Hard metals 208 INDEX

Hardgrove index Hard lenses Hard metals Hardness... 

Figure Bl.21.1. Atomic hard-ball models of low-Miller-index bulk-temiinated surfaces of simple metals with face-centred close-packed (fee), hexagonal close-packed (licp) and body-centred cubic (bcc) lattices (a) fee (lll)-(l X 1) (b)fcc(lO -(l X l) (c)fcc(110)-(l X 1) (d)hcp(0001)-(l x 1) (e) hcp(l0-10)-(l X 1), usually written as hcp(l010)-(l x 1) (f) bcc(l 10)-(1 x ]) (g) bcc(100)-(l x 1) and (li) bcc(l 11)-(1 x 1). The atomic spheres are drawn with radii that are smaller than touching-sphere radii, in order to give better depth views. The arrows are unit cell vectors. These figures were produced by the software program BALSAC [35]-...

Figure Bl.21.2. Atomic hard-ball models of stepped and kinked high-Miller-index bulk-temiinated surfaces of simple metals with fee lattices, compared with anfcc(l 11) surface fcc(755) is stepped, while fee...

Sa.tura.tion Index. Materials of constmction used in pools are subject to the corrosive effects of water, eg, iron and copper equipment can corrode whereas concrete and plaster can undergo dissolution, ie, etching. The corrosion rate of metallic surfaces has been shown to be a function of the concentrations of Cl ,, dissolved O2, alkalinity, and Ca hardness as well as buffer intensity, time, and the calcium carbonate saturation index (35). 

The effect of pH on the corrosion of zinc has already been mentioned (p. 4.170). In the range of pH values from 5 -5 to 12, zinc is quite stable, and since most natural waters come within this range little difficulty is encountered in respect of pH. The pH does, however, affect the scale-forming properties of hard water (see Section 2.3 for a discussion of the Langelier index). If the pH is below the value at which the water is in equilibrium with calcium carbonate, the calcium carbonate will tend to dissolve rather than form a scale. The same effect is produced in the presence of considerable amounts of carbon dioxide, which also favours the dissolution of calcium carbonate. In addition, it is important to note that small amounts of metallic impurities (particularly copper) in the water can cause quite severe corrosion, and as little as 0-05 p.p.m. of copper in a domestic water system can be a source of considerable trouble with galvanised tanks and pipes. 

In addition to the examples discussed above, where the hybrid materials were derived from the alkoxides of the transition metals, it is necessary to mention that M(OR) (M = Ti, Zr) are the typical inorganic chain-forming reagents often added to the silicon alkoxides to play the cross-linking role between the organosilicon units, which increases the hardness and the refractive index of the hybrid materials. M(OR)n were also found to catalyze the condensation of siloxanes. 

Library of Congress Cataloging in Publication Data. Main entry under title Theoretical inorganic chemistry. (Topics in current chemistry 56). Bibliography p, Includes index. CONTENTS Jorgensen, C. K. Continuum effects indicated by hard and soft antibases (Lewis acids) and bases. - Brunner, H. Stereochemistry of the reactions of optically active organometallic transition metal compounds, [etc.]. 1. Chemistry, Physical and theoretical- Addresses, essays, lectures. I. Series. 

Metal alkoxides act as cross-linking agents between organosilicon units, increasing the hardness of the materials. Tetrafunctional silicon alkoxides are more commonly employed, but transition metal alkoxides M(OR) (M = Ti, Zr, etc.) can also be used. They not only serve as cross-linking reagents, but can also increase the refractive index or catalyze condensation. 

One of the most popular techniques used for determining the hardness of a material is the Mohs scale that consists of a qualitative but an arbitrary hardness index scheme ranging from extremely soft materials (value of 1 Moh) to very hard materials such as diamond (10 Moh). Other techniques that are often employed for measuring hardness of substances are developed by Rockwell [72], Brinell [72], Knoop, and Vickers [73]. Over the years, more quantitative methods such as nanoindentation [74] have been developed. This technique applies a small and a controllable load on to the substrate with a probe. The depth of penetration along with a known geometry of the probe provides an indirect way to measure the area of contact at full penetration, which is then used to determine the hardness. The hardness is determined by the ratio of the total force to the contact area. Table 7.2 lists the bulk hardness of different materials, metal films, and abrasive particles, in both Moh and microhardness scales [75]. 

---