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Homogeneous acid-catalyzed transesterification process

The homogeneous acid-catalyzed transesterification process does not enjoy the same popularity in commercial application as its counterpart, the base-catalyzed process, one of the main reasons being that it is about 4000 times slower, due to the different mechanism [10]. Thus, in the reaction sequence triglyceride is converted stepwise to diglyceride, monoglyceride and finally glycerol with formation of one molecule of methyl ester at each step (Scheme 10.1). [Pg.330]

Since the transesterification of glycerides is an amphoteric catalytic reaction, it can be carried out in presence of either an acid catalyst or a base catalyst. For an alkali-catalyzed transesterification, the raw materials must be anhydrous and with low FFAs less than 1% to avoid the production of soap (348). If the content of such compounds is greater, the acid-catalyzed transesterification can be utilized (349). However, the use of a liquid acid catalyst is costly, since it needs a distillation process for water removal, a methanol recycling unit, purification of ester, and separation of the homogeneous catalyst (350,351). [Pg.1498]

The term reactive distillation (RD) refers to both catalyzed and uncatalyzed reaction systems. Catalytic distillation systems may use a homogenous or heterogenous catalyst to accelerate the reaction. Reactive distillation is a well-known example of reactive separation process, and is used commercially. The first patent and early journal articles deal mainly with homogenously catalyzed reactions such as esterifications, transesterifications, and hydrolysis.f Heterogenous catalysis with RD is a more recent development. The key advantages for a properly designed RD colunm are complete conversion of reactants and attainment of high selectivity. An example of the benefits of RD is the acid catalyzed production of methyl acetate by... [Pg.2542]

Generally, the above transesterification reactions are catalyzed by strong acids or alkalis [1, 2]. In the homogeneous catalytic process by acids or alkalis, neutralization is required of the product. This post-treatment produces waste water, and increases equipment investment and production cost. Recently, more attention has been paid to the heterogeneous catalysis process [3] for an easier production process and to reduce pollution of the environment. [Pg.153]

Biodiesel is a mixture of methyl esters of fatty acids and is produced from vegetable oils by transesterification with methanol (Fig. 10.1). For every three moles of methyl esters one mole of glycerol is produced as a by-product, which is roughly 10 wt.% of the total product. Transesterification is usually catalyzed with base catalysts but there are also processes with acid catalysts. The base catalysts are the hydroxides and alkoxides of alkaline and alkaline earth metals. The acid catalysts are hydrochloride, sulfuric or sulfonic acid. Some metal-based catalysts can also be exploited, such as titanium alcoholates or oxides of tin, magnesium and zinc. All these catalyst acts as homogeneous catalysts and need to be removed from the product [16, 17]. The advantages of biodiesel as fuel are transportability, heat content (80% of diesel fuel), ready availability and renewability. The... [Pg.211]

In homogeneous catalysis, the catalyst is in the same phase as the reactants and products. Here we will concentrate on homogeneous catalysis in the liquid phase. In the classic case, the reactant (also called the substrate) molecules and the catalyst are reacted in a solvent. For example, the transesterification of fatty acid triglycerides with methanol (Figure 1.10) is catalyzed by hydroxide (OH-) ions. This is an important process for making fatty acid methyl esters which are then used as biodiesel. [Pg.12]


See other pages where Homogeneous acid-catalyzed transesterification process is mentioned: [Pg.75]    [Pg.170]    [Pg.166]    [Pg.182]    [Pg.258]    [Pg.158]    [Pg.269]    [Pg.461]    [Pg.67]   
See also in sourсe #XX -- [ Pg.330 ]




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Acid process

Acid-catalyzed transesterification

Catalyzed process

Homogeneous acid-catalyzed

Homogeneous acid-catalyzed process

Homogenization process

Process homogeneous

Processes homogenous

Transesterification process

Transesterifications

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