Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Isopropyl chloride

Boiling point Freezing point Refractive index Solubility in water 12. 5 C Specific gravity 20/4 C Viacoaity 22. 5 C Weight per gallon [Pg.127]


The NMR spectrum of isopropyl chloride (Figure 13 17) illustrates the appearance of an isopropyl group The signal for the six equivalent methyl protons at 8 1 5 is split into a doublet by the proton of the H—C—Cl unit In turn the H—C—Cl proton signal at 8 4 2 IS split into a septet by the six methyl protons A doublet-septet pattern is char acteristic of an isopropyl group... [Pg.540]

MHz H NMR spectrum of isopropyl chloride showing the doublet-septet pattern of an isopropyl group... [Pg.540]

Isopropylbenzene is prepared by the Friedel-Crafts alkylation of benzene y using isopropyl chloride and aluminum chloride (Section 12 6) j... [Pg.933]

Mechanism. The mechanism of alkylation and of other related Friedel-Crafts reactions is best explained by the carbocation concept. The alkylation of benzene with isopropyl chloride may be used as a general example ... [Pg.552]

The order of reactivity with acid is HI > HBi > HCl. Reaction with hydrochloric acid [7647-01-0] to form isopropyl chloride [75-29-6] is faciUtated by a zinc chloride catalyst. [Pg.105]

Chloropropane Isopropyl chloride 199 C,H,Cl 2-Methylpentane Isohexane 24 QHi4... [Pg.99]

Acyl radicals can fragment with toss of carbon monoxide. Decarbonylation is slower than decarboxylation, but the rate also depends on the stability of the radical that is formed. For example, when reaction of isobutyraldehyde with carbon tetrachloride is initiated by t-butyl peroxide, both isopropyl chloride and isobutyroyl chloride are formed. Decarbonylation is competitive with the chlorine-atom abstraction. [Pg.722]

This type of polarization appears to be general in such systems and it has been proposed that it arises because of T i-S mixing. An interesting and important addif ional observation comes from a study of the reaction of isopropyl chloride with sodium naphthalene in a field of 60 G. Net emission in the products is predicted for T i-S mixing and multiplet polarization for Tq-S mixing. Since no multiplet polarization can be detected, it would seem that Tq-S mixing is suppressed in this system (Garst et al., 1971). Presumably, the naphthalene radical anion... [Pg.113]

Reduction of simple alkyl halides to alkanes by ethylenediamine complexes of Cr(II), denoted Cr"(en) occurs readily , e.g. for isopropyl chloride in aqueous dimethylformamide at 25 °C simple second-order behaviour is found with ki dependent on [en]/[Cr(II)] but reaching a limiting value of 1.6x 10 l.mole . sec . Competition studies between a mixture of two alkyl chlorides for Cr(II) was achieved by estimating alkane products by gas-liquid chromatography and... [Pg.483]

ETHYLENE GLYCOL ETHYL MERCAPTAN DIMETHYL SULPHIDE ETHYL AMINE DIMETHYL AMIDE MONOETHANOLAMINE ETHYLENEDIAMINE ACRYLONITRILE PROPADIENE METHYL ACETYLENE ACROLEIN ACRYLIC ACID VINYL FORMATE ALLYL CHLORIDE 1 2 3-TRICHLOROPROPANE PROPIONITRILE CYCLOPROPANE PROPYLENE 1 2-DICHLOROPROPANE ACETONE ALLYL ALCOHOL PROPIONALDEHYDE PROPYLENE OXIDE VINYL METHYL ETHER PROPIONIC ACID ETHYL FORMATE METHYL ACETATE PROPYL CHLORIDE ISOPROPYL CHLORIDE PROPANE... [Pg.942]

Isopropyl bromide Isopropyl chloride Isopropyl iodide Kerosene Linseed oil, raw Mercury Methnol, 100% Methanol, 90% Methanol, 40%... [Pg.485]

A stream of phosgene was passed into diisopropyl methylphospho-nate (270 g, 1.50 mol) for 10 h with stirring at 20 to 30°C. After completion of the addition, the mixture was allowed to stand overnight, and then the excess phosgene and isopropyl chloride were evaporated under reduced pressure. The residue was vacuum distilled (38°C/2 torr) to give isopropyl methylphosphonochloridate (222 g, 94%). [Pg.133]

