Foams interfacial phenomena

In milk, the important interfaces are those between the liquid product and air and between the milk plasma and the fat globules contained therein. Studies of the surface tension (liquid/air) have been made to ascertain the relative effectiveness of the milk components as depressants to follow changes in surface-active components as a result of processing to follow the release of free fatty acids during lipolysis and to attempt to explain the foaming phenomenon so characteristic of milk. Interfacial tensions between milk fat and solutions of milk components have been measured in studies of the stabilization of fat globules in natural and processed milks. 

Petrov etal. (1980) analyzed the causes for the entrapment of water between the solid substrate and the monolayer in Z-type depositions. This phenomenon has many common features with film thinning processes found during foam and emulsion breakdown and it is dependent on interfacial properties and on molecular interactions between the solid substrate and the monolayer. Petrov etal. (1980) measured the maximum speed of removal of the solid substrate before entrainment of a water layer and found it to be dependent on pH and ionic strength. There is no record in the publication of the measurement of dynamic contact angles. 

As is the case in most discussions of interfacial systems and their applications, definitions and nomenclature can play a significant role in the way the material is presented. The definition of an emulsion to be followed here is that they are heterogeneous mixtures of at least one immiscible liquid dispersed in another in the form of droplets, the diameters of which are, in general, greater than 0.1 (.m. Such systems possess a minimal stability, generally defined rather arbitrarily by the application of some relevant reference system such as time to phase separation or some related phenomenon. Stability may be, and usually is, enhanced by the inclusion of additives such as surfactants, finely divided solids, and polymers. Such a definition excludes foams and sols from classification as emulsions, although it is possible that systems prepared as emulsions may, at some subsequent time, become dispersions of solid particles or foams. 

---