Fibers with titanium dioxide

The case histories presented in Section 21.6.4 to 21.6.6 demonstrate that fibers and titanium dioxide can be recovered from a whitewater by DAF under full flow pressurization mode or recycle pressurization mode with or without chemical addition.59... 

Almost all fiber and partial titanium dioxide can be recovered from white water by DAF under full flow pressurization mode43 with chemical addition. On June 10, 1982, at Mead Corporation, pulp was prepared with 40% cotton fiber and 60% wood fiber. The loading of titanium dioxide was about 50% (i.e., 273 kg Ti02 per 600 kg total pulp). The white water from No. 2 machine was fed to a DAF cell (diameter = 3 m) at 15.8 L/s (250gal/min) under full flow pressurization mode. Turkey red oil (TRO) was dosed as a flotation aid at 80mL/min. The influent white water (before TRO addition), DAF effluent, and floated scum were sampled for analysis. The DAF influent had 98 mg/L of TSS, and 650 NTU of turbidity at pH 9.27. The DAF effluent had 15 mg/L TSS and 550 NTU of turbidity at pH 9.25. Although TSS (fiber and titanium dioxide) recovery rate was 85%, the ash content (titanium dioxide) of the recovered TSS was very low. Therefore, using a DAF clarifier under full flow pressurization mode and TREO, the majority of fibers in white water but only about half of titanium dioxide can be recovered. 

Lam, Y.L., Kan, C.W., Yuen, C.W.M., 2011. Effect of plasma pretreatment on the wrinkle-resistance properties of cotton fibers treated with a 1,2,3,4-butanetetracarboxylic acid-sodium hypophosulfite system with titanium dioxide as a cocatalyst. J. Appl. Polym. Sci. 120, 1403-1410. 

The original yams were marketed as silk substitutes for use in apparel, hosiery, lace, home furnishings, ribbons, braids, and in a whole range of fabrics using blends with cotton or wool yams. As the end uses expanded beyond silk replacement, the harsh metallic luster of the yam proved disadvantageous and dull "matt" fibers had to be developed. Oil dulling was invented (11) in 1926, and an improved method using titanium dioxide was developed (12) in 1929. 

A significant advantage of the PLM is in the differentiation and recognition of various forms of the same chemical substance polymorphic forms, eg, brookite, mtile, and anatase, three forms of titanium dioxide calcite, aragonite and vaterite, all forms of calcium carbonate Eorms I, II, III, and IV of HMX (a high explosive), etc. This is an important appHcation because most elements and compounds possess different crystal forms with very different physical properties. PLM is the only instmment mandated by the U.S. Environmental Protection Agency (EPA) for the detection and identification of the six forms of asbestos (qv) and other fibers in bulk samples. 

Polyester. The most common polyester in use is derived from the homopolymer poly (ethylene terephthalate). Many types of this fiber contain a delustrant, usually titanium dioxide. Optically brightened polymers are quite common. The optical brightener, such as specially stabilized derivatives of either stilbenes or phenylcoumarins, can be added to the polyester before formation of the fiber (107). Some commercial fibers contain minor amounts of copolymerized modifier to confer such properties as basic dyeability. A wide range of polyester fibers is used for consumer end-uses. Both staple fiber and filament yarn are available. Filament yarns with noncircular cross-sections are made (107). 

Even beyond this, why wash clothes at all Some have experimented with nano-particles of titanium dioxide, a substance that can be coated onto clothes in a thin layer the substance then reacts with sunlight to break down dirt and other organic material. Others have proposed infusing clothing fibers with bacteria that eat dirt, in essence enabling the clothes to clean themselves. 

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