External momentum

Tn this discussion we missed some important point. Since momentum is conserved, a diagram yields a iionvamshing contribution only if the total external momentum flowing into any of its connected parts sums tip to zero. The diagram of Fig. 4.8a, for instance, contributes only if pi 4- p2 4- P i + P4 = 0, P5 4- pc = 0. For each connected component of a diagram the last integral over an endpoint takes the form... 

By repeated application of this identity index 02 can be reduced to zero (see Fig.2) which implies that the calculation of 7(ai, 02) is reduced to the calculation of vacuum bubble integrals that do not dependent on the external momentum p. That is a significant simplification. 

In all the above 2-loop graphs one has the external momentum p, which satisfies the mass-shell constraint p2 = —m2, me being the mass of the electron, and 2 loop momenta, ki and k2 with them one can form the 5 scalar products k2,k2, (p.ki), (p.k2), (ki.k2). Any of the occurring graphs involves a subset of the following Feynman propagators (more exactly inverse Feynman propagators in the momentum representation)... 

Electrons and most other fiindamental particles have two distinct spin wavefunctions that are degenerate in the absence of an external magnetic field. Associated with these are two abstract states which are eigenfiinctions of the intrinsic spin angular momentum operator S... 

The tliree conservation laws of mass, momentum and energy play a central role in the hydrodynamic description. For a one-component system, these are the only hydrodynamic variables. The mass density has an interesting feature in the associated continuity equation the mass current (flux) is the momentum density and thus itself is conserved, in the absence of external forces. The mass density p(r,0 satisfies a continuity equation which can be expressed in the fonn (see, for example, the book on fluid mechanics by Landau and Lifshitz, cited in the Furtlier Reading)... 

The probability of a transition —>/resulting from any external perturbation which impulsively transfers momentum q to the internal momenta of the electrons of the target system is... 

Now, consider the case of spinless particles not subject to external electronic and magnetic fields. We may now choose the unitai7 operator U as the unit operator, that is, T = K. For the coordinate and momentum operators, one then obtains... 

The creation terms embody the changes in momentum arising from external forces in accordance with Newton s second law (F = ma). The body forces arise from gravitational, electrostatic, and magnetic fields. The surface forces are the shear and normal forces acting on the fluid diffusion of momentum, as manifested in viscosity, is included in these terms. In practice the vector equation is usually resolved into its Cartesian components and the normal stresses are set equal to the pressures over those surfaces through which fluid is flowing. 

Conservation of linear and angular momentum. If the potential function U depends only on particle separation (as is usual) and there is no external field applied, then Newton s equation of motion conserves the total linear momentum of the system, P,... 

MOMEN- TUM BALANCE Rate of change of momentum per unit volume Rale of change of momenium by convection per unit volume Rale of change of momentum by molecular transfer (viscous transfer) per volume Generation per volume (External forces) (Ex gravity) Empirically determined flux specified (3)< Velocity specified (1.2b) ... 

Before returning to the non-BO rate expression, it is important to note that, in this spectroscopy case, the perturbation (i.e., the photon s vector potential) appears explicitly only in the p.i f matrix element because this external field is purely an electronic operator. In contrast, in the non-BO case, the perturbation involves a product of momentum operators, one acting on the electronic wavefimction and the second acting on the vibration/rotation wavefunction because the non-BO perturbation involves an explicit exchange of momentum between the electrons and the nuclei. As a result, one has matrix elements of the form (P/ t)Xf > in the non-BO case where one finds lXf > in the spectroscopy case. A primary difference is that derivatives of the vibration/rotation functions appear in the former case (in (P/(J.)x ) where only X appears in the latter. 

Two system-dependent interpretative pictures have been proposed to rationalize this percolative behavior. One attributes percolation to the formation of a bicontinuous structure [270,271], and the other it to the formation of very large, transient aggregates of reversed micelles [249,263,272], In both cases, percolation leads to the formation of a network (static or dynamic) extending over all the system and able to enhance mass, momentum, and charge transport through the system. This network could arise from an increase in the intermicellar interactions or for topological reasons. Then all the variations of external parameters, such as temperature and micellar concentration leading to an extensive intermicellar connectivity, are expected to induce percolation [273]. 

The classical kinetic energy of the system has now been separated into the effect of displacement of the center of mass of the system, with momentum P and that of the relative movement of the two particles, with momentum p. In the absence of external forces, the interaction of the two (spherical) particles is only a function of (heir separation, r. That is, the potential function appearing in Eq. (37) depends only on the internal coordinates x, y, z. 

The intrinsic constitutive laws (equations of state) are those of each phase. The external constitutive laws are four transfer laws at the walls (friction and mass transfer for each phase) and three interfacial transfer laws (mass, momentum, energy). The set of six conservation equations in the complete model can be written in equivalent form ... 

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