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Hydrogen cyclohexadiene

Transfer hydrogenation cyclohexadiene, 10% Pd/C, DMF, 90 min, 99% yield. This method was developed for deprotection of nucleoside derivatives because conventional hydrogenolysis often results in over reduction of the nucleobase. ... [Pg.292]

Alkenes in (alkene)dicarbonyl(T -cyclopentadienyl)iron(l+) cations react with carbon nucleophiles to form new C —C bonds (M. Rosenblum, 1974 A.J. Pearson, 1987). Tricarbon-yi(ri -cycIohexadienyI)iron(l-h) cations, prepared from the T] -l,3-cyclohexadiene complexes by hydride abstraction with tritylium cations, react similarly to give 5-substituted 1,3-cyclo-hexadienes, and neutral tricarbonyl(n -l,3-cyciohexadiene)iron complexes can be coupled with olefins by hydrogen transfer at > 140°C. These reactions proceed regio- and stereospecifically in the successive cyanide addition and spirocyclization at an optically pure N-allyl-N-phenyl-1,3-cyclohexadiene-l-carboxamide iron complex (A.J. Pearson, 1989). [Pg.44]

Reduction of arenes by catalytic hydrogenation was described m Section 114 A dif ferent method using Group I metals as reducing agents which gives 1 4 cyclohexadiene derivatives will be presented m Section 1111 Electrophilic aromatic substitution is the most important reaction type exhibited by benzene and its derivatives and constitutes the entire subject matter of Chapter 12... [Pg.438]

Tetracyanobenzoquinone [4032-03-5] 3,6-dioxo-l,4-cyclohexadiene-l,2,4,5-tetracarbonitrile, is a remarkably strong oxidizing agent for a quinone it abstracts hydrogen from tetralin or ethanol even at room temperature (50). It is a stronger TT-acid than TCNE because it forms more deeply colored TT-complexes with aromatic hydrocarbons. [Pg.405]

Vanadium pentafluoride replaces benzylic hydrogen by fluonne but also adds fluonne to the aromatic system, giving fluonnated cyclohexadienes and cyclohexenes [5] (equation 5)... [Pg.120]

FIGURE 11.2 Heats of hydrogenation of cyclohexene, 1,3-cyclohexadiene, a hypothetical 1,3,5-cyclohexa-triene, and benzene. All heats of hydrogenation are in kilojoules per mole. [Pg.429]

Pd-C using transfer hydrogenation. A number of methods have been developed in which hydrogen is generated in situ. These include the use of cyclohexene (1-8 h, 80-90% yield)," cyclohexadiene (25°, 2 h, good yields)," HC02H, ammonium formate (MeOH, reflux, 91% yield), ... [Pg.79]

Chauvin s group described the selective hydrogenation of cyclohexadiene to cyclohexene through making use of the biphasic reaction system [46]. Since the solubility of cyclohexadiene in [BMIM][SbFg] is about five times higher than the solubility of cyclohexene in the same ionic liquid, the latter was obtained in 98 % selectivity at 96 % conversion. [Pg.230]

We can get a quantitative idea of benzene s stability by measuring heats of hydrogenation (Section 6.6). Cyclohexene, an isolated alkene, has ff ydrog = -118 kj/mol (-28.2 kcal/mol), and 1,3-cyclohexadiene, a conjugated diene, has A/Chydrog = 230 kj/mol (-55.0 kcal/mol). As noted in Section 14.1, this value for 1,3-cyclohexadiene is a bit less than twice that for cyclohexene because conjugated dienes are more stable than isolated dienes. [Pg.520]

As described ( 6.5.3.1) l-phenylbora-2,5-cyclohexadiene (cyclic divinylborane) reacts with FeCCOj under irradiation to the Fe(CO)3 complex. The dinuclear borabenzene complex [(C5H5BPh)Fe(CO>2]2 is found as a by-product. It is to be compared with the well-known [Tj -CpFe(CO)2]2. CjHjBPh reacts spontaneously with Co2(CO)u to form three products. Above 60°C (C5H5BPh)Co(CO)2 is the only product . At 30°C yellow isomers III and IV having partially hydrogenated borabenzene ligands form above 40°C III isomerizes to IV. [Pg.92]

Nonadiabatic transitions definitely play crucial roles for molecules to manifest various functions. The theory of nonadiabatic transition is very helpful not only to comprehend the mechanisms, but also to design new molecular functions and enhance their efficiencies. The photochromism that is expected to be applicable to molecular switches and memories is a good example [130]. Photoisomerization of retinal is well known to be a basic mechanism of vision. In these processes, the NT type of nonadiabatic transitions play essential roles. There must be many other similar examples. Utilization of the complete reflection phenomenon can also be another candidate, as discussed in Section V.C. In this section, the following two examples are cosidered (1) photochromism due to photoisomerization between cyclohexadiene (CHD) and hexatriene (HT) as an example of photoswitching molecular functions, and (2) hydrogen transmission through a five-membered carbon ring. [Pg.182]

Scheme 16 Hydrogen-mediated coupling of 1,3-cyclohexadiene to a-ketoaldehydes... Scheme 16 Hydrogen-mediated coupling of 1,3-cyclohexadiene to a-ketoaldehydes...

See other pages where Hydrogen cyclohexadiene is mentioned: [Pg.353]    [Pg.22]    [Pg.428]    [Pg.328]    [Pg.146]    [Pg.39]    [Pg.49]    [Pg.394]    [Pg.428]    [Pg.533]    [Pg.180]    [Pg.215]    [Pg.163]    [Pg.631]    [Pg.1292]    [Pg.54]    [Pg.56]    [Pg.118]    [Pg.1010]    [Pg.1010]    [Pg.1432]    [Pg.1436]    [Pg.201]    [Pg.202]    [Pg.159]    [Pg.102]    [Pg.9]    [Pg.270]    [Pg.263]    [Pg.105]    [Pg.106]    [Pg.106]    [Pg.117]   
See also in sourсe #XX -- [ Pg.163 ]




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1,3-Cyclohexadiene heat hydrogenation

1,4-Cyclohexadienes, hydrogenations

1,4-Cyclohexadienes, hydrogenations

1.4- Cyclohexadiene hydrogenation

1.4- Cyclohexadiene hydrogenation

1.4- Cyclohexadiene, reactions with hydrogen

1.4- Cyclohexadiene, reactions with hydrogen atoms

Cyclohexadiene, 1,4-, hydrogen donor

Cyclohexadiene, 1,4-, hydrogen donor transfer hydrogenolysis

Hydrogen transfer from 1,4-cyclohexadiene

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