E)-2-Chlorovinyl phenyl ketone (1.83 g, 11 mmol) and triisopropyl phosphite (2.08 g, 10 mmol) were heated under an argon atmosphere for 1 h at 120 to 130°C. When all of the isopropyl chloride formed had distilled, the residue was chromatographed on a column of silica gel (18 g) being eluted with a 1 1 mixture of methylene chloride-ethyl acetate. The eluent was evaporated of solvent and the residue vacuum distilled to give pure diisopropyl (E)-2-benzoylvinylphosphonate (1.33 g, 45%). [Pg.182]

However, thermal decomposition of isopropylthiocyanate-trichloroborane does not yield an iminoborane, rather, tris(thiocyanato)-borane and isopropyl-chloride are produced. Methylisothiocyanate-trichloroborane does not rearrange under comparable conditions 33). [Pg.56]

This procedure illustrates a process which is general for 1,1-diphenyl substituted hydrocarbons. Diphenylmethane has been alkylated3 with benzyl chloride, benzhydryl chloride, a-phenyl-ethyl chloride, /3-phenylethyl chloride, isopropyl chloride, 2-ethylbutyl bromide, and re-octyl bromide in yields of 99, 96, 97, 88, 86, 96, and 99%, respectively. [Pg.42]

Nakane ei al. (1964) established equilibrium constants of boron isotope exchange between boron trifluoride gas on one side and boron trifluoride methyl fluoride, methyl chloride, isopropyl chloride and t-butyl chloride. The value of the equilibrium constants, which represents the thermodynamic isotope effect, was related to the polarity, stability and catalytic activity of the complexes. [Pg.308]


See other pages where Isopropyl chloride is mentioned: [Pg.95]    [Pg.227]    [Pg.176]    [Pg.532]    [Pg.104]    [Pg.366]    [Pg.274]    [Pg.353]    [Pg.298]    [Pg.176]    [Pg.139]    [Pg.845]    [Pg.334]    [Pg.107]    [Pg.1099]    [Pg.2404]    [Pg.484]    [Pg.445]    [Pg.385]    [Pg.133]    [Pg.249]    [Pg.25]    [Pg.94]    [Pg.716]    [Pg.745]    [Pg.34]    [Pg.61]   
See also in sourсe #XX -- [ Pg.210 ]

See also in sourсe #XX -- [ Pg.210 ]

See also in sourсe #XX -- [ Pg.34 ]

See also in sourсe #XX -- [ Pg.82 , Pg.95 , Pg.194 , Pg.453 , Pg.825 ]

See also in sourсe #XX -- [ Pg.125 ]

See also in sourсe #XX -- [ Pg.82 , Pg.95 , Pg.194 , Pg.453 , Pg.825 ]

See also in sourсe #XX -- [ Pg.44 , Pg.52 ]

See also in sourсe #XX -- [ Pg.4 , Pg.55 ]

See also in sourсe #XX -- [ Pg.514 ]

See also in sourсe #XX -- [ Pg.1360 , Pg.1361 ]

See also in sourсe #XX -- [ Pg.59 ]

See also in sourсe #XX -- [ Pg.1129 ]

See also in sourсe #XX -- [ Pg.931 ]

See also in sourсe #XX -- [ Pg.138 ]

See also in sourсe #XX -- [ Pg.66 ]

See also in sourсe #XX -- [ Pg.94 , Pg.95 ]

See also in sourсe #XX -- [ Pg.32 ]

See also in sourсe #XX -- [ Pg.203 ]




SEARCH



2-isopropyl- -acetic acid chloride

Alkylation with isopropyl chloride

Diphenylphosphorodiamidic chloride di-isopropyl fluorophosphonate,

Diphenylphosphorodiamidic chloride di-isopropyl hydrogen phosphite

Diphenylphosphorodiamidic chloride di-isopropyl phosphorofluoridate

ISOPROPYL CHLORIDE.179(Vol

Isopropyl acetate chloride

Isopropyl chloride ’H NMR spectrum

Isopropyl chloride, *H NMR

Isopropyl magnesium chloride

Magnesium isopropyl- chlorid

Nuclear magnetic resonance spectra isopropyl chloride

© 2024 chempedia.info