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Glycosidation Using Glycosyl Phosphates

Scheme 6.12 Rearrangement to C-aryl glycosides from aryl O-glycosides following a-selective synthesis using glycosyl phosphates. Scheme 6.12 Rearrangement to C-aryl glycosides from aryl O-glycosides following a-selective synthesis using glycosyl phosphates.
Fraser-Reid et al. [21,22] reported the synthesis of polymer supported oligosaccharides using n-pentenyl glycosides, while Seeberger et al. [23] accomplished the synAesis of p-(l- 4)- and p.(2 6)-linked ohgosaccharides using glycosyl phosphates combined with an octenediol linker. [Pg.747]

Chapter 3 demonstrates the development of environmentally benign 0- and C-glycosylation methods using glycosyl phosphates, glycosyl fluorides, methyl glycosides, and 1-hydroxy sugars in several ionic liquids. [Pg.513]

Singh G, Vankayalapati H (2001) Efficient stereocontrolled synthesis of C-glycoside using glycosyl donors substituted by propane 1,3-diyl phosphate as the leaving group. Tetrahedron Asymmetr 12 1727-1735... [Pg.114]

Construction of Glycosidic Bonds Using Glycosyl Phosphates... [Pg.152]

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