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Silver- amide

Exposure of ammoniacal silver chloride solutions to air or heat produces a black crystalline deposit of fulminating silver , mainly silver nitride, with silver diimide and silver amide also possibly present [1], Attention is drawn [2] to the possible explosion hazard in a method of recovering silver from the chloride by passing an ammoniacal solution of the chloride through an ion exchange column to separate the Ag(NH3)+ ion, prior to elution as the nitrate [3], It is essential to avoid letting the ammoniacal solution stand for several hours, either alone or on the column [2], See Silver nitride... [Pg.11]

Metal amides Lead amide, potassium amide, silver amide, sodium amide... [Pg.60]

Nitrogen trilluoride, 4336 Nitrogen triodide, 4633 Nitrogen triiodide-silver amide, 4634 Nitrogen triiodide-ammonia, 4635 Nitrosyl chloride, 4023 Nitrosyl fluoride, 4302 Nitryl chloride, 4025 Nitryl fluoride, 4303... [Pg.184]

Mercury(II) /V-pcrchlory lbcnzylamidc. 3651 Monopotassium perchlorylamide, 3994 Nitrogen triiodide-silver amide, 4634 Nitrosylruthenium trichloride, 4144 Pentaamminedinitrogenruthenium(II) salts, 4596 Pentakis(dimethylamino)tantalum, 3384 Pentasilver diamidophosphate, 0046 Pentasilver orthodiamidophosphate, 0044 Plutonium nitride, 4726 Poly (dimercury immonium hydroxide), 4422... [Pg.232]

Silver acetylide-silver nitrate, 0569 Silver-aluminium alloy, 0002 Silver amide, 0015... [Pg.383]

It is too sensitive to be used for any practical purpose (See also Silver Amide, under Amides, Inorganic in Vol 1 of Encycl, p A169-R) Refs 1) C.L. Berthollet, AnnChimPhys 1(1),... [Pg.616]

M + NHj = MNHj + 1/2H,. Catalysts such as spongy Pt or Fe oxides greatly accelerate the reaction. These amides may serve for theprepnof the very explosive silver amides... [Pg.127]

Metallic amides and imides can be pptd from liq ammonia solns of certain metallic salts by the action of potassium amide, KNH2 Some amides and imides are explosive, eg, silver amide and lead imide (Compare with Nitrides) (See also Polyamides)... [Pg.168]

Silver Amide, AgriHJt buiky wh ppt which darkens on exposure to air and shrinks in vol ... [Pg.169]

Silver Amide, AgNH2, bulky wh ppt which darkens on exposure to air and shrinks in vol very expl and its sensitiveness to deton is not materially charged by lowering the temp to -190° (Ref 4). Can be prepd by mixing a soln of potassamide with Ag nitrate (or iodide) in liq NH, followed by washing by decantation and careful drying (Refs 2,4 ... [Pg.169]

Fulminating Silver of Berthollet. See Silver Amide under Amides A169-R... [Pg.683]


See other pages where Silver- amide is mentioned: [Pg.931]    [Pg.14]    [Pg.14]    [Pg.1719]    [Pg.208]    [Pg.232]    [Pg.165]    [Pg.189]    [Pg.213]    [Pg.169]    [Pg.169]    [Pg.259]    [Pg.278]    [Pg.279]    [Pg.338]    [Pg.169]    [Pg.169]    [Pg.690]    [Pg.7]    [Pg.7]   


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Amidation reactions, silver-mediated oxidation

Fulminating Silver of Berthollet Amide under Amides

Silver complexes amides

Silver- amide azide

Silver- amide diamidophosphate

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