Glycosyl phosphate

Phosphate esters and anhydrides dominate the living world. Major areas of synthetic interest include oligonucleotides (polymeric phosphate diesters), phospho-rylated peptides, phospholipids, glycosyl phosphates, and inositol phosphates. ... [Pg.662]

Figure 25.7 Glycoprotein formation occurs by initial phosphorylation of the starting carbohydrate to a glycosyl phosphate, followed by reaction with UTP to form a glycosyl uridine 5 -diphosphate. Nucleophilic substitution by an -OH (or -NH2) group on a protein then gives the glycoprotein.

Prolonged chromatography when purifying glycosyl phosphates will lead to hydrolysis and decomposition of the product. [Pg.120]

Glycosyl Phosphates Deoxy sugars, which are vital components of various biomolecules such as vancomycin, erythromycin and daunomycin are difficult to be... [Pg.83]

Synthesis of glycosyl phosphates by exposure of hemiacetals to 81 activated derivatives of phosphoric acid... [Pg.9]

Approaches to the synthesis of glycosyl phosphate diesters as constituents of glycopolymers of the outer membrane of bacteria, yeasts and protozoa and the latest achievements in the field have been profoundly reviewed and will not be covered in this chapter.1,2... [Pg.70]

Employment of glycosyl halides for generation of glycosyl phosphates in... [Pg.73]

Synthesis of glycosyl phosphates by activation of the anomeric hydroxyl group... [Pg.80]

Synthesis of glycosyl phosphates by reaction of hemiacetals with activated phosphoric acid derivatives... [Pg.83]

Approaches to glycosyl phosphates based on P(m)-intermediates 4.1 Phosphoramidite approach in the synthesis of glycosyl phosphates... [Pg.84]

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