Formic acid propyl ester

Synonym formic acid propyl ester, methanoic acid n-propyl ester, propyl methanoate... 

Acetic acid, pentyl ester 8.0 Formic acid, propyl ester 9.2... 

Formic acid propyl ester. See Propyl formate Formic acid sodium salt. See Sodium formate Formic aldehyde. See Formaldehyde Formic ether. See Ethyl formate Formimidic acid, 1-carbamoyl-. SeeOxamide Formol 55. See Urea-formaldehyde resin Formol. See Formaldehyde Formonitrile. See Hydrogen cyanide Formosa camphor. See Camphor Formosa camphor oil Formose oil of campor. See Camphor (Cinnamomum camphora) oil Formosol. See Sodium formaldehyde sulfoxylate... 

CAS 110-74-7 EINECS/ELINCS 203-798-0 UN 1281 (DOT) FEMA 2943 Synonyms Formic acid propyl ester n-Propyl formate n-Propyl methanoate... 

Beilstein Handbook Reference) AI3-24240 BRN 1738888 EINECS 208-818-1 FEMA No. 2197 Formic acid, 2-methylpropyl ester Formic acid, isobutyl ester Iso-butyl formate Isobutyl formate Isobutyl methanote Isobutylester kyseliny mravenci 2-Methylpropyl formate 2-Methyl-1-propyl formate NSC 6958 Tetryl formate UN2393. Industrial solvent. Liquid mpn-95.8° bp = 98.2° d O = 0.8776 slightly soluble in H2O (1 g/100 ml), CHCI3, very soluble in MezCO, freely soluble in EtOH, Et20. 

Synonyms Carbonochloridic acid, propyl ester Chloroformic acid propyl ester Formic acid, chloro-, propyl ester Propyl chlorocarbonate ... 

Methyl, ethyl, n-propyl, isopropyl, n-hutyl, benzyl, cyclohexyl esters of formic, acetic, oxalic, succinic, tartaric, citric, benzoic, salicylic (and other substituted benzoic acids), phthalic and cinnamic acids phenyl esters of acetic, benzoic and salicylic acids. 

Formic acid (FA), benzoic acid (BA), sorbic acid (SA), and the methyl, ethyl, and propyl esters of 4-hydroxybenzoic acid (EsHBA) or their salts are the organic acids (OAs) most frequently used for the preservation of marmalades, jams, mustard, mayonnaise, margarine, wine, juices, sardines in oil, canned tuna, fish homogenate, diet foods, milk products, salad dressings, desserts, soft drinks, and other types of foods and beverages. 

Beilstein Handbook Reference) AI3-52665 BRN 1633747 Carbonochloridothioic acid, S-propyl ester CCRIS 6097 EINECS 237-656-4 Formic acid, chlorothio-, S-propyl ester HSDB 6155 NSC 72086 Propyl chlorothiofbrmate n-Propyl chloro-thioformate S-Propyl chlorothioformate n-Propyl thiochlorofbrmate ... 

Figure 18.2.1. Chromatogram of substances emitted during degreasing. Oven temperature 40°C. 1 - benzene, 2 -2,2-dichloromethylpropane, 3 - butyl ester of formic acid, 4 - methylbenzene, 5 - water, 6 - 1-butanol, 7, 8,10, 11, 12, 13, 14 - derivatives of methyl ethyl benzene, 9 - propyl benzene.

SPE of acidified sample on graphi-tized carbon black (elution with 90 10 CHzClz/MeOH, 0.025 M in formic acid) formation of propyl or butyl esters in injection port... 

These compounds converted to methyl esters, then GC-MS These compounds propylated with propanol-formic acid-acetyl chloride, then GC-electron impact MC or GC chemical ionisatiorv-MS and GC-MS/MS... 

Carboxylic acids show strongly exothermic reactions with HsO" " and should therefore react at the collisional limit. As with alcohols and aldehydes, dehydration reactions have been identified for all but the smallest acids, formic and acetic [38]. However, for the small number of carboxylic acids whose reactions have been characterized, the non-dissociative channel dominates (>90%) in almost every case. Dehydration is also an issue for esters, although non-dissociative proton transfer has been established as the dominant reaction channel for many relatively simple esters [38], The formates, methyl and ethyl formate, are somewhat unusual in that their dissociative channels, both accounting for <5% of product yield at 300 K, involve CO ejection rather than dehydration. With esters derived from propyl alcohol and higher alcohols, fragmentation is ubiquitous and can involve a number of reaction channels [39]. 

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