Hardness properties creep behavior

Although the dynamic mechanical properties and the stress-strain behavior iV of block copolymers have been studied extensively, very little creep data are available on these materials (1-17). A number of block copolymers are now commercially available as thermoplastic elastomers to replace crosslinked rubber formulations and other plastics (16). For applications in which the finished object must bear loads for extended periods of time, it is important to know how these new materials compare with conventional crosslinked rubbers and more rigid plastics in dimensional stability or creep behavior. The creep of five commercial block polymers was measured as a function of temperature and molding conditions. Four of the polymers had crystalline hard blocks, and one had a glassy polystyrene hard block. The soft blocks were various kinds of elastomeric materials. The creep of the block polymers was also compared with that of a normal, crosslinked natural rubber and crystalline poly(tetra-methylene terephthalate) (PTMT). 

Other important mechanical properties are surface hardness and creep or cold flow behavior. The latter represents the tendency of a polymer to react with a... 

Using a nanoindentation technique, Shen et al. [150] studied the effects of clay concentrations on the mechanical properties (hardness, elastic modulus, and creep behavior) of exfoliated polyamide 6,6-clay nanocomposites. The results were discussed in conjnnction with those obtained by dynamic mechanical analysis and optical microscopy, and also conjunction with changes in morphology, crystallinity, and x-ray diffraction. 

Elevated temperature applications require materials that can maintain good mechanical properties such as strength and hardness. Ceramics have good mechanical properties at high temperature and, thus, appear to be good candidates for elevated temperature applications. However, due to their brittle nature, monolithic ceramics are unsuitable for many applications where reliability is a critical issue. In the last few years, a new class of ceramic materials has been developed and studied. It is understood that two brittle materials can show non-brittle behavior if they are properly mixed. Fiber-reinforced ceramic matrix composites (CMCs) exhibit pseudo-plastic behavior at room temperature, as well as in an elevated temperature environment. Since the fiber and the matrix are made of ceramic material, creep behavior and hazardous emissions are reduced considerably. 

The rate dependencies of the ferroelectric material properties are also reflected in the dynamics after fatigue. Initially, most of the domain system will be switched almost instantaneously [235], and only a small amount of polarization will creep for longer time periods [194]. A highly retarded stretched exponential relaxation was observed after bipolar fatigue treatment [235], and these observations correlated well with the thermally activated domain dynamics. If the overall materials response was represented in a rate-dependent constitutive material law 236], however, then a growing defect cluster size would retard the domain dynamics considerably. Hard and soft material behaviors were also representable as different barrier heights to a thermally activated domain wall motion, as demonstrated by the theoretical studies of Belov and Kreher [236]. 

---