Expected and Available Results

Boron Halides.—Non-empirical valence-electron (NEVE) M.O. calculations have been performed on all of the monohalides of Group m (B to In, F to I), llie trends in calculated properties are as expected, and the results agree well with available all-electron ab initio results, which are much more costly in computer... 

The planning processes described herein were traditional in nature, with little variation from year to year. Growth was steady, equipment technology advancements were available for the conditions expected, and while utility facilities were capital-intensive, a regulated guaranteed return on investment resulted in adequate financing capital. The utility planner had a vision of the future with acceptable accuracy. 

A measurement technique such as titration is employed that provides a single result that, on repetition, scatters somewhat around the expected value. If the difference between expected and observed value is so large that a deviation must be suspected, and no other evidence such as gross operator error or instrument malfunction is available to reject this notion, a statistical test is applied. (Note under GMP, a deviant result may be rejected if and when there is sufficient documented evidence of such an error.)... 

Where mobility data are available over a considerable range of temperature, the activation energy is often found to be temperature-dependent. Thus, in n-pentane the activation energy increases with temperature whereas in ethane it decreases (Schmidt, 1977). Undoubtedly, part of the explanation lies in the temperature dependence of density, but detailed understanding is lacking. In very high mobility liquids, the mobility is expected to decrease with temperature as in the case of the quasi-free mobility. Here again, as pointed out by Munoz (1991), density is the main determinant, and similar results can be expected at the same density by different combinations of temperature and pressure. This is true for LAr, TMS, and NP, but methane seems to be an exception. 

This simple valence-bond rationale, involving a resonance hybrid of forms 1 and 2, appears to explain many of the physical data available for sulfoxide complexes. It appears that S-bonding does not involve such a major internal rearrangement of the molecule as one may initially expect and is almost certainly a result of the increased orbital diffuseness on passing from oxygen to sulfur. Thus with typical hard acids (see ref. 437), orbital overlap will be most favorable with the less diffuse donor orbital of oxygen. In the case of typical soft metals, this overlap is less favorable due to the orbital diffuseness of the soft acid, and so coordination via sulfur occurs, where the orbital diffuseness of the donor and acceptor are more evenly matched. 

The carcinogenicity of polycyclic aromatic compound-rich tyre extender oils has lead to the proposal of a legislative ban on their use in Europe. The suitability of naphthenic oils as non-toxic plasticisers in tyre treads is discussed and results are presented of experimental studies of the use of these plasticisers in SBR, EPDM, sulphur-cured EPDM and peroxide-cured EPDM. Despite their low aromatic content, the naphthenic plasticisers are shown to give good results in SBR, probably as a result of the contribution to solvent characteristics of the naphthenic molecular structure. The use of naphthenic oils is expected to increase worldwide as they are said to be one of the best alternatives to aromatic extracts with regard to solvent properties, compatibility, performance and availability. 

The comparison between measured and calculated results for vapor-liquid equilibria in aqueous systems of weak electrolytes confirms the applicability of van Krevelen 1s method for moderate temperatures and concentrations. The comparison also indicates that the procedure of Edwards, Maurer, Newman and Prausnitz yields reliable results also at temperatures around 100 °C therefore, it may be expected that it is also useful at higher temperatures where experimental material, necessary for checking that procedure, is not available... 

The modest electrical drive requbements of these diodes, and the resulting option to power the laser with standard penlight (AA) batteries, allow these CnLiSAF lasers to boast an impressive electrical-to-optical efficiency of over 4 %, which until recently" was the highest reported overall system efficiency of any femtosecond laser source. The amplitude stability of the laser output was observed to be very stable with a measured fluctuation of less than 1% for periods in excess of 1 h. These measurements were made on a laser that was not enclosed and located in a lab that was not temperature-controlled. In a more enclosed and conbolled local envbonment we would expect the amplitude fluctuations of this laser to be extremely small. While the output powers achievable from these lasers have been limited by the available power from the AlGalnP red laser pump diodes, there are already sbong indications that commercial access to higher-power suitable diode lasers is imminent. 

---