Flow-injection analysis propelling systems

Automatic systems based on FIA were also implemented for wine analysis. In a comprehensive review, Ferreira and coworkers [97] remarked that some systems had limitations as many of them were only tested with a particular wine type or demanded a previous treatment of the sample before injection. The lack of robustness of some manifold components (tubing of peristaltic pumps, some types of injection devices) was also thought to prevent the extensive use of FIA in industrial laboratories [98]. SIA has been proposed as a mechanically simple alternative to FIA [99]. As previously stated, SIA is based on the sequential aspiration of well-defined sample and reagent zones into a holding coil by means of a multiposition valve. The flow is then reversed and the stacked zones are mixed and propelled to the detector, where the reaction product is monitored. As already described for other beverage matrices (water, juices), the SIA of wine has been developed in recent years for the determination of more than 20 species and several aspects of these systems were reviewed by Segundo et al. [100] in a recent paper. The authors focused on the implementation of in-line treatment and the adaptation of system operation through software control to enable determination in different kind of wines. 

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