Fulminates silver fulminate

Cadmium fulminate Copper fulminate Dimethylthallium fulminate Diphenylthallium fulminate Mercury(ll) mothyinitrolate Mercury(ll) formhydroxamatc Mercury(ll) fulminate Silver fulminate Sodium fulminate Thallium fulminate... 

Fulminating gold Fulminating mercury Fulminating platinum Fulminating silver Fulminic acid Furan... 

Fulminates (silver fulminate, AgCNO, can form in the reaction mixture from the Tolens test for aldehydes if it is allowed to stand for some time. This can be prevented by adding dilute nitric (V) acid to the test mixture as soon as the test has been completed.)... 

AZ, CZ, SZ, MZ, LZ, MECURY FULMINATE, SILVER FULMINATE, COPPER FULMINATE, SILVER NITRIDE, MERCURY NITRIDE, SULFUR NITIRDE... 

Mercury fulminate Silver fulminate Lead azide Silver azide... 

Do not heat the silver solution or allow it to stand even for a few hours, since explosive silver fulminate may be formed. The ammoniacal solution of silver nitrate is prepared by treating 3 ml. of 0-lN silver nitrate solution with very dilute ammonia solution dropwise until the precipitate which is first formed just redissolves. 

Knall-saure, /. fulminic acid, -silber, n. fulminating silver, -welle, /. explosion wave, shock wave, -zucker, m. (Expl.) nitro-saccharose. -ziinder, m. detonator, -zund-mittel, n. detonating priming, knapp, a. close, tight, narrow scanty exact. Enappe, m. miner. 

Silberoxyd, n. silver oxide, -ammoniak, n, fulminating silver, -salz, n. silver oxysalt. 

Silver Nitride. (Fulminating Silver). Ag3N, mw 337.65, N4.15%, blk-grey powd, mp 25° (start of decompn), d 9.0 lg/cc at 19°. Sol in weak acids, si sol in aq ammonia sol in aq solns of Na chioride and K cyanide. Prepd by treating aq Ag oxide with aq ammonia soln, or by heating coned ammoniacal Ag chloride with solid KOH until evolution of ammonia ceases. The thoroug-ly washed product must be stored under w and, even so, is sensitive to touch (Refs 1—7)... 

Singh and Palkar [726] identified an initial deceleratory reaction in the decomposition of silver fulminate. This obeyed first-order kinetics (E = 27 kJ mole-1) and overlapped with the acceleratory period of the main reaction, which obeyed the power law [eqn. (2), n = 2] with E = 119 kj mole-1. The mechanism proposed included the suggestion that two-dimensional growth of nuclei involved electron transfer from anion to metal. 

A mixture of solid silver nitrate and ethanol was handled with a metallic spatula. The mixture detonated as soon as it came into contact with the spatula. This detonation could be explained by the accidental formation of silver fulminate. However, witnesses noticed the smell of ethyl nitrate after the accident. 

When nitromethane comes into contact with silver nitrate, this can cause spontaneous explosions that are explained by the formation of explosive silver fulminate (see reaction below). 

Action of silver on nitric acid in presence of ethanol may form the readily detonable silver fulminate. 

Exposure of ammoniacal silver chloride solutions to air or heat produces a black crystalline deposit of fulminating silver , mainly silver nitride, with silver diimide and silver amide also possibly present [1], Attention is drawn [2] to the possible explosion hazard in a method of recovering silver from the chloride by passing an ammoniacal solution of the chloride through an ion exchange column to separate the Ag(NH3)+ ion, prior to elution as the nitrate [3], It is essential to avoid letting the ammoniacal solution stand for several hours, either alone or on the column [2], See Silver nitride... 

Aqueous silver nitrate reacts with acetaldehyde to give explosive silver fulminate. 

A silvering solution exploded when disturbed. This is a particularly dangerous mixture, because both silver nitride and silver fulminate could be formed. 

Silver oxide and ammonia or hydrazine slowly form explosive silver nitride and, in presence of alcohol, silver fulminate may also be produced. 

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