Fast atom bombardment mass spec

Curtis and Eisenstein355 have made a molecular orbital analysis of the regioselectivity of the addition of nucleophiles to 77-allyl complexes and on the conformation of the 773-allyl ligand in [MoX(CO)2L2(773-allyl)] type complexes. A detailed study of the chirality retention in rearrangements of complexes of the type [MX(CO)2(dppe)(rj3-C3H5)] has been made.356 Studies of the photoelectron spectra,357 electrochemical properties,358 infrared spectroelectrochemistry,359 and fast atom bombardment mass spec-... 

Abdulsada, A. K. et al., A fast-atom-bombardment mass-spectrometric study of room-temperature l-ethyl-3-methylimidazolium chloroaluminate(Iii) ionic liquids Evidence for the existence of the decachlorotrialuminate(Iii) anion. Org. Mass Spec., 28, 759, 1993. 

Facino, R.M., Carini, M., Aldini, G., and Colombo, L., Characterization of the intermediate products of lipid peroxidation in phosphatidylcholine liposomes by fast-atom bombardment mass spectrometry and tandem mass spectrometry techniques, Rapid Commun. Mass Spec., 10, 1148, 1996. 

Future work will involve the use of soft-ionization mass spec-trometric techniques such as field desorption and fast atom bombardment to try to identify these compounds. 

For detection of carbohydrates in principle, ultraviolet (UV), laser-induced fluorescence, refractive index, electrochemical, amperometric, and mass spec-trometric detection can be used. Mass spectrometry, with its various ionization methods, has traditionally been one of the key techniques for the structural determination of proteins and carbohydrates. Fast-atom bombardment (FAB) and electrospray ionization (ESI) are the two on-line ionization methods used for carbohydrate analysis. The ESI principle has truly revolutionized the modern mass spectrometry of biological molecules, due to its high sensitivity and ability to record large-molecule entities within a relatively smaU-mass scale. 

Ukena, T. et al., Structural confirmation of ostreocin-D by application of negative-ion fast-atom bombardment collision-induced dissociation tandem mass spectrometric methods. Rapid Commun. Mass Spec., 16, 2387, 2002. 

Kayganich, K.A. and Murphy, R.C. (1992) Fast atom bombardment tandem mass spec-trometric identification of diacyl, alkylacyfi and alk-l-enylacyl molecular species of glycerophosphoethanolamine in human polymorphonuclear leukocytes. Anal. Chem. 64,... 

Griffiths, W. J. Brown, A. Reimendal, R. Yang, Y. Zhang, J. Sjoevall, J. A comparison of fast-atom bombardment and electrospray as methods of ionization in the study of sulfated- and sulfonated lipids by tandem mass spectrometry. Rapid Commun. Mass Spec. 1996, 10, 1169-1174. 

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