Mixes hardened

The patching mix may be processed in an asphalt hot-mix plant and transported to the various patching sites in a heated vessel. Alternatively, the patching mix may be produced by remelting previously made hardened mix in a mobile heated vessel equipped with an agitator. The latter process is particularly adaptable for use during the winter in areas where hot-mix plants are not normally operational. 

All these tests have to be carried out with ready to use glue mixes, i.e., adhesive and hardener mixed before application. In case of separate spreading of adhesive... 

A relatively new concept is to inject resin into the dry fibrous preform just before it enters the die. A resin-hardener mix is stored and supplied through a steel chamber attached to the front end of the die. An optimized... 

PART A RESIN PARTB HARDENER MiXED MIX RATIO 1 TYPICAL PERFORMANCE (BY VOL) n ... 

PART A RESiN PARTS HARDENER MIXED MIX RATIO (BY VOL) TYPICAL PERFORMANCE ... 

In the realm of boat building or repair such a glue would obviously be required, but there are few candidates that fit this specification. Undoubtedly one of the best and relatively easy to use is resorcinol/formaldehyde which is a two-part adhesive consisting of liquid resin and powder hardener. Mixed just before using, it is a dark red colour that shows up the glue line. 

Mixed with sand it hardens as mortar and plaster by taking up carbon dioxide from the air. Calcium from limestone is an important element in Portland cement. 

Furan hot-box resins are used in both ferrous and nonferrous foundries (66,67). In this process, resin and catalyst are intimately mixed with dry sand and then blown into heated metal boxes containing a cavity the shape of the desired core. In seconds, the surface of the sand mass hardens and, as soon as the core has cured sufficiently to be rigid and handleable the box is opened and the core removed. Automotive cores with exceUent dimensional accuracy and high strengths are made via this forty-year-old process. 

Urea.—Forma.IdehydeResins. Cellular urea—formaldehyde resins can be prepared in the following manner an aqueous solution containing surfactant and catalyst is made into a low density, fine-celled foam by dispersing air into it mechanically. A second aqueous solution consisting of partially cured urea—formaldehyde resin is then mixed into the foam by mechanical agitation. The catalyst in the initial foam causes the dispersed resin to cure in the cellular state. The resultant hardened foam is dried at elevated temperatures. Densities as low as 8 kg/m can be obtained by this method (117). 

In the post-dispersion process, the soHd phenoHc resin is added to a mixture of water, cosolvent, and dispersant at high shear mixing, possibly with heating. The cosolvent, frequently an alcohol or glycol ether, and heat soften the resin and permit small particles to form. On cooling, the resin particles, stabilized by dispersant and perhaps thickener, harden and resist settling and agglomeration. Both resole and novolak resins have been made by this process (25). 

A variety of materials has been proposed to modify the properties of asphaltic binders to enhance the properties of the mix (112), including fillers and fibers to reinforce the asphalt—aggregate mixture (114), sulfur to strengthen or harden the binder (115,116), polymers (98,117—121), mbber (122), epoxy—resin composites (123), antistripping agents (124), metal complexes (125,126), and lime (127,128). AH of these additives serve to improve the properties of the binder and, ultimately, the properties of the asphalt—aggregate mix. 

Hemihydrate. The abiUty of plaster of Paris to readily revert to the dihydrate form and harden when mixed with water is the basis for its many uses. Of equal significance is the abiUty to control the time of rehydration in the range of two minutes to over eight hours through additions of retarders, accelerators, and/or stabilizers. Other favorable properties include its fire resistance, excellent thermal and hydrometric dimensional stabiUty, good compressive strength, and neutral pH. 

Carbon dioxide is widely used in the hardening of sand cores and molds in foundries. Sand is mixed with a sodium siHcate binder to form the core or mold after which it is contacted with gaseous carbon dioxide. Carbon dioxide reacts with the sodium siHcate to produce sodium carbonate and bicarbonate, plus siHcic acid, resulting in hardening of the core or mold without baking. 

The phases and their proportions present ia hardened amalgam are controlled by many factors. The composition of the alloy the size, shape, and size distribution of the particles the thermal history of the cast ingot and the comminuted alloy and the surface treatment of the particles are some of the factors for which the manufacturer is responsible. The tooth cavity preparation and the mixing, compacting, and finishing techniques of the dentist can make the difference between satisfactory and unsatisfactory restorations, even with the best of alloys. A minimal amount of residual mercury and porosity are needed to obtain the most serviceable restorations (138). 

The polysulfide base material contains 50—80% of the polyfunctional mercaptan, which is a clear, amber, sympy Hquid polymer with a viscosity at 25°C of 35, 000 Pa-s(= cP), an average mol wt of 4000, a pH range of 6—8, and a ntild, characteristic mercaptan odor. Fillers are added to extend, reinforce, harden, and color the base. They may iaclude siUca, calcium sulfate, ziac oxide, ziac sulfide [1314-98-3] alumina, titanium dioxide [13463-67-7] and calcium carbonate. The high shear strength of the Hquid polymer makes the compositions difficult to mix. The addition of limited amounts of diluents improves the mix without reduciag the set-mbber characteristics unduly, eg, dibutyl phthalate [84-74-2], tricresyl phosphate [1330-78-5], and tributyl citrate [77-94-1]. 

The term epoxy is familiar to nonchemists because of the widespread use of epoxy glues and resins. These are crosslinked polyether thermoplastics made from a liquid resin which is typically a mixture of bisphenol A diglycidyl ether (70) and a polymer (71 Scheme 86). The liquid resin is cured or hardened to the final resin by mixing with a crosslinking reagent, which can be an acid, a di- or poly-alcohol, or a di- or poly-amine (Scheme 86). 

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