Halogen suppl

Bolt HM. 1987. Pharmacokinetic factors and their implication in the induction of mouse liver tumors by halogenated hydrocarbons. Arch Toxicol Suppl 10 190-203. 

Some Halogenated Hydrocarbons, Lyon, pp. 83-96 lARC (1987) lARC Monographs on the Evaluation of Carcinogenic Risks to Humans, Suppl. l. 

G.F. Koser, Hypervalent halogen compounds, in The Chemistry of Functional Groups, Suppl. D, eds S. Patai and Z. Rappoport, Chapter 18. Wiley-Interscience, Chichester, 1983. 

Dark reddish -brown, volatile, diatomic liquid suffocating odor vaporizes rapidly at room temperature, mp —7.25 (265.90 K) bp 59.47° (JANAF Thermochemical TaWes) 58.78 (Mdlor s Suppl. II, Part I, The Halogens ) dj5 3.1023 crit temp 315 crit pressure 102 atm. Heat capacity at constant pressure (liq, 25°) 18.089 cal/mole deg Hjl-denhrand et al.. J. Am. Chem. Soc. 80, 4129 (1958). Vapor pressure data A. N. Nesmeyanov, Vapor Pressure of the Chemical Eiements, R. Gary, Ed. (Elsevier, New York, 1963) pp 354-58. Total soly in water (25 ) 0.2141 moles/l with formation of 0.00115 moles/1 of HOBrl freely sol in ale. 

Methane forms explosive mixtures with air the LEL and UEL values are 5.5% and 14% by volume of air, respectively. The explosion is loudest at 10% volume concentration. The combustion of methane in air forming CO2 involves chain reactions, propagated by free radicals, CH3-, HO-, H-, and O- (Meyer 1989). Being a saturated molecule, the reactivity of methane toward most substances is very low. However, under catalytic conditions, violent reactions have been reported with halogens and certain fluorides of nonmetals. This includes reactions with chlorine at room temperature over yellow mercuric oxide, bromine pentafluoride, oxygen difluoride in the presence of a spark (MeUor 1946, Suppl. 1956), and nitrogen trifluoride (Lawless and Smith 1968). 

Anders MW, Jakobson I. 1985. Biotransformation of halogenated solvents. Scand J Work Environ Health 11(Suppl 1) 23-32... 

Halogenalcohols (s. a. Halogen-hydrins) 16, 90 suppl. 24 (Halogenalkoxy)stannanes as intermediates 19, 336 suppl. 24 Halogenamines... 

Mannich bases, transamination with amidines, cyclic 18, 482 suppl. 21 Mannich reaction —, N-heterocyclics by — 21, 798 —, double, N-heterocycles by — 13, 775 suppl. 21 anfi-Markownikoff hydro-halogenation 14, 205 suppl. 21... 

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