the starting [29] point (diameter 8 to 10 mm) and dry Then apply sample solution and gas with hydrogen (desiccator) for 1 h Maleic and fumanc acids yield succinic acid etc, which may also be separated chromatographically... [Pg.61]

Oxygen and silicon are the most abundant elements in the earth s crust. Table 25-111 shows that 60% of the atoms are oxygen atoms and 20% are silicon atoms. If our sample included the oceans, hydrogen would move into the third place ahead of aluminum (remember that water contains two hydrogen atoms for every oxygen atom). If the sample included the central core... [Pg.441]

IV, CCR and oxidation stability are three strictly co-related parameters. As a general rale, the reduction of IV (on the same feedstock) dramatically improves the oxidation stability. On the contrary the distillation step removes the main part of naturally occurring antioxidants. For this reason, even after hydrogenation the Rancimat induction time (as measured according to the EN 14112 standard) of the hydrogenated sample does not fulfill the EN 14214 requirement for oxidation stabihty (6 hours at 110°C), 4 hours being the measured induction period. [Pg.275]

Results of raw waste load found in verification sampling for a hydrogen cyanide plant are given in Table 22.13. [Pg.936]

The usefulness of urinary thiosulfate as an indicator of nonfatal hydrogen sulfide toxicity has been studied (Kangas and Savolainen 1987). Urinary samples for thiosulfate were obtained from volunteers exposed by inhalation to 8, 18, or 30 ppm of hydrogen sulfide for 30-45 minutes (the occupational exposure limit of 10 ppm for 8 hours was never exceeded). Excretion of urinary thiosulfate increased linearly up to 15 hours postexposure. Beyond 15 hours, the urinary thiosulfate concentration remained low, possibly indicating that most of the absorbed hydrogen sulfide was metabolized or excreted within 15 hours. [Pg.114]

The Iodometric method has also been utilized in analyzing hydrogen sulfide in the air (EPA 1978). The method is based on the oxidation of hydrogen sulfide by absorption of the gas sample in an impinger containing a standardized solution of iodine and potassium iodide. This solution will also oxidize sulfur dioxide. The Iodometric method is suitable for occupational settings. The accuracy of the method is approximately 0.50 ppm hydrogen sulfide for a 30-L air sample (EPA 1978). [Pg.163]

FEP calculations for paths A, B and C were performed with a 40 ps equilibration run prior to the sampling for all points along the path. The free energy contributions were sampled for 20 ps for each point on the MEP. In all cases a time step of 2.0 fs was employed, maintaining a constant temperature of 300 K. The SHAKE [47] algorithm was used to constrain all bonds involving hydrogen atoms. [Pg.66]

The Cr203 content of each catalyst was determined by atomic absorption spectroscopy (Varian/Spectr AA-20 plus) on acid-digested samples. Total surface areas were determined by a single point BET method (nitrogen adsorption-desorption at 77.5 K) using a mixture of 29.7% N2 in helium. Samples were wet-loaded into the flow tube and dried at 423 K in a hydrogen flow for 15 minutes and then for another 30 minutes at 513 K before cooling in helium. [Pg.34]

Copper metal surface area was determined by nitrous oxide decomposition. A sample of catalyst (0.2 g) was reduced by heating to 563 K under a flow of 10 % H2/N2 (50 cm min"1) at a heating rate of 3 deg.min 1. The catalyst was then held at this temperature for 1 h before the gas flow was switched to helium. After 0.5 h the catalyst was cooled in to 333 K and a flow of 5 %N20/He (50 cm3mirr ) passed over the sample for 0.25 h to surface oxidise the copper. At the end of this period the flow was switched to 10 % H2/N2 (50 entitlin 1) and the sample heated at a heating rate of 3 deg.min"1. The hydrogen up-take was quantified, from this a... [Pg.85]

Occasional explosions experienced during use of hot perchloric acid to dissolve steel samples for analysis [1] were attributed to formation of hydrogen-perchloric... [Pg.1359]

Krishnamurty, K. V. et al., At. Abs. Newslett., 1976, 15, 68-70 When preparing soil and sediment samples for atomic absorption spectral analysis for trace metals, pre-oxidation with nitric acid before addition of hydrogen peroxide eliminates the danger of explosion. [Pg.1588]

Let us now turn to a comparison of theory with experiment. Comparing (95), (84), and (68), we find that the dependence of the photocatalytic effect K on the position of the Fermi level at the surface s and in the bulk cv of an unexcited sample for the oxidation of water is the same as for the oxidation of CO or for the hydrogen-deuterium exchange reaction. For this reason, such factors as the introduction of impurities into a specimen, the adsorption of gases on the surface of the specimen, and the preliminary treatment of the specimen will exert the same influence on the photocatalytic effect in all the three reactions indicated above. The dependence of K on the intensity I of the exciting light must also be the same in all the three cases. [Pg.201]

Compression molded (150°C for 3 minutes press chilled with cold water immediately thereafter) samples of poly(trans-l,4-hexadiene) (14) and poly(5-methyl-l,4-hexadiene) were examined with a General Electric (XRD-3) X-ray unit. Transmission Laue X-ray photographs were taken using nickel filtered copper X-radiation. Samples were stretched to four times of their original lengths to obtain oriented fibers. The fiber patterns were obtained in a flat plate film holder with the specimen to film distance standardized at 5 centimeters. X-ray diffraction patterns were similarly obtained for the hydrogenated sample of poly(5-methyl-l,4-hexadiene). [Pg.174]

Hydrogen sulfide gas interfered in the determination of antimony since, after the addition of hydrogen sulfide, a peak comes a few seconds after the antimony peak. It was found that either degassing the sample for 300 s or placing lead acetate in the line eliminated the problem without interfering with the antimony determination. [Pg.137]


See other pages where Hydrogen sampling for is mentioned: [Pg.193]    [Pg.474]    [Pg.474]    [Pg.127]    [Pg.235]    [Pg.86]    [Pg.328]    [Pg.193]    [Pg.474]    [Pg.474]    [Pg.127]    [Pg.235]    [Pg.86]    [Pg.328]    [Pg.130]    [Pg.411]    [Pg.414]    [Pg.179]    [Pg.232]    [Pg.108]    [Pg.2197]    [Pg.191]    [Pg.11]    [Pg.440]    [Pg.55]    [Pg.26]    [Pg.355]    [Pg.525]    [Pg.229]    [Pg.1213]    [Pg.63]    [Pg.330]    [Pg.573]    [Pg.214]    [Pg.85]    [Pg.27]    [Pg.717]    [Pg.381]    [Pg.522]    [Pg.33]    [Pg.93]   
See also in sourсe #XX -- [ Pg.112 , Pg.115 , Pg.117 , Pg.119 ]




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