Gradient method oscillation

Note Because of its neglect of off-diagonal blocks, this optimizer can sometimes oscillate and fail to converge. In this case, use a conjugate gradient method. 

The procedure uses second derivative information and can be quite efficient compared to conjugate gradient methods. However, th e neglect of couplin g in th e Hessian m atrix can lead to situation s where oscillation is possible. Conjugate gradient methods. 

Natural cause and effect 175 Naturally occurring oscillations 126 Negative feedback 158 Nelder-Mead search algorithm 108 Newton s gradient method 108 Nitrogen 572 Non-equilibrium... 

The basic difficulty with the steepest descent method is that it is too sensitive to the scaling of/(x), so that convergence is very slow and what amounts to oscillation in the x space can easily occur. For these reasons steepest descent or ascent is not a very effective optimization technique. Fortunately, conjugate gradient methods are much faster and more accurate. 

Figure 3. A simple gradient method tends to oscillate around the bottom of the valley in a hemstitching pattern making very slow progress.

Most NC-AFMs use a frequency modulation (FM) teclmique where the cantilever is mounted on a piezo and serves as the resonant element in an oscillator circuit [101. 102]. The frequency of the oscillator output is instantaneously modulated by variations in the force gradient acting between the cantilever tip and the sample. This teclmique typically employs oscillation amplitudes in excess of 20 mn peak to peak. Associated with this teclmique, two different imaging methods are currently in use namely, fixed excitation and fixed amplitude. 

One should note that the phase shift becomes time-independent and maximal for a = 1, i.e., at the resonance condition v = vG. The frequency spectrum 4>(a) bears a sine shape with a bandwidth inversely proportional to the number of oscillations of the gradient field (Fig. 4). Such a behaviour was also predicted in Ref. 15. Recording in a systematic way the phase shift as a function of vG without space encoding would be a very fast and efficient method to scan in a whole object the possible frequencies of spin motions. 

Figure 15.6 is a schematic diagram of an AFM with an optical interferometer (Erlandsson et al., 1988). The lever is driven by a lever oscillator through a piezoelectric transducer. The detected force gradient F is compared with a reference value, to drive the z piezo through a controller. In addition to the vibrating lever method, the direct detection of repulsive atomic force through the deflection of the lever is also demonstrated. 

Fig. 4.10 Instantaneous nondimensional velocity profiles in a circular duct with an oscillating pressure gradient. The mean velocity, averaged over one full period, shows that the parabolic velocity profile or the Hagen-Poiseuille flow. These solutions were computed in a spreadsheet with an explicit finite-volume method using 16 equally spaced radial nodes and 200 time steps per period. The plotted solution is that obtained after 10 periods of oscillation.

The first derivatives of a potential energy function define the gradient of the potential and the second derivatives describe the curvature of the energy surface (Fig. 3.4). In most molecular mechanics programs the potential functions used are relatively simple and the derivatives are usually determined analytically. The second derivatives of harmonic oscillators correspond to the force constants. Thus, methods using the whole set of second derivatives result in some direct information on vibrational frequencies. 

In the EHD impedance method, modulation of the flow velocity causes a modulation of the velocity gradient at the interface which, in turn, causes a modulation in the concentration boundary layer thickness. As demonstrated previously in Section 10.3.3 and Fig. 10.3 the experiment shows a relaxation time determined solely by the time for diffusion across the concentration boundary layer. Although there is a characteristic penetration depth, 8hm, of the velocity oscillation above the surface, and at sufficiently high modulation frequencies this is smaller than the concentration boundary layer thickness, any information associated with the variation of hm with w is generally lost, unless the solution is very viscous. The reason is simply that, at sufficiently high modulation frequencies, the amplitude of the transfer function between flow modulation and current density is small. So, in contrast to the AC impedance experiment, the depth into the solution probed by the EHD experiment is not a function... 

The clasdcal fundamentals of the theory of the Kerr effect are due to Voigt in terms of dectron theory of the atom as an anharmonic oscillator and to Langevin in terms of statistical optical reorioitation of anisotropic molecules in a static dectric fidd. Buckingham proposed a theory and method of measurement of the optical birefringence induced by the gradient of a static electric field permitting the determination of electric quadrupole moments. 

---