Fischer-Tropsch synthesis kinetics

Fischer-Tropsch Synthesis Kinetics and Effect of Water for a C0/AI2O3 Catalyst... 

Yates, I. C., and Satterfield, C. N. 1991. Intrinsic kinetics of the Fischer-Tropsch synthesis on a cobalt catalyst. Energy Fuels 5 168-73. 

Nettelhoff, H., Kokuun, R., Ledakpwicz, S., and Deckwer, W.D. 1985. Studies on the kinetics of Fischer-Tropsch synthesis in slurry phase. Ger. Chem. Eng. 8 177-85. 

Ma, W.P., Jacobs, G., Sparks, D.E., Spicer, R.L., Graham, U.M., and Davis, B. H. 2008. Comparison of the kinetics of the Fischer-Tropsch synthesis reaction between structured alumina supported cobalt catalysts with different pore size. Prepr. Am. Chem. Soc. Div. Petro. Chem. 53 99-102. (see Chapter 8 of this book.)... 

Zennaro, R., Tagliabue, M., and Bartholomew, C. 2000. Kinetics of Fischer-Tropsch synthesis on titania-supported cobalt. Catal. Today 58 309-19. 

Withers, H.P., Eliezer, K.F., and Mitchell, J.W. 1990. Slurry-phase Fischer-Tropsch synthesis and kinetic studies over supported cobalt carbonyl derived catalysts. Ind. Eng. Chem. Res. 29 1807-14. 

Li, S., Ding, W., Meitzner, G.D., and Iglesia, E. 2002. Spectroscopic and transient kinetic studies of site requirements in iron-catalyzed Fischer-Tropsch synthesis. J. Phys. Chem. B 106 85-91. 

Van Der Laan, G. P., and Beenackers, A. A. C. M. 1999. Kinetics and selectivity of the Fischer-Tropsch synthesis A literature review. Catalysis Reviews—Science and Engineering 41 255-318. 

Detailed Kinetic Study and Modeling of the Fischer-Tropsch Synthesis over a State-of-the-Art Cobalt-Based Catalyst... 

In this work, a detailed kinetic model for the Fischer-Tropsch synthesis (FTS) has been developed. Based on the analysis of the literature data concerning the FT reaction mechanism and on the results we obtained from chemical enrichment experiments, we have first defined a detailed FT mechanism for a cobalt-based catalyst, explaining the synthesis of each product through the evolution of adsorbed reaction intermediates. Moreover, appropriate rate laws have been attributed to each reaction step and the resulting kinetic scheme fitted to a comprehensive set of FT data describing the effect of process conditions on catalyst activity and selectivity in the range of process conditions typical of industrial operations. 

Kinetic Study and Modeling of the Fischer-Tropsch Synthesis... 

Visconti, C.G., Tronconi, E., Lietti, L., Zennaro, R., and Forzatti, P. 2007. Development of a complete kinetic model for the Fischer-Tropsch synthesis over Co/A1203 catalysts. Chem. Eng. Sci. 62 5338 -3. 

Fischer-Tropsch synthesis, 28 80, 97, 103, 30 166-168, 34 18, 37 147, 39 221-296 activation energy and kinetics, 39 276 added olefin reactions, 39 251-253 bed residence time effects on chain growth probability and product functionality, 39 246-250... 

In 1976 he was appointed to Associate Professor for Technical Chemistry at the University Hannover. His research group experimentally investigated the interrelation of adsorption, transfer processes and chemical reaction in bubble columns by means of various model reactions a) the formation of tertiary-butanol from isobutene in the presence of sulphuric acid as a catalyst b) the absorption and interphase mass transfer of CO2 in the presence and absence of the enzyme carboanhydrase c) chlorination of toluene d) Fischer-Tropsch synthesis. Based on these data, the processes were mathematically modelled Fluid dynamic properties in Fischer-Tropsch Slurry Reactors were evaluated and mass transfer limitation of the process was proved. In addition, the solubiHties of oxygen and CO2 in various aqueous solutions and those of chlorine in benzene and toluene were determined. Within the framework of development of a process for reconditioning of nuclear fuel wastes the kinetics of the denitration of efQuents with formic acid was investigated. 

